scholarly journals Implementation of Bismuth Chalcogenides as an Efficient Anode: A Journey from Conventional Liquid Electrolyte to an All-Solid-State Li-Ion Battery

Molecules ◽  
2020 ◽  
Vol 25 (16) ◽  
pp. 3733 ◽  
Author(s):  
Rini Singh ◽  
Pooja Kumari ◽  
Manoj Kumar ◽  
Takayuki Ichikawa ◽  
Ankur Jain
Keyword(s):  
Solid State ◽  
Lithium Ion ◽  
High Volume ◽  
Liquid Electrolyte ◽  
Li Ion Batteries ◽  
Environmental Friendliness ◽  
Bismuth Chalcogenides ◽  
Carbon Framework ◽  
Narrow Bandgap ◽  
Li Ion

Bismuth chalcogenide (Bi2X3; X = sulfur (S), selenium (Se), and tellurium (Te)) materials are considered as promising materials for diverse applications due to their unique properties. Their narrow bandgap, good thermal conductivity, and environmental friendliness make them suitable candidates for thermoelectric applications, photodetector, sensors along with a wide array of energy storage applications. More specifically, their unique layered structure allows them to intercalate Li+ ions and further provide conducting channels for transport. This property makes these suitable anodes for Li-ion batteries. However, low conductivity and high-volume expansion cause the poor electrochemical cyclability, thus creating a bottleneck to the implementation of these for practical use. Tremendous endeavors have been devoted towards the enhancement of cyclability of these materials, including nanostructuring and the incorporation of a carbon framework matrix to immobilize the nanostructures to prevent agglomeration. Apart from all these techniques to improve the anode properties of Bi2X3 materials, a step towards all-solid-state lithium-ion batteries using Bi2X3-based anodes has also been proven as a key approach for next-generation batteries. This review article highlights the main issues and recent advances associated with Bi2X3 anodes using both solid and liquid electrolytes.

Hybrid solid electrolyte with the combination of Li7La3Zr2O12 ceramic and ionic liquid for high voltage pseudo-solid-state Li-ion batteries

2016 ◽  
Vol 4 (43) ◽  
pp. 17025-17032 ◽  
Author(s):  
Hyun Woo Kim ◽  
Palanisamy Manikandan ◽  
Young Jun Lim ◽  
Jin Hong Kim ◽  
Sang-cheol Nam ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solid State ◽  
Solid Electrolyte ◽  
High Voltage ◽  
Liquid Electrolyte ◽  
Li Ion Batteries ◽  
Ceramic Particles ◽  
Ionic Liquid Electrolyte ◽  
Safety Aspects ◽  
Li Ion

Concerning the safety aspects of high-voltage Li-ion batteries, a pelletized hybrid solid electrolyte (HSE) was prepared by blending Li7La3Zr2O12 (LLZO) ceramic particles and an ionic liquid electrolyte (ILE) for use in pseudo-solid-state Li-ion batteries.

scholarly journals MgH2–CoO: a conversion-type composite electrode for LiBH4-based all-solid-state lithium ion batteries

RSC Advances ◽  
2018 ◽  
Vol 8 (41) ◽  
pp. 23468-23474 ◽  
Author(s):  
Abdelouahab El Kharbachi ◽  
Hiroki Uesato ◽  
Hironori Kawai ◽  
Sigurd Wenner ◽  
Hiroki Miyaoka ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Ion Batteries ◽  
Composite Electