Is High Viscosity a Requirement for Fracturing Fluids?

Uniformly distributing proppant inside fractures with low damage on fracture conductivity is the most important index of successful fracturing fluids. However, due to very low proppant suspension capacity of slickwater and friction reducers fracturing fluids and longer fracture closure time in nano & pico darcies formations, proppants settles quickly and accumulates near wellbore resulting in worse-than-expected well performance, as the fracture full capacity is not open and contributing to production. Traditionally, cross-linked polymer fluid systems are capable to suspend and transport high loading of proppants into a hydraulically generated fracture. Nevertheless, amount of unbroken cross-linked polymers is usually left in fractures causing damage to fracture proppant conductivity, depending on polymer loading. To mitigate these challenges, a low viscosity-engineered-fluid with excellent proppantcarrying capacity and suspension-in excess of 30 hours at static formation temperature conditions - has been designed, enhancing proppant placement and distribution within developed fractures, with a 98% plus retained conductivity. In this work experimental and numerical tests are presented together with the path followed in developing a network of packed structures from polymer associations providing low viscosity and maximum proppant suspension. Challenges encountered during field injection with friction are discussed together with the problem understanding characterized via extensive friction loop tests. Suspension tests performed with up to 8-10 PPA of proppant concentration at temperature conditions are shared, together with slot tests performed. Physics-based model results from a 3D Discrete Fracture Network simulator that computes viscosity, and elastic parameters based on shear rate, allows to estimate pressure losses along the flow path from surface lines, tubular goods, perforations, and fracture. This work will demonstrate the advanced capabilities and performance of the engineered fluid over conventional fracturing fluids and its benefits. Additionally, this paper will present field injection pressure analysis performed during the development of this fluid, together with a field case including production results after 8 months of treatment. The field case production decline observed after fracture treatment demonstrates the value of this system in sustaining well production and adding additional reserves.

Hydraulic Fracture Treatment and Landing Zone Interval Optimization: An Eagle Ford Case Study

This paper focuses on optimizing future well landing zones and their corresponding hydraulic fracture treatments in the Eagle Ford shale play. The optimum landing zone and stimulation treatment were determined by analyzing multiple landing zone options, including the lower Austin Chalk, Eagle Ford, and Pepper Shale, with several hydraulic fracturing treatment possibilities. Fracturing fluids and their volume, proppant size, and cluster spacing were investigated to determine the optimum hydraulic fracturing treatment for the subject geologic area. Ranges of 75,000 to 300,000 gallons of pure gel, pure slickwater, and hybrid fracturing fluids along with 20/40, 30/50, 40/70, and 100 mesh proppant were tested. Cluster spacing of twenty feet to eighty feet were also sensitized in this study. A fully three-dimensional hydraulic fracture modeling software was used to develop a geological and geomechanical model of the studied area. The generated model was calibrated with available field data to ensure that the model reflects the area's geological and geomechanical characteristics. The developed model was used to create fracture results for each sensitized parameter. Production analysis was performed for all fracture models to determine the optimum landing zone and fracturing treatment implications. The study shows that the Eagle Ford had better production than the lower Austin Chalk in the subject area. The Pepper Shale had the highest potential hydrocarbon production, around 326 Mbbl cumulative, when fractured with a pure gel treatment. The analyses showed that a hybrid treatment with 70% gel and 30% slickwater yielded the optimum production due to the treatment economics even though the highest production was obtained using the pure gel. Treating the formation with larger proppant provided better production than smaller proppant due to conductivity concerns associated with damaging mechanisms in the studied area. Since increasing the volume above 175,000 gallons caused a negligible increase in the production, 175,000 gallons of fracturing fluid per stage appeared to be the optimum fracturing fluid volume. Thirty-foot cluster spacing was the optimum spacing in the study area. Overall, the study suggests that oil production can be improved in the Eagle Ford study area through a detailed workflow development and optimization process. The hydraulic fracture treatment and landing zone optimization workflow ensures optimum hydrocarbon extraction from the study area. The developed workflow can be applied to new unconventional plays instead of using trial and error methods.

Experimental Study of Proppant Bridging in a Model of a Hydraulic Fracture

Summary In this article, we investigate formation of the local clogging (bridging) of proppant in a channel with gradually narrowing walls. The experimental facility allows us to simulate the process of the proppant transport in a hydraulic fracture by reproduction of the characteristic channel width, velocity of slurry, rheology of fracturing fluids, and typical concentrations of proppant. The goal of the study is to give qualitative description of the dynamics of the congestion of the proppant up to the complete blockage of the flow. In contrast to common practice of imposing bridging criteria by postulating certain threshold value of the width to proppant size ratio, we demonstrate that the bridging process involves several stages: clogging of two to three particles, growth of stable “islands,” connection of the islands by arches, and, finally, the total sandout of the cell by the bridged proppant. The observations of the paper gives better understanding of the bridging process giving the directions for more precise numerical simulations.

Effects of imidazolium- and ammonium-based ionic liquids on clay swelling: experimental and simulation approach

Water-based fracturing fluids without an inhibitor promote clay swelling, which eventually creates wellbore instability. Several ionic liquids (ILs) have been studied as swelling inhibitors in recent years. The cations of the ILs are crucial to the inhibitory mechanisms that take place during hydraulic fracturing. Individual studies were carried out on several ILs with various cations, with the most frequently found being ammonium and imidazolium cations. As a result, the goal of this study is to compare these two cations to find an effective swelling inhibitor. A comparison and evaluation of the clay swelling inhibitory properties of tetramethylammonium chloride (TMACl) and 1-ethyl-3-methylimidazolium chloride (EMIMCl) were conducted in this work. Their results were also compared to a conventional inhibitor, potassium chloride (KCl), to see which performed better. The linear swelling test and the rheology test were used to determine the inhibitory performance of these compounds. Zeta potential measurements, Fourier-transform infrared spectroscopy, and contact angle measurements were carried out to experimentally explain the inhibitory mechanisms. In addition, the COSMO-RS simulation was conducted to explain the inhibitory processes and provide support for the experimental findings. The findings of the linear swelling test revealed that the swelling was reduced by 23.40% and 15.66%, respectively, after the application of TMACl and EMIMCl. The adsorption of ILs on the negatively charged clay surfaces, neutralizing the charges, as well as the lowering of the surface hydrophilicity, aided in the improvement of the swelling inhibition performance.

Fracturing Fluid Design: A Closer Look at Breaker and Surfactant Selection

Guar and its derivatives are the most commonly used gelling agents for fracturing fluids. At high temperature, higher polymer loadings are required to maintain sufficient viscosity for proper proppant carry and creating the fracture geometry. To minimize fracturing fluids damage and optimize fracture conductivity, it is necessary to design a fluid that is easy to clean up by ensuring proper breaking and sufficiently low surface tension for flow back. Therefore, breakers and surfactants must be carefully selected and optimally dosed to ensure the success of fracturing treatments. In this study, two fracturing fluids were evaluated for moderate to high temperature applications with a focus on post-treatment cleanup efficiency. The first is a guar-based fluid with a borate crosslinker evaluated at 280°F and the second is a CMHPG-based fluid with a zirconate crosslinker evaluated at 320°F. The shear viscosities of both fluids were tested with a live sodium bromate breaker, a polymer encapsulated ammonium persulfate breaker and a dual breaker system combining the two breakers. Different anionic and nonionic surfactant chemistries (aminosulfonic acid and alcohol based) were investigated by measuring surface tension of the surfactant solutions at different concentrations. The compatibility of the surfactants with other fracturing fluid additives and their adsorption in Berea sandstone was also investigated. Finally, the damage caused by leak-off for each fracturing fluid was simulated by using coreflooding experiments and Berea sandstone core plugs. Lab results showed the guar and CMHPG fluids maintained sufficient viscosity for the first two hours at baseline, respectively. The encapsulated breaker proved to be effective in delaying the breaking of the fracturing fluids. The dual breaker system was the most effective and the loading was optimized for each tested temperature to provide the desired viscosity profile. Two of the examined surfactants were effective in lowering surface tension (below 30 dyne/cm) and were stable for all tested temperatures. The guar broken fluid showed better regained permeability (up to 94%) when compared to the CMHPG (up to 53%) fluid for Berea sandstone. This paper outlines a methodical approach to selecting and optimizing fracturing fluid chemical additives for better post-treatment cleanup and subsequent well productivity.

