scholarly journals Preparation of Flame-Retardant Polyurethane and Its Applications in the Leather Industry

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1730
Author(s):  
Shaolin Lu ◽  
Yechang Feng ◽  
Peikun Zhang ◽  
Wei Hong ◽  
Yi Chen ◽  
...  

As a novel polymer, polyurethane (PU) has been widely applied in leather, synthetic leather, and textiles due to its excellent overall performance. Nevertheless, conventional PU is flammable and its combustion is accompanied by severe melting and dripping, which then generates hazardous fumes and gases. This defect limits PU applications in various fields, including the leather industry. Hence, the development of environmentally friendly, flame-retardant PU is of great significance both theoretically and practically. Currently, phosphorus-nitrogen (P-N) reactive flame-retardant is a hot topic in the field of flame-retardant PU. Based on this, the preparation and flame-retardant mechanism of flame-retardant PU, as well as the current status of flame-retardant PU in the leather industry were reviewed.

2022 ◽  
Vol 10 (5) ◽  
pp. 1349-1364
Author(s):  
Li Wang ◽  
Rongbai Tong ◽  
Juanli Wang ◽  
Jintao Wan ◽  
Yuhu Li ◽  
...  

2010 ◽  
Vol 10 (11) ◽  
pp. 7374-7377 ◽  
Author(s):  
Cevdet Kaynak ◽  
Huseyin Ozgur Gunduz ◽  
Nihat Ali Isitman

e-Polymers ◽  
2019 ◽  
Vol 19 (1) ◽  
pp. 545-554 ◽  
Author(s):  
Anxin Li ◽  
Pingli Mao ◽  
Bing Liang

AbstractIn order to improve the compatibility of flame retardant and epoxy resin, a phosphorus nitrogen flame retardant curing agent poly(p-xylylenediamine spirocyclic pentaerythritol bisphosphonate) (PPXSPB) was synthesized. FTIR, 1HNMR, and mass spectroscopy were used to identify the chemical structure of PPXSPB. Epoxy resin (E-44) and PPXSPB as the raw material, a series of thermosetting systems were prepared. The effects of PPXSPB on flame retardancy, water resistance, thermal degradation behavior, mechanical properties and the adhesive strength of EP/PPXSPB thermosets were investigated. The results show that with the increase of phosphorus content, the oxygen index and carbon residue of the system both increased significantly, and the heat release rate gradually decreased, which is of great significance in delaying the occurrence of fire. When the phosphorus content is 3.24% in EP/PPXSPB thermosets, EP-2 can successfully pass the UL94 V-0 flammability rating, the LOI value of EP-2 can reach 31.4%, the impact strength and tensile strength was 6.58 kJ/m2 and 47.10 MPa respectively, and the adhesive strength was 13.79 MPa, the system presents a good overall performance.


2020 ◽  
Vol 55 (27) ◽  
pp. 12836-12847 ◽  
Author(s):  
Zongmin Zhu ◽  
Panlong Lin ◽  
Hao Wang ◽  
Luoxin Wang ◽  
Bin Yu ◽  
...  

2020 ◽  
Vol 190 ◽  
pp. 107926 ◽  
Author(s):  
Jingkai Liu ◽  
Jinyue Dai ◽  
Shuaipeng Wang ◽  
Yunyan Peng ◽  
Lijun Cao ◽  
...  

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