scholarly journals An All-Solid-State Silicate Ion-Selective Electrode Using PbSiO3 as a Sensitive Membrane

Sensors ◽  
2019 ◽  
Vol 19 (3) ◽  
pp. 525
Author(s):  
Rongrong Wu ◽  
Xue-Gang Chen ◽  
Chunhui Tao ◽  
Yuanfeng Huang ◽  
Ying Ye ◽  
...  
Keyword(s):  
Solid State ◽  
Emerging Technology ◽  
In Situ Monitoring ◽  
Ion Selective Electrode ◽  
Aqueous Environment ◽  
Selective Electrode ◽  
Multiple Parameters ◽  
Potentiometric Response ◽  
Interfering Ions

Ion-Selective Electrode (ISE) is an emerging technology for in situ monitoring of the chemical concentrations of an aqueous environment. In this work, we reported a novel all-solid-state silicate ISE, using an Ag/Pb/PbSiO3 electrode. This electrode responded to aqueous SiO32− with a reasonable slope of −31.34 mV/decade and a good reproductivity. The linear range covered from 10−5 M to 10−1 M, for the Na2SiO3 solutions and the response time was generally less than 5 s. Its potentiometric response to pH and silicate indicated that the prepared electrode was sensitive to silicate, rather than pH. Compared to the traditional liquid ISE, our all-solid-state silicate electrode was resistant to high pressure and could be used in situ, in deep water. In addition, the miniaturized electrodes (diameter of 0.4 mm and a length of 2–3 cm) could be easily integrated into a multi-modal sensor, which could simultaneously determine multiple parameters. Our prepared silicate ISE could potentially be used to determine the presence of silicate in a low-chloride aqueous environment, where the ISE exhibited better selectivity for silicate, over interfering ions such as, SO42−, NO3−, CH3COO−, CO32−, and PO43−.

scholarly journals An All-Solid-State Nitrate Ion-Selective Electrode with Nanohybrids Composite Films for In-Situ Soil Nutrient Monitoring

Sensors ◽  
2020 ◽  
Vol 20 (8) ◽  
pp. 2270
Author(s):  
Ming Chen ◽  
Miao Zhang ◽  
Xuming Wang ◽  
Qingliang Yang ◽  
Maohua Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Composite Film ◽  
Composite Films ◽  
Influential Factors ◽  
Ion Selective Electrode ◽  
Selective Electrode ◽  
N Content ◽  
Detection Range ◽  
Electrochemically Reduced Graphene Oxide

In this paper, an all-solid-state nitrate doped polypyrrole (PPy(NO3−) ion-selective electrode (ISE) was prepared with a nanohybrid composite film of gold nanoparticles (AuNPs) and electrochemically reduced graphene oxide (ERGO). Preliminary tests on the ISE based in-situ soil nitrate–nitrogen (NO3−-N) monitoring was conducted in a laboratory 3-stage column. Comparisons were made between the NO3−-N content of in-situ soil percolate solution and laboratory-prepared extract solution. Possible influential factors of sample depth, NO3−-N content, soil texture, and moisture were varied. Field-emission scanning electron microscopy (FESEM) and X-ray powder diffraction (XRD) characterized morphology and content information of the composite film of ERGO/AuNPs. Due to the performance excellence for conductivity, stability, and hydrophobicity, the ISE with ERGO/AuNPs illustrates an acceptable detection range from 10−1 to 10−5 M. The response time was determined to be about 10 s. The lifetime was 65 days, which revealed great potential for the implementation of the ERGO/AuNPs mediated ISE for in-situ NO3−-N monitoring. In-situ NO3−-N testing results conducted by the all-solid-state ISE followed a similar trend with the standard UV-VIS method.

scholarly journals A novel chemical sensor with multiple all-solid-state electrodes and its application in freshwater environmental monitoring

