scholarly journals Study of a Novel Gemini Viscoelastic Surfactant with High Performance in Clean Fracturing Fluid Application

Polymers ◽  
2018 ◽  
Vol 10 (11) ◽  
pp. 1215 ◽  
Author(s):  
Wenlong Zhang ◽  
Jincheng Mao ◽  
Xiaojiang Yang ◽  
Heng Zhang ◽  
Zhaoyang Zhang ◽  
...  
Keyword(s):  
Shear Rate ◽  
Hydraulic Fracturing ◽  
Secondary Amine ◽  
High Performance ◽  
Critical Micellar Concentration ◽  
Organic Salt ◽  
Core Flooding ◽  
Fracturing Fluid ◽  
Flexible Polymer ◽  
Viscoelastic Surfactant

Gemini surfactant, as a functionally flexible polymer-like material in the aqueous solution, has attracted increased attention in reservoir stimulation of hydraulic fracturing in recent decades. A new Gemini cationic viscoelastic surfactant named JS-N-JS, which has a secondary amine spacer group and two ultra-long hydrophobic tails, was synthesized from erucamidopropyl dimethylamine, diethanolamine, and thionyl chloride as a thickener for hydraulic fracturing fluid. Compared with some Gemini cationic surfactant with methylene spacer, JS-N-JS showed a lower critical micellar concentration (CMC) and higher surface activity due to the hydrogen bond formed between the secondary amine and water molecule intends to reduce electrostatic repulsion, which is more beneficial to be the fracturing fluid thickener. Moreover, the performance of JS-N-JS solution can be further improved by salts of potassium chloride (KCl) or sodium salicylate (NaSal), while organic salt behaved better according to the measurements. The SEM observation confirmed that JS-N-JS/NaSal system owned a tighter network microstructure, and JS-N-JS/NaSal system exhibited a distinct superior viscoelasticity system at a sweep frequency of 0.1–10 Hz. As a fracturing fluid, the solution with a formula of 30 mmol JS-N-JS and 100 mmol NaSal was evaluated according to the petroleum industrial standard and presented excellent viscoelastic properties, the viscosity of which can maintain above 70 mPa·s for 110 min under a shear rate of 170 s−1 at 120 °C. Meanwhile, the drag reducing rate of the formula could reach above 70% with the increase of shear rate. Finally, the viscous fracturing fluid can be broken into the water-like fluid in 1.2 h after being fully exposed to hydrocarbons and the water-like fluid presented a low damage to the tight sand reservoirs according to the core flooding experiments, in which the permeability recovery rate can reach 85.05%. These results fully demonstrate that the JS-N-JS solution fully meets the requirement of the industrial application of hydraulic fracturing.

scholarly journals Experimental Investigation and Performance Evaluation of Modified Viscoelastic Surfactant (VES) as a New Thickening Fracturing Fluid

Polymers ◽  
2020 ◽  
Vol 12 (7) ◽  
pp. 1470
Author(s):  
Z. H. Chieng ◽  
Mysara Eissa Mohyaldinn ◽  
Anas. M. Hassan ◽  
Hans Bruining
Keyword(s):  
Shear Rate ◽  
Hydraulic Fracturing ◽  
Shear Resistance ◽  
Core Flooding ◽  
Single Chain ◽  
Fracturing Fluid ◽  
The Core ◽  
Core Damage ◽  
Fracturing Fluids ◽  
Viscoelastic Surfactant

In hydraulic fracturing, fracturing fluids are used to create fractures in a hydrocarbon reservoir throughout transported proppant into the fractures. The application of many fields proves that conventional fracturing fluid has the disadvantages of residue(s), which causes serious clogging of the reservoir’s formations and, thus, leads to reduce the permeability in these hydrocarbon reservoirs. The development of clean (and cost-effective) fracturing fluid is a main driver of the hydraulic fracturing process. Presently, viscoelastic surfactant (VES)-fluid is one of the most widely used fracturing fluids in the hydraulic fracturing development of unconventional reservoirs, due to its non-residue(s) characteristics. However, conventional single-chain VES-fluid has a low temperature and shear resistance. In this study, two modified VES-fluid are developed as new thickening fracturing fluids, which consist of more single-chain coupled by hydrotropes (i.e., ionic organic salts) through non-covalent interaction. This new development is achieved by the formulation of mixing long chain cationic surfactant cetyltrimethylammonium bromide (CTAB) with organic acids, which are citric acid (CA) and maleic acid (MA) at a molar ratio of (3:1) and (2:1), respectively. As an innovative approach CTAB and CA are combined to obtain a solution (i.e., CTAB-based VES-fluid) with optimal properties for fracturing and this behaviour of the CTAB-based VES-fluid is experimentally corroborated. A rheometer was used to evaluate the visco-elasticity and shear rate & temperature resistance, while sand-carrying suspension capability was investigated by measuring the settling velocity of the transported proppant in the fluid. Moreover, the gel breaking capability was investigated by determining the viscosity of broken VES-fluid after mixing with ethanol, and the degree of core damage (i.e., permeability performance) caused by VES-fluid was evaluated while using core-flooding test. The experimental results show that, at pH-value ( 6.17 ), 30 (mM) VES-fluid (i.e., CTAB-CA) possesses the highest visco-elasticity as the apparent viscosity at zero shear-rate reached nearly to 10 6 (mPa·s). Moreover, the apparent viscosity of the 30 (mM) CTAB-CA VES-fluid remains 60 (mPa·s) at (90 ∘ C) and 170 (s − 1 ) after shearing for 2-h, indicating that CTAB-CA fluid has excellent temperature and shear resistance. Furthermore, excellent sand suspension and gel breaking ability of 30 (mM) CTAB-CA VES-fluid at 90 ( ∘ C) was shown; as the sand suspension velocity is 1.67 (mm/s) and complete gel breaking was achieved within 2 h after mixing with the ethanol at the ratio of 10:1. The core flooding experiments indicate that the core damage rate caused by the CTAB-CA VES-fluid is ( 7.99 % ), which indicate that it does not cause much damage. Based on the experimental results, it is expected that CTAB-CA VES-fluid under high-temperature will make the proposed new VES-fluid an attractive thickening fracturing fluid.

Laboratory Study and Evaluation on a Novel Clearfrac Fluid System

2012 ◽  
Vol 488-489 ◽  
pp. 133-136
Author(s):  
Shuang Fei Zhong ◽  
Fu Jian Liu ◽  
Dong Xu Li
Keyword(s):  
Hydraulic Fracturing ◽  
Oil And Gas ◽  
Water Injection ◽  
The Novel ◽  
Fracturing Fluid ◽  
Fluid System ◽  
Effective Measure ◽  
Temperature Resistance ◽  
Well Production ◽  
Viscoelastic Surfactant

Hydraulic fracturing is an effective measure to recover the permeabilityof reservoir and important to enhance oil and gas well production and water injection well. Fracturing fluid is the key factor in the fracture treatments. At present, water-based fracturing fluids are popular, because of low costs and steady performance, which has the largest applications. However, it performs badly in residue. The novel developed clearfrac fluid system named CF1 has lowresidue, cost affectivity, prior temperature resistance properties. Evaluation through a series of lab experiments, the experiments result show that the novel clearfrac fluid system can satisfy with the requirement of low damage and have favorable temperature resistance under 120 。C. The damage to the core matrix due to with the broken frac-fluid is low. Prior properties of the novel clear-fracturing fluid are suitable to high temperature and high pressure reservoirs. It is also a novel environmental friendly viscoelastic surfactant fracturing fluid. The development of the novel clear-fracturing fluid for hydraulic fracturing industry is significant.

scholarly journals Laboratory Testing of Fracture Conductivity Damage by Foam-Based Fracturing Fluids in Low Permeability Tight Gas Formations

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1783
Author(s):  
Klaudia Wilk-Zajdel ◽  
Piotr Kasza ◽  
Mateusz Masłowski
Keyword(s):  
Hydraulic Fracturing ◽  
Guar Gum ◽  
Polymer Concentration ◽  
Laboratory Research ◽  
Damage Effect ◽  
Tight Gas ◽  
Fracturing Fluid ◽  
Fracture Conductivity ◽  
Fracturing Fluids ◽  
Sandstone Rock

In the case of fracturing of the reservoirs using fracturing fluids, the size of damage to the proppant conductivity caused by treatment fluids is significant, which greatly influence the effective execution of hydraulic fracturing operations. The fracturing fluid should be characterized by the minimum damage to the conductivity of a fracture filled with proppant. A laboratory research procedure has been developed to study the damage effect caused by foamed and non-foamed fracturing fluids in the fractures filled with proppant material. The paper discusses the results for high quality foamed guar-based linear gels, which is an innovative aspect of the work compared to the non-foamed frac described in most of the studies and simulations. The tests were performed for the fracturing fluid based on a linear polymer (HPG—hydroxypropyl guar, in liquid and powder form). The rheology of nitrogen foamed-based fracturing fluids (FF) with a quality of 70% was investigated. The quartz sand and ceramic light proppant LCP proppant was placed between two Ohio sandstone rock slabs and subjected to a given compressive stress of 4000–6000 psi, at a temperature of 60 °C for 5 h. A significant reduction in damage to the quartz proppant was observed for the foamed fluid compared to that damaged by the 7.5 L/m3 natural polymer-based non-foamed linear fluid. The damage was 72.3% for the non-foamed fluid and 31.5% for the 70% foamed fluid, which are superior to the guar gum non-foamed fracturing fluid system. For tests based on a polymer concentration of 4.88 g/L, the damage to the fracture conductivity by the non-foamed fluid was 64.8%, and 26.3% for the foamed fluid. These results lead to the conclusion that foamed fluids could damage the fracture filled with proppant much less during hydraulic fracturing treatment. At the same time, when using foamed fluids, the viscosity coefficient increases a few times compared to the use of non-foamed fluids, which is necessary for proppant carrying capacities and properly conducted stimulation treatment. The research results can be beneficial for optimizing the type and performance of fracturing fluid for hydraulic fracturing in tight gas formations.

Optimization on Fracturing Fluid Flowback Model after Hydraulic Fracturing in Oil Well

2021 ◽  
pp. 108703
Author(s):  
Zhanqing Qu ◽  
Jiwei Wang ◽  
Tiankui Guo ◽  
Lin Shen ◽  
Hualin Liao ◽  
...  
Keyword(s):  
Hydraulic Fracturing ◽  
Oil Well ◽  
Fracturing Fluid

scholarly journals Performance Evaluation of Enzyme Breaker for Fracturing Applications under Simulated Reservoir Conditions

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3133
Author(s):  
Yuling Meng ◽  
Fei Zhao ◽  
Xianwei Jin ◽  
Yun Feng ◽  
Gangzheng Sun ◽  
...  
Keyword(s):  
Hydraulic Fracturing ◽  
Shear Resistance ◽  
Ammonium Persulfate ◽  
Fracturing Fluid ◽  
Medium Temperature ◽  
Fracture Conductivity ◽  
Wide Range ◽  
Reservoir Conditions ◽  
Alkaline Conditions ◽  
Resistance Performance

Fracturing fluids are being increasingly used for viscosity development and proppant transport during hydraulic fracturing operations. Furthermore, the breaker is an important additive in fracturing fluid to extensively degrade the polymer mass after fracturing operations, thereby maximizing fracture conductivity and minimizing residual damaging materials. In this study, the efficacy of different enzyme breakers was examined in alkaline and medium-temperature reservoirs. The parameters considered were the effect of the breaker on shear resistance performance and sand-suspending performance of the fracturing fluid, its damage to the reservoir after gel breaking, and its gel-breaking efficiency. The experimental results verified that mannanase II is an enzyme breaker with excellent gel-breaking performance at medium temperatures and alkaline conditions. In addition, mannanase II did not adversely affect the shear resistance performance and sand-suspending performance of the fracturing fluid during hydraulic fracturing. For the same gel-breaking result, the concentration of mannanase II used was only one fifth of other enzyme breakers (e.g., mannanase I, galactosidase, and amylase). Moreover, the amount of residue and the particle size of the residues generated were also significantly lower than those of the ammonium persulfate breaker. Finally, we also examined the viscosity-reducing capability of mannanase II under a wide range of temperatures (104–158 °F) and pH values (7–8.5) to recommend its best-use concentrations under different fracturing conditions. The mannanase has potential for applications in low-permeability oilfield development and to maximize long-term productivity from unconventional oilwells.

Environmental impact and treatment of hydraulic fracturing in shale gas

2021 ◽  
Author(s):  
Heng Wang ◽  
Lifa Zhou
Keyword(s):  
Surface Water ◽  
High Risk ◽  
Water Resources ◽  
Hydraulic Fracturing ◽  
Environmental Impacts ◽  
Shale Gas ◽  
Pollution Sources ◽  
Fracturing Fluid ◽  
Geological Disasters ◽  
Surface Water And Groundwater

<p>Hydraulic fracturing is one of the key technologies to stimulate shale gas production and may have some environmental impacts while enhancing shale gas development. Through the introduction of hydraulic fracturing technology from the design and construction aspects, analysis of its potential adverse environmental impacts in water resource consumption, surface water and groundwater pollution, geological disasters, and other aspects, and based on the existing problems to form targeted solutions.</p><p>According to EIA report, during the stimulation process of shale gas fracturing, the amount of water resources is about 10,000m<sup>3</sup>, of which 20%-80% can be returned, and the flowback rate of Shale gas in China is 20%-60%, which means that at least 20%-40% polluted water containing various chemical raw materials will be hidden in the formation for a long time. The shale flowback rate in China is significantly lower than that in the United States, not only due to formation conditions, but also due to equipment and technology. In view of this situation, it is necessary to control the whole process from design to construction.</p><p>In the design process of hydraulic fracturing of shale gas, real-time control of the fracture range is carried out in conjunction with seismic monitoring and software simulation fitting, so as to reduce the consumption of water resources on the premise of achieving the purpose of increasing production. Especially, to reducing the fracturing program as much as possible in the water-scarce areas, so as to ensure the security of public water resources. Reduce the use of chemical additives to alleviate the pollution of surface water and groundwater. After detection of possible pollution, determine the amount of pollution sources on site and carry out comprehensive pollutant recovery and treatment. Strictly prohibit high-risk pollution sources from entering the fracturing fluid process. At the same time, the fracturing fluid is used to recycled and purified. In terms of geological disasters caused by fracturing, high-risk geological disaster zones should be identified and monitored in advance to prevent large-scale geological activities caused by micro-earthquakes caused by fracturing from causing uncontrollable geological disasters.</p>

Application of Heat Treatment to Prevent Fracturing Fluid-Induced Formation Damage and Enhance Matrix Permeability in Shale Gas Reservoirs

2021 ◽  
Author(s):  
Mingjun Chen ◽  
Peisong Li ◽  
Yili Kang ◽  
Xinping Gao ◽  
Dongsheng Yang ◽  
...  
Keyword(s):  
Heat Treatment ◽  
Hydraulic Fracturing ◽  
Shale Gas ◽  
Gas Transport ◽  
Formation Damage ◽  
Transport Capacity ◽  
Fracturing Fluid ◽  
Gas Reservoir ◽  
Shale Gas Reservoir ◽  
The Matrix

Abstract The low flowback efficiency of fracturing fluid would severely increase water saturation in a near-fracture formation and limit gas transport capacity in the matrix of a shale gas reservoir. Formation heat treatment (FHT) is a state-of-the-art technology to prevent water blocking induced by fracturing fluid retention and accelerate gas desorption and diffusion in the matrix. A comprehensive understanding of its formation damage removal mechanisms and determination of production improvement is conducive to enhancing shale gas recovery. In this research, the FHT simulation experiment was launched to investigate the effect of FHT on gas transport capacity, the multi-field coupling model was established to determine the effective depth of FHT, and the numerical simulation model of the shale reservoir was established to analyze the feasibility of FHT. Experimental results show that the shale permeability and porosity were rising overall during the FHT, the L-1 permeability increased by 30- 40 times, the L-2 permeability increased by more than 100 times. The Langmuir pressure increased by 1.68 times and the Langmuir volume decreased by 26%, which means the methane desorption efficiency increased. Results of the simulation demonstrate that the FHT process can practically improve the effect of hydraulic fracturing and significantly increase the well production capacity. The stimulation mechanisms of the FHT include thermal stress cracking, organic matter structure changing, and aqueous phase removal. Furthermore, the special characteristics of the supercritical water such as the strong oxidation, can not be ignored, due to the FHT can assist the retained hydraulic fracturing fluid to reach the critical temperature and pressure of water and transform to the supercritical state. The FHT can not only alleviate the formation damage induced by the fracturing fluid, but also make good use of the retained fracturing fluid to enhance the permeability of a shale gas reservoir, which is an innovative method to dramatically enhance gas transport capacity in shale matrix.

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