scholarly journals Analysis of a Hybrid Suspended-Supported Photocatalytic Reactor for the Treatment of Wastewater Containing Benzothiazole and Aniline

Water ◽  
2019 ◽  
Vol 11 (2) ◽  
pp. 337 ◽  
Author(s):  
Cristian Ferreiro ◽  
Natalia Villota ◽  
José Lombraña ◽  
María Rivero ◽  
Verónica Zúñiga ◽  
...  
Keyword(s):  
Industrial Effluent ◽  
Supported Catalyst ◽  
Operating Conditions ◽  
Energy Costs ◽  
Photocatalytic Reactor ◽  
Operating Variables ◽  
Ms Analysis ◽  
Photocatalytic Material ◽  
Main Operating

In this work, a study of the main operating variables affecting TiO2/UV photocatalysis was carried out. The treatment of an industrial effluent containing aniline and benzothiazole from the manufacture of accelerants for vulcanization was performed in a TiO2-supported commercial photoreactor. The degradation of both contaminants was monitored by GC-MS analysis. The proposed experiments were able to properly identify the phenomenon of adsorption, as well as to improve the performance of the commercial photoreactor by adding small amounts of TiO2 in suspension. The removal performance, durability of the photocatalytic material, and energy costs were analysed. The results showed that the use of suspensions intensifies the degradation obtaining an improvement of 23.15% with respect to the use of the supported catalyst. For an aniline and benzothiazole solution, the best operating conditions were found at pH = 12.0, introducing 60.0 mg L−1 of suspended TiO2 together with the existing supported catalyst.

Cake Formation in Cross-Flow Microfiltration Systems

1992 ◽  
Vol 25 (10) ◽  
pp. 149-162 ◽  
Author(s):  
V. L. Pillay ◽  
C. A. Buckley
Keyword(s):  
Cross Flow ◽  
Operating Conditions ◽  
Waste Waters ◽  
Domestic Waste ◽  
Time Curve ◽  
Good Correspondence ◽  
Operating Variables ◽  
Start Up ◽  
Turbulent Flow Regime ◽  
Cake Formation

Cross-flow microfiltration (CFMF) has potentially wide application in the processing of industrial and domestic waste waters. Optimum design and operation of CFMF systems necessitates a knowledge of the characteristic system behaviour, and an understanding of the mechanisms governing this behaviour. This paper is a contribution towards the elucidation and understanding of the behaviour of a woven fibre CFMF operated in the turbulent flow regime. The characteristic flux-time curve and effects of operating variables on flux are presented for a limestone suspension cross-flow filtered in a 25 mm woven fibre tube. The phenomena contributing to the shape of the flux-time curve are discussed. A model of the mechanisms governing cake growth and limit is presented. Predicted steady-state fluxes show a notably good correspondence with experimentally measured values. It is also found that the flux may not be uniquely defined by the operating conditions, but may also be a function of the operating path taken to reach the operating point. This is of significance in the start-up and operation of CFMF units.

scholarly journals Effective Chromium Adsorption From Aqueous Solutions and Tannery Wastewater Using Bimetallic Fe/Cu Nanoparticles: Response Surface Methodology and Artificial Neural Network

2021 ◽  
Vol 14 ◽  
pp. 117862212110281
Author(s):  
Ahmed S. Mahmoud ◽  
Nouran Y. Mohamed ◽  
Mohamed K. Mostafa ◽  
Mohamed S. Mahmoud
Keyword(s):  
Response Surface Methodology ◽  
Response Surface ◽  
Industrial Effluent ◽  
Oxygen Demand ◽  
Operating Conditions ◽  
Tannery Wastewater ◽  
P Value ◽  
Cu Nanoparticles ◽  
Artificial Neural ◽  
Cr Removal