2018 ◽  
Vol 78 (2) ◽  
pp. 432-440 ◽  
Author(s):  
Yifan Zhou ◽  
Luis Alejandro Mur ◽  
Arwyn Edwards ◽  
John Davies ◽  
Jiwan Han ◽  
...  
Keyword(s):  
Detection Limit ◽  
Solid State ◽  
Chemical Sensor ◽  
Dairy Farm ◽  
In Situ Monitoring ◽  
Multiple Parameters ◽  
Response Slope ◽  
Activity Measurements ◽  
Storage Demand

Abstract Freshwater quality detection is important for pollution control. Three important components of water quality are pH, ammonia and dissolved H2S and there is an urgent need for a high-precision sensor for simultaneous and continuous measurement. In this study, all-solid-state electrodes of Eh, pH, NH4+ and S2− were manufactured and mounted to a wireless chemical sensor with multiple parameters. Calibration indicated that the pH electrode had a Nernst response with slope of 53.174 mV; the NH4+ electrode had a detection limit of 10−5 mol/L (Nernst response slope of 53.56 mV between 10−1 to 10−4 mol/L). Ag/Ag2S has a detection limit of 10−7 mol/L (Nernst response slope of 28.439 mV). The sensor was cylindrical and small with low power consumption and low storage demand to achieve continuous in-situ monitoring for long periods. The sensor was tested for 10 days in streams at Trawsgoed Dairy farm in Aberystwyth, UK. At the intensively farmed Trawsgoed, the concentration of NH4+ in the stream rose sharply after the application of slurry to adjacent fields. Further, the stream was overhung with extensive vegetation and exhibited changes in pH, which correlated with photosynthetic activity. Measurements of S2− were stable throughout the week. Our data demonstrate the applicability of our multiple electrode sensor.

scholarly journals Ionic Liquid-Multiwalled Carbon Nanotubes Nanocomposite Based All Solid State Ion-Selective Electrode for the Determination of Copper in Water Samples

Water ◽  
2021 ◽  
Vol 13 (20) ◽  
pp. 2869
Author(s):  
Cecylia Wardak ◽  
Karolina Pietrzak ◽  
Małgorzata Grabarczyk
Keyword(s):  
Carbon Nanotubes ◽  
Ionic Liquid ◽  
Solid State ◽  
Multiwalled Carbon Nanotubes ◽  
Water Samples ◽  
Limit Of Detection ◽  
Ion Selective Electrode ◽  
Selective Electrode ◽  
Multiwalled Carbon ◽  
Copper Determination

A new copper sensitive all solid-state ion-selective electrode was prepared using multiwalled carbon nanotubes-ionic liquid (1-butyl-3-methylimidazolium hexafluorophosphate) nanocomposite as an additional membrane component. The effect of nanocomposite content in the membrane on the electrode parameters was investigated. The study compares, among others, detection limits, sensitivity, and the linearity ranges of calibration curves. Content 6 wt.% was considered optimal for obtaining an electrode with a Nernstian response of 29.8 mV/decade. An electrode with an optimal nanocomposite content in the membrane showed a lower limit of detection, a wider linear range and pH range, as well as better selectivity and potential stability compared to the unmodified electrode. It was successfully applied for copper determination in real water samples.

Determination of Iodide in Feeds and Plants by Ion-Selective Electrode Analysis

1971 ◽  
Vol 54 (4) ◽  
pp. 760-763
Author(s):  
William L Hoover ◽  
James R Melton ◽  
Peggy A Howard
Keyword(s):  
Ionic Strength ◽  
Solid State ◽  
Necessary Conditions ◽  
Ion Selective Electrode ◽  
Phosphate Solution ◽  
Selective Electrode ◽  
Aoac Method ◽  
Low Levels ◽  
High Concentrations

Abstract A method for determining low levels of iodide in feeds and plants is proposed. The samples are mixed with a 10% phosphate solution to maintain relatively constant ionic strength and pH and analyzed with a solid-state iodide electrode. Ashing is not required and there are no significant interferences by ions commonly found in feeds. The method is accurate in determining iodide content ranging from 10.0 ppm to high concentrations. Necessary conditions for storing and cleaning the electrodes are described. The proposed method is rapid and results compare favorably with AOAC method 7.091.

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