scholarly journals The Investigation of the Seebeck Effect of the Poly(3,4-Ethylenedioxythiophene)-Tosylate with the Various Concentrations of an Oxidant

Polymers ◽  
2018 ◽  
Vol 11 (1) ◽  
pp. 21 ◽  
Author(s):  
Joon-Soo Kim ◽  
Woongsik Jang ◽  
Dong Wang
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Power Factor ◽  
In Situ Polymerization ◽  
Seebeck Effect ◽  
Particle Sizes ◽  
Seebeck Coefficients ◽  
Optimal Power ◽  
Electrical Conductivities

Poly(3,4-ethylenedioxythiophene)-tosylate (PEDOT-Tos) can be synthesized through an in situ polymerization and doping process with iron(III) p-toluenesulfonate hexahydrate as an oxidant. Both the Seebeck coefficient and the electrical conductivity were modified by varying the concentration of the oxidant. We investigated the effects of varying the concentration of the oxidant on the particle sizes and doping (oxidation) levels of PEDOT-Tos for thermoelectric applications. We demonstrated that an increase in the oxidant enabled an expansion of the particle sizes and the doping levels of the PEDOT-Tos. The modification of the doping levels by the concentration of the oxidant can provide another approach for having an optimal power factor for thermoelectric applications. De-doping of PEDOTs by reduction agents has been generally investigated for changing its oxidation levels. In this study, we investigated the effect of the concentration of the oxidant of PEDOT-Tos on the oxidation levels, the electrical conductivities and the Seebeck coefficients. As loading the oxidant of PEDOT-Tos, the Seebeck coefficient was compromised, while the electrical conductivity increased.

scholarly journals Preparation and Thermoelectric Properties of Graphite/poly(3,4-ethyenedioxythiophene) Nanocomposites

Energies ◽  
2018 ◽  
Vol 11 (10) ◽  
pp. 2849 ◽  
Author(s):  
Yong Du ◽  
Haixia Li ◽  
Xuechen Jia ◽  
Yunchen Dou ◽  
Jiayue Xu ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Thermoelectric Properties ◽  
Power Factor ◽  
Oxidative Polymerization ◽  
Polymerization Process ◽  
Measurement Temperature ◽  
Temperature Range ◽  
Different Content

Graphite/poly(3,4-ethyenedioxythiophene) (PEDOT) nanocomposites were prepared by an in-situ oxidative polymerization process. The electrical conductivity and Seebeck coefficient of the graphite/PEDOT nanocomposites with different content of graphite were measured in the temperature range from 300 K to 380 K. The results show that as the content of graphite increased from 0 to 37.2 wt %, the electrical conductivity of the nanocomposites increased sharply from 3.6 S/cm to 80.1 S/cm, while the Seebeck coefficient kept almost the same value (in the range between 12.0 μV/K to 15.1 μV/K) at 300 K, which lead to an increased power factor. The Seebeck coefficient of the nanocomposites increased from 300 K to 380 K, while the electrical conductivity did not substantially depend on the measurement temperature. As a result, a power factor of 3.2 μWm−1 K−2 at 380 K was obtained for the nanocomposites with 37.2 wt % graphite.

scholarly journals Nitrogen-Doped Carbon Nanotube/Polypropylene Composites with Negative Seebeck Coefficient

2020 ◽  
Vol 4 (1) ◽  
pp. 14 ◽  
Author(s):  
Beate Krause ◽  
Ioannis Konidakis ◽  
Mohammad Arjmand ◽  
Uttandaraman Sundararaj ◽  
Robert Fuge ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Power Factor ◽  
Transient Absorption ◽  
Transient Absorption Spectroscopy ◽  
Polypropylene Composites ◽  
Nitrogen Doped ◽  
Seebeck Coefficients ◽  
Multi Walled Carbon Nanotubes ◽  
Nitrogen Doped Carbon

This study describes the application of multi-walled carbon nanotubes that were nitrogen-doped during their synthesis (N-MWCNTs) in melt-mixed polypropylene (PP) composites. Different types of N-MWCNTs, synthesized using different methods, were used and compared. Four of the five MWCNT grades showed negative Seebeck coefficients (S), indicating n-type charge carrier behavior. All prepared composites (with a concentration between 2 and 7.5 wt% N-MWCNTs) also showed negative S values, which in most cases had a higher negative value than the corresponding nanotubes. The S values achieved were between 1.0 μV/K and −13.8 μV/K for the N-MWCNT buckypapers or powders and between −4.7 μV/K and −22.8 μV/K for the corresponding composites. With a higher content of N-MWCNTs, the increase in electrical conductivity led to increasing values of the power factor (PF) despite the unstable behavior of the Seebeck coefficient. The highest power factor was achieved with 4 wt% N-MWCNT, where a suitable combination of high electrical conductivity and acceptable Seebeck coefficient led to a PF value of 6.1 × 10−3 µW/(m·K2). First experiments have shown that transient absorption spectroscopy (TAS) is a useful tool to study the carrier transfer process in CNTs in composites and to correlate it with the Seebeck coefficient.

scholarly journals Boosting the Power Factor of Benzodithiophene Based Donor–Acceptor Copolymers/SWCNTs Composites through Doping

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1447
Author(s):  
Zhongming Chen ◽  
Mengfei Lai ◽  
Lirong Cai ◽  
Wenqiao Zhou ◽  
Dexun Xie ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Power Factor ◽  
Room Temperature ◽  
Composite Films ◽  
Side Chain ◽  
Seebeck Coefficients ◽  
Electrical Conductivities ◽  
Before And After ◽  
Donor Acceptor ◽  
Walled Carbon Nanotubes

In this study, a benzodithiophene (BDT)-based donor (D)–acceptor (A) polymer containing carbazole segment in the side-chain was designed and synthesized and the thermoelectric composites with 50 wt % of single walled carbon nanotubes (SWCNTs) were prepared via ultrasonication method. Strong interfacial interactions existed in both of the composites before and after immersing into the 2,3,5,6-Tetrafluoro-7,7,8,8-tetracyanoquinodimethane (F4TCNQ) solution as confirmed by UV-Vis-NIR, Raman, XRD and SEM characterizations. After doping the composites by F4TCNQ, the electrical conductivity of the composites increased from 120.32 S cm−1 to 1044.92 S cm−1 in the room temperature. With increasing the temperature, the electrical conductivities and Seebeck coefficients of the undoped composites both decreased significantly for the composites; the power factor at 475 K was only 6.8 μW m−1 K−2, which was about nine times smaller than the power factor at room temperature (55.9 μW m−1 K−2). In the case of doped composites, although the electrical conductivity was deceased from 1044.9 S cm−1 to 504.17 S cm−1, the Seebeck coefficient increased from 23.76 μV K−1 to 35.69 μW m−1 K−2, therefore, the power factors of the doped composites were almost no change with heating the composite films.

scholarly journals Formation and Evaluation of Silicon Substrate with Highly-Doped Porous Si Layers Formed by Metal-Assisted Chemical Etching

2021 ◽  
Vol 16 (1) ◽  
Author(s):  
Yijie Li ◽  
Nguyen Van Toan ◽  
Zhuqing Wang ◽  
Khairul Fadzli Bin Samat ◽  
Takahito Ono
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Contact Resistance ◽  
Power Factor ◽  
Chemical Etching ◽  
Porous Si ◽  
Si Substrate ◽  
Si Substrates ◽  
Output Performance ◽  
Metal Assisted Chemical Etching

AbstractPorous silicon (Si) is a low thermal conductivity material, which has high potential for thermoelectric devices. However, low output performance of porous Si hinders the development of thermoelectric performance due to low electrical conductivity. The large contact resistance from nonlinear contact between porous Si and metal is one reason for the reduction of electrical conductivity. In this paper, p- and n-type porous Si were formed on Si substrate by metal-assisted chemical etching. To decrease contact resistance, p- and n-type spin on dopants are employed to dope an impurity element into p- and n-type porous Si surface, respectively. Compared to the Si substrate with undoped porous samples, ohmic contact can be obtained, and the electrical conductivity of doped p- and n-type porous Si can be improved to 1160 and 1390 S/m, respectively. Compared with the Si substrate, the special contact resistances for the doped p- and n-type porous Si layer decreases to 1.35 and 1.16 mΩ/cm2, respectively, by increasing the carrier concentration. However, the increase of the carrier concentration induces the decline of the Seebeck coefficient for p- and n-type Si substrates with doped porous Si samples to 491 and 480 μV/K, respectively. Power factor is related to the Seebeck coefficient and electrical conductivity of thermoelectric material, which is one vital factor that evaluates its output performance. Therefore, even though the Seebeck coefficient values of Si substrates with doped porous Si samples decrease, the doped porous Si layer can improve the power factor compared to undoped samples due to the enhancement of electrical conductivity, which facilitates its development for thermoelectric application.

Measuring transient solute transport through the vadoze zone using time domain reflectometry

Soil Research ◽  
2001 ◽  
Vol 39 (6) ◽  
pp. 1359 ◽  
Author(s):  
I. Vogeler ◽  
S. Green ◽  
A. Nadler ◽  
C. Duwig
Keyword(s):  
Electrical Conductivity ◽  
Solute Transport ◽  
Time Domain ◽  
Deterministic Model ◽  
Soil Surface ◽  
Time Domain Reflectometry ◽  
Richards Equation ◽  
Electrical Conductivities ◽  
Destructive Measurement

Time domain reflectometry (TDR) was used to monitor the transport of conservative tracers in the field under transient water flow in a controlled experiment under a kiwifruit vine. A mixed pulse of chloride and bromide was applied to the soil surface of a 16 m2 plot that had been isolated from the surrounding orchard soil. The movement of this solute pulse was monitored by TDR. A total of 63 TDR probes were installed into the plot for daily measurements of both the volumetric water content (θ) and the bulk soil electrical conductivity (σa). These TDR-measured σa were converted into pore water electrical conductivities (σw) and solute concentrations using various θ–σa–σw relationships that were established in the laboratory on repacked soil. The depth-wise field TDR measurements were compared with destructive measurement of the solute concentrations at the end of the experiment. These results were also compared with predictions using a deterministic model of water and solute transport based on Richards’ equation, and the convection–dispersion equation. TDR was found to give a good indication of the shape of the solute profile with depth, but the concentration of solute was under- or over-estimated by up to 50%, depending on the θ–σa–σw relationships used. Thus TDR can be used to monitor in situ transport of contaminants. However, only rough estimates of the electrical conductivity of the soil solution can so far be obtained by TDR.

Critical role of nanoinclusions in silver selenide nanocomposites as a promising room temperature thermoelectric material

2019 ◽  
Vol 7 (9) ◽  
pp. 2646-2652 ◽  
Author(s):  
Khak Ho Lim ◽  
Ka Wai Wong ◽  
Yu Liu ◽  
Yu Zhang ◽  
Doris Cadavid ◽  
...  
Keyword(s):  
Seebeck Coefficient ◽  
Room Temperature ◽  
Opposite Effect ◽  
Critical Role ◽  
Free Carrier ◽  
Silver Selenide ◽  
Band Bending ◽  
Seebeck Coefficients ◽  
Electrical Conductivities

The introduction of nonmetal nanoinclusions within Ag2Se results in an interphase band bending that promotes electron filtering and increase Seebeck coefficient. Similar loading of metal nanoinclusions provided an opposite effect-modulating free carrier concentration, as characterized by superior electrical conductivities and lower Seebeck coefficients.

scholarly journals Annealing Effect on the Thermoelectric Properties of Bi2Te3Thin Films Prepared by Thermal Evaporation Method