Tannery industrial effluent is one of the most difficult wastewater types since it contains a huge concentration of organic, oil, and chrome (Cr). This study successfully prepared and applied bimetallic Fe/Cu nanoparticles (Fe/Cu NPs) for chrome removal. In the beginning, the Fe/Cu NPs was equilibrated by pure aqueous chrome solution at different operating conditions (lab scale), then the nanomaterial was applied in semi full scale. The operating conditions indicated that Fe/Cu NPs was able to adsorb 68% and 33% of Cr for initial concentrations of 1 and 9 mg/L, respectively. The removal occurred at pH 3 using 0.6 g/L Fe/Cu dose, stirring rate 200 r/min, contact time 20 min, and constant temperature 20 ± 2ºC. Adsorption isotherm proved that the Khan model is the most appropriate model for Cr removal using Fe/Cu NPs with the minimum error sum of 0.199. According to khan, the maximum uptakes was 20.5 mg/g Cr. Kinetic results proved that Pseudo Second Order mechanism with the least possible error of 0.098 indicated that the adsorption mechanism is chemisorption. Response surface methodology (RSM) equation was developed with a significant p-value = 0 to label the relations between Cr removal and different experimental parameters. Artificial neural networks (ANNs) were performed with a structure of 5-4-1 and the achieved results indicated that the effect of the dose is the most dominated variable for Cr removal. Application of Fe/Cu NPs in real tannery wastewater showed its ability to degrade and disinfect organic and biological contaminants in addition to chrome adsorption. The reduction in chemical oxygen demand (COD), biological oxygen demand (BOD), total suspended solids (TSS), total phosphorus (TP), total nitrogen (TN), Cr, hydrogen sulfide (H2S), and oil reached 61.5%, 49.5%, 44.8%, 100%, 38.9%, 96.3%, 88.7%, and 29.4%, respectively.

scholarly journals Simulation of a Downdraft Gasifier for Production of Syngas from Different Biomass Feedstocks

2021 ◽  
Vol 5 (2) ◽  
pp. 20
Author(s):  
Mateus Paiva ◽  
Admilson Vieira ◽  
Helder T. Gomes ◽  
Paulo Brito
Keyword(s):  
Modeling And Simulation ◽  
Pilot Scale ◽  
Operating Conditions ◽  
Fuel Gas ◽  
Heating Value ◽  
Downdraft Gasifier ◽  
Process Operation ◽  
Independent Parameters ◽  
Gasification Temperature ◽  
Main Operating

In the evaluation of gasification processes, estimating the composition of the fuel gas for different conditions is fundamental to identify the best operating conditions. In this way, modeling and simulation of gasification provide an analysis of the process performance, allowing for resource and time savings in pilot-scale process operation, as it predicts the behavior and analyzes the effects of different variables on the process. Thus, the focus of this work was the modeling and simulation of biomass gasification processes using the UniSim Design chemical process software, in order to satisfactorily reproduce the operation behavior of a downdraft gasifier. The study was performed for two residual biomasses (forest and agricultural) in order to predict the produced syngas composition. The reactors simulated gasification by minimizing the free energy of Gibbs. The main operating parameters considered were the equivalence ratio (ER), steam to biomass ratio (SBR), and gasification temperature (independent variables). In the simulations, a sensitivity analysis was carried out, where the effects of these parameters on the composition of syngas, flow of syngas, and heating value (dependent variables) were studied, in order to maximize these three variables in the process with the choice of the best parameters of operation. The model is able to predict the performance of the gasifier and it is qualified to analyze the behavior of the independent parameters in the gasification results. With a temperature between 850 and 950 °C, SBR up to 0.2, and ER between 0.3 and 0.5, the best operating conditions are obtained for maximizing the composition of the syngas in CO and H2.

The Influences of Reaction Conditions on Phenanthrene Hydrogenation over NiW/Al2O3 Catalyst

2012 ◽  
Vol 512-515 ◽  
pp. 2200-2206
Author(s):  
Kun Wang ◽  
Jun Guan ◽  
De Min He ◽  
Qiu Min Zhang
Keyword(s):  
Positive Impact ◽  
Volume Ratio ◽  
Operating Conditions ◽  
Reaction Conditions ◽  
Remarkable Effect ◽  
Ms Analysis ◽  
Temperature And Pressure ◽  
Cracking Products

Hydrogenation of phenanthrene (PHE HYD) was investigated over a commercial NiW/Al2O3catalyst under practical reaction conditions. GC-MS analysis was utilized to identify the numerous products formed during PHE HYD. The products included dihydrophenanthrene (DHP), 1,2,3,4-tetrahydrophenanthrene (THP), sym-octahydrophenanthrene (1,8-OHP), asym-octahydrophenanthrene (1,10-OHP) and perhydrophenanthrene (PHP), but the cracking products were not found under the reaction conditions. The effects of operating conditions such as temperature, pressure and H2/liquor on PHE HYD were tested in detail. It is found that temperature and pressure had remarkable effect on PHE HYD, but volume ratio of H2/liquor had little effect on PHE HYD at the observation range. The addition of decalin had a positive impact on PHE HYD; it could increase the conversion of PHE and the selectivity to PHP.

Comparison of the efficiency of large-scale ceramic and membrane aeration systems with the dynamic off-gas method

2002 ◽  
Vol 46 (4-5) ◽  
pp. 317-324 ◽  
Author(s):  
J.A. Libra ◽  
A. Schuchardt ◽  
C. Sahlmann ◽  
J. Handschag ◽  
U. Wiesmann ◽  
...  
Keyword(s):  
Large Scale ◽  
Operating Conditions ◽  
Air Distribution ◽  
Energy Costs ◽  
Dissolved Oxygen Concentration ◽  
Membrane Aeration ◽  
Aeration System ◽  
Oxygen Transfer Efficiency ◽  
Aeration Efficiency ◽  
Period Measurement

The aeration systems of two full-scale activated sludge basins were compared over 2.5 years under the same operating conditions using dynamic off-gas testing. Only the material of the diffuser was different, membrane vs. ceramic tube diffusers. The experimental design took the complexity and dynamics of the system into consideration. The investigation has shown that, although the membrane diffusers have higher initial standard oxygen transfer efficiency (SOTE) and standard aeration efficiency (SAE), these decreased over time, while the SAE of the ceramic diffusers started lower, but increased slightly over the whole period. Measurement of air distribution in the basins along with dissolved oxygen concentration profiles have provided important information on improving process control and reducing energy costs. The results show that dynamic off-gas testing can effectively be used for monitoring the aeration system and to check design assumptions under operating conditions. The information can be used to improve the design of new aeration systems or in retro-fitting existing basins.

Photo-degradation of butyl parahydroxybenzoate by using TiO2-supported catalyst

2013 ◽  
Vol 67 (10) ◽  
pp. 2141-2147 ◽  
Author(s):  
Patrick Atheba ◽  
Patrick Drogui ◽  
Brahima Seyhi ◽  
Didier Robert
Keyword(s):  
Flow Rate ◽  
Photocatalytic Oxidation ◽  
Supported Catalyst ◽  
Operating Conditions ◽  
Treatment Efficiency ◽  
Optimal Operating ◽  
Photo Degradation ◽  
Photochemical Process ◽  
Recirculation Flow ◽  
High Treatment

The present work evaluates the potential of the photocatalysis (PC) process for the degradation of butylparaben (BPB). Relatively high treatment efficiency was achieved by comparison to photochemical process. Prior to photocatalytic degradation, adsorption (AD) of BPB occurred on the titanium dioxide (TiO2)-supported catalyst. AD was described by Langmuir isotherm (KL = 0.085 L g−1, qm = 4.77 mg g−1). The influence of angle of inclination of the reactor, pH, recirculation flow rate and initial concentration of BPB were investigated. The PC process applied under optimal operating conditions (recirculation flow rate of 0.15 L min−1, angle of inclination of 15°, pH = 7 and 5 mg L−1 of BPB) is able to oxidize 84.9–96.6% of BPB and to ensure around 38.7% of mineralization. The Langmuir–Hinshelwood kinetic model described well the photocatalytic oxidation of BPB (k = 7.02 mg L−1 h−1, K = 0.364 L mg−1).

Using Taguchi Experimental Design to Investigate Operating Variables That Significantly Affect Wear in Mud Pumps

1995 ◽  
Vol 209 (1) ◽  
pp. 29-40
Author(s):  
S H Mok ◽  
D G Gorman
Keyword(s):  
Experimental Design ◽  
Normal Load ◽  
Drilling Fluid ◽  
Operating Conditions ◽  
Taguchi Experimental Design ◽  
Drilling Mud ◽  
Test Rig ◽  
Offshore Drilling ◽  
Wear Rates ◽  
Operating Variables

Maintenance of offshore drilling mud pumps is normally based on running hours. It is generally accepted, however, that time does not provide an accurate means of scheduling maintenance, given the varying operating conditions of the reciprocating mud pumps. The energy expended at the interaction of sliding surfaces is hypothesized to be a better alternative. The effects of operating variables on wear rates are investigated. A Taguchi experimental design was used to identify those factors that significantly affect wear. Within the confines of an experimental test rig, the normal load and abrasive sand content was found to have a significant effect on the specific wear rate of nitrile rubber sliding on steel in drilling fluid.

scholarly journals Purification of Polybutylene Terephthalate by Oligomer Removal Using a Compressed CO2 Antisolvent

Polymers ◽  
2019 ◽  
Vol 11 (7) ◽  
pp. 1230 ◽  
Author(s):  
Wen Yu ◽  
Jian-Hao Huang ◽  
Chung-Sung Tan
Keyword(s):  
Molecular Weight ◽  
Response Surface Methodology ◽  
Experimental Design ◽  
Operating Time ◽  
Operating Conditions ◽  
Low Molecular Weight ◽  
Polybutylene Terephthalate ◽  
Operating Variables ◽  
Cyclic Oligomers ◽  
Short Operating Time

In this study, the cyclic oligomers in the highly chemically resistant polyester polybutylene terephthalate (PBT) were effectively removed using a compressed CO2 antisolvent technique in which 1,1,1,3,3,3-hexafluoro-2-propanol (HFIP) was used as the solvent. In addition to the oligomers, tetrahydrofuran was completely removed because of its low molecular weight and liquid state. The effects of the operating variables, including temperature, pressure, and the PBT concentration in HFIP, on the degree of removal of the oligomers were systematically studied using experimental design and the response surface methodology. The most appropriate operating conditions for the purification of PBT were 8.3 MPa and 23.4 °C when using 4.5 wt % PBT in HFIP. Under these conditions, the cyclic trimers and dimers could be removed by up to 81.4% and 95.7%, respectively, in a very short operating time.

scholarly journals Dispersed phase hold-up and characteristic velocity in a pulsed packed extraction column

2012 ◽  
Vol 18 (2) ◽  
pp. 255-262 ◽  
Author(s):  
Mehdi Asadollahzadeh ◽  
Jaber Safdari ◽  
Ali Haghighi-Asl ◽  
Meisam Torab-Mostaedi
Keyword(s):  
Physical Properties ◽  
Packed Column ◽  
Operating Conditions ◽  
Empirical Correlation ◽  
Extraction Column ◽  
Dispersed Phase ◽  
Characteristic Velocity ◽  
Operating Variables ◽  
Liquid Systems ◽  
Good Agreement

Dispersed phase hold-up has been measured in a 76.2 mm diameter pulsed packed column for four different liquid-liquid systems. The effects of pulsation intensity, phase ratio, and packing characteristic on the hold-up have been investigated under a variety of operating conditions. The dispersed phase axial hold-up shows a strong non-uniformity, depending on the operating conditions. The results indicated that the characteristic velocity approach is applicable to this type of extraction column for analysis of hold-up. An empirical correlation is derived for prediction of the hold-up in terms of operating variables, physical properties of the systems, and packing geometry. Good agreement between prediction and experiments was observed for all investigated operating conditions.

Torque and Thrust Parameters in Drilling Using Dimensional Analysis

1980 ◽  
Vol 102 (1) ◽  
pp. 37-44 ◽  
Author(s):  
T. J. Roadinger ◽  
M. A. Townsend
Keyword(s):  
Strain Rate ◽  
Dimensional Analysis ◽  
Operating Conditions ◽  
Drilling Process ◽  
Materials Properties ◽  
Operating Variables ◽  
Dimensionless Groups ◽  
Independent Parameters ◽  
Similarity Laws ◽  
Drill Design

The application of dimensional analysis to the drilling process has provided relevant dimensionless groups for the prediction of torques and thrust and evaluating the influences of several operating variables. Drill design, operating conditions and various materials properties are considered. The applicable experimental procedures are thereby indicated to identify possible strain rate and/or speed effects. Similarity laws are established for large drills (over 1/2 inch diameter), although the same general forms are found for smaller drills. In conjunction with a mathematical analysis, strain rate and speed effects are found to be equivalent, but do not influence torque and thrust, other things being equal. The effects of pilot holes and point angle parameters are also investigated experimentally. The dimensional analysis-similarity approach allows hypothesizing various independent parameters and establishing their influences, if any. Experimental results here are compared with others’ data in terms of the dimensionless groups and are in general agreement.

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