Optimizing Seawater Based Fracture Fluids Rheology Utilizing Chelating Agents

Due to the scarcity and high cost of freshwater, especially in the Gulf region, utilization of seawater as a fracturing fluid gained noticeable interest. However, seawater contains high total dissolved solids (TDS) that may damage the formation and degrade the performance of the fracturing fluids. Numerous additives are required to reduce the damaging effect and improve the viscosity resulting in an expensive and non-eco-friendly fracturing fluid system. Chelating agents, which are environmentally benign, are proposed in this study as the replacement of many additives for seawater fracturing fluids. This study focuses on optimizing chelating agents to achieve high viscosity employing the standard industry rheometers. Carboxymethyl Hydroxypropyl Guar Gum (CMHPG) polymer, which is effective in hydraulic fracturing, was used in this research with 0.5 and 1.0 wt% in deionized water (DW) as well as seawater (SW). It was first tested as a standalone additive at different conditions to provide a benchmark then combined with different concentrations, and pH level chelating agents. In this study the hydration test was conducted through different conditions. It was observed that CMHPG, when tested as a standalone additive, provided slightly higher viscosity in SW compared to DW. Also, increasing polymer concentration from 0.5 to 1.0 wt% provided three folds of viscosity. The viscosity did not show time dependence behavior at room temperature for the aforementioned experiments where all hydration tests were run at 511 1/s shear rate. Temperature, however, had a significant impact on both viscosity magnitude and behavior. At 70 °C, the fluid viscosity increased with time where low viscosity was achieved early on but kept increasing with shearing time. Similarly, high pH chelating agents provided time dependant viscosity behavior when mixed with CMHPG. This behavior is important as low viscosity is favorable during pumping but high viscosity when the fluids hit the formation. The study investigates the possibility of utilizing chelating agents with seawater to replace numerous additives. It acts as a crosslinker at early shearing times, where a gradual increase in viscosity was observed and a breaker in the reservoir harsh conditions. It also captures the divalent ions that are common in seawater, which replaces the need for scale inhibitors. The viscosity increase behavior can be controlled by adjusting the pH level, which could be desirable during operations.

Novel Trends in the Development of Surfactant-Based Hydraulic Fracturing Fluids: A Review

Viscoelastic surfactants (VES) are amphiphilic molecules which self-assemble into long polymer-like aggregates—wormlike micelles. Such micellar chains form an entangled network, imparting high viscosity and viscoelasticity to aqueous solutions. VES are currently attracting great attention as the main components of clean hydraulic fracturing fluids used for enhanced oil recovery (EOR). Fracturing fluids consist of proppant particles suspended in a viscoelastic medium. They are pumped into a wellbore under high pressure to create fractures, through which the oil can flow into the well. Polymer gels have been used most often for fracturing operations; however, VES solutions are advantageous as they usually require no breakers other than reservoir hydrocarbons to be cleaned from the well. Many attempts have recently been made to improve the viscoelastic properties, temperature, and salt resistance of VES fluids to make them a cost-effective alternative to polymer gels. This review aims at describing the novel concepts and advancements in the fundamental science of VES-based fracturing fluids reported in the last few years, which have not yet been widely industrially implemented, but are significant for prospective future applications. Recent achievements, reviewed in this paper, include the use of oligomeric surfactants, surfactant mixtures, hybrid nanoparticle/VES, or polymer/VES fluids. The advantages and limitations of the different VES fluids are discussed. The fundamental reasons for the different ways of improvement of VES performance for fracturing are described.

A Comprehensive Review on the Characteristics, Challenges and Reuse Opportunities Associated with Produced Water in Fracturing Operations

Amid the rise in energy demand over recent years, natural gas from tight reservoirs has been targeted abundantly around the globe by different oil operators. Hydraulic fracturing technology has been instrumental in the successful exploitation of energy from tight formations. The process is associated with enormous usage of water. Hydraulic fracturing requires as little as 500,000 gallons of freshwater, and up to 6 million gallons per well depending on the type of well and the number of stages treated. Now operators, as well as service companies worldwide, have shown a desire to use produced water in field operations to enhance economics and reduce their environmental footprint. Reusing produced water in field operations appears to be a win-win proposition by transforming the industry's biggest waste product into a resource. This paper highlights the recent findings in published articles about formulating a fracturing fluid from produced water as a base fluid. The rheological properties and fluid performance requirements, such as proppant carrying capacity, mixing, fluid efficiency, ability to crosslink and break, and cleanup after treatment, will be evaluated in detail. This paper identified the critical parameters associated with high TDS fluids (produced water) such as pH, hydration time, ionic strength, and suspended solids, collected the corresponding optimal ranges for these parameters in laboratory tests, and reported some of the validity of the findings under actual conditions in field trials around the world. Most studies demonstrated the feasibility of using untreated produced water as a base fluid for crosslinked gel-based hydraulic fracturing. Through adjusting the hydration time, the gel loading, and the amount of breakers applied, it is conceivable that crosslinked gels with optimal rheological characteristics can be formulated with untreated produced water. Multiple generations of guar- and CMHPG-based crosslinked fracturing fluids, developed with 100% untreated produced water, exhibited optimal viscosities exceeding 200 cp at 40 s−1 for at least 60 minutes. The ability to provide fracturing fluids with high-salinity produced water can be a successful water conservation approach and an attractive solution for enhancing operation economics. Some studies indicated that using produced water can be better than freshwater because the produced water is more compatible with the reservoir and may be less likely to cause conditions such as salinity shock, which can damage the formation. More studies are needed to understand the associated technical challenges further.

Supramolecular dynamic binary complexes with pH and salt-responsive properties for use in unconventional reservoirs

Hydraulic fracturing of unconventional reservoirs has seen a boom in the last century, as a means to fulfill the growing energy demand in the world. The fracturing fluid used in the process plays a substantial role in determining the results. Hence, several research and development efforts have been geared towards developing more sustainable, efficient, and improved fracturing fluids. Herein, we present a dynamic binary complex (DBC) solution, with potential to be useful in the hydraulic fracturing domain. It has a supramolecular structure formed by the self-assembly of low molecular weight viscosifiers (LMWVs) oleic acid and diethylenetriamine into an elongated entangled network under alkaline conditions. With less than 2 wt% constituents dispersed in aqueous solution, a viscous gel that exhibits high viscosities even under shear was formed. Key features include responsiveness to pH and salinity, and a zero-shear viscosity that could be tuned by a factor of ~280 by changing the pH. Furthermore, its viscous properties were more pronounced in the presence of salt. Sand settling tests revealed its potential to hold up sand particles for extended periods of time. In conclusion, this DBC solution system has potential to be utilized as a smart salt-responsive, pH-switchable hydraulic fracturing fluid.

Enhancing Performance of High Viscosity Friction Reducers HVFRs in Brine

High Viscosity Friction Reducers (HVFRs) are often employed in hydraulic fracturing fluids to increase the proppant carrying capacity of slickwater fluids. However, it has been widely reported that the performance of HVFR fluids drops precipitously with even small amounts of salt. This study explores and reports the use of surfactants to alleviate the loss of performance of HVFR fluids due to salinity in the mix water. Fracturing fluids were prepared in the laboratory by mixing the HVFR at concentrations between 2 and 8 gal/1,000 gal with and without surfactant formulations. The viscosities of the fluids were measured on a TA Instruments DHR-3 rheometer using a concentric cylinder geometry. Both anionic and cationic HVFRs were tested with various surfactants. As expected, we observed that HVFR fluids display dramatic loss of viscosity with the addition of as little as 1% salt to the mix water. However, certain surfactant formulations were found to provide a significant boost in viscosity of HVFR fluids in brines over a wide range of shear rates. Increases in viscosity by a factor of as much as 10 times were observed, particularly at low shear rates. The ability of the surfactant formulations to enhance fluid viscosity was observed in both monovalent and divalent model brines, as well as brines that mimicked field produced water compositions. In addition, measurements were also performed in a slot flow device to determine if the results from the rheometer translated to proppant transport characteristics of the fluids. The slot flow results were found to correlate well with fluid viscosity measurements. The fluids containing the surfactant formulation transported nearly 4 times as much proppant as fluids not containing surfactant through a 2.5 ft. long rectangular slot of 0.5 in. thickness at a proppant concentration of 2 lb/gal. An obvious benefit of the approach proposed in this study is that it can enable the use of HVFR fluids in recycled and produced waters, providing both cost and sustainability benefits. Secondly, these surfactant formulations can reduce the amount of HVFR required to obtain a certain target viscosity in brine, thereby reducing the likelihood and potential severity of formation damage from HVFR residue.