2013 ◽  
Vol 2013 ◽  
pp. 1-6 ◽  
Author(s):  
Jyun-Min Lin ◽  
Ying-Chung Chen ◽  
Chi-Pi Lin
Keyword(s):  
Thin Films ◽  
Seebeck Coefficient ◽  
Thermoelectric Properties ◽  
Power Factor ◽  
Room Temperature ◽  
Annealing Temperature ◽  
Thermal Evaporation ◽  
Thermal Evaporation Method ◽  
Si Substrates ◽  
Seebeck Coefficients

Bismuth telluride-based compounds are known to be the best thermoelectric materials within room temperature region, which exhibit potential applications in cooler or power generation. In this paper, thermal evaporation processes were adopted to fabricate the n-type Bi2Te3thin films on SiO2/Si substrates. The influence of thermal annealing on the microstructures and thermoelectric properties of Bi2Te3thin films was investigated in temperature range 100–250°C. The crystalline structures and morphologies were characterized by X-ray diffraction and field emission scanning electron microscope analyses. The Seebeck coefficients, electrical conductivity, and power factor were measured at room temperature. The experimental results showed that both the Seebeck coefficient and power factor were enhanced as the annealing temperature increased. When the annealing temperature increased to 250°C for 30 min, the Seebeck coefficient and power factor of n-type Bi2Te3-based thin films were found to be about −132.02 μV/K and 6.05 μW/cm·K2, respectively.

scholarly journals Influence of crystallinity on the thermoelectric power factor of P3HT vapour-doped with F4TCNQ

RSC Advances ◽  
2018 ◽  
Vol 8 (3) ◽  
pp. 1593-1599 ◽  
Author(s):  
Jonna Hynynen ◽  
David Kiefer ◽  
Christian Müller
Keyword(s):  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Thermoelectric Power ◽  
Power Factor ◽  
Thermoelectric Power Factor ◽  
Order Of Magnitude

The crystallinity of P3HT strongly benefits the electrical conductivity but not Seebeck coefficient, leading to an increase in power factor by one order of magnitude.

Carbon nanotubes enhanced Seebeck coefficient and power factor of rutile TiO2

2015 ◽  
Vol 17 (12) ◽  
pp. 8120-8124 ◽  
Author(s):  
Yao-Cheng Lai ◽  
Hsin-Jung Tsai ◽  
Chia-I Hung ◽  
Hiroyuki Fujishiro ◽  
Tomoyuki Naito ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Seebeck Coefficient ◽  
Power Factor ◽  
Filling Fraction ◽  
Rutile Tio2

Ti–C substitution occurs when carbon nanotubes were thermally dispersed in rutile TiO2 and the electrical conductivity as well as Seebeck coefficient were simultaneously promoted at a low filling fraction of tubes.

Preparation of Polyaniline @ Polypyrrole Conductive Composite via In Situ Polymerization

2013 ◽  
Vol 562-565 ◽  
pp. 1137-1142
Author(s):  
Hui Xia Feng ◽  
Bing Wang ◽  
Lin Tan ◽  
Na Li Chen
Keyword(s):  
Electron Microscopy ◽  
Electrical Conductivity ◽  
Scanning Electron Microscopy ◽  
Fourier Transform ◽  
In Situ Polymerization ◽  
Conductive Composite ◽  
The Core ◽  
Novel Method ◽  
Scanning Electron

We prepared the polyaniline@polypyrrole (PAn@PPy) conductive composite by a novel method. The struction like Pre-prepared PAn as the core and PPy as the shell for the composite has been prepared by in-situ polymerization. The PAn@PPy conductive composite presents an electrical conductivity of 12.5 S/cm, which is much higher than pure PAn. The synthesized polymer composites are characterized by Fourier Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM) and Thermogravimetric analysis (TG). The results indicated that PPy successfully grafted on PAn and the heat resistance of nanocomposite is remarkably increased.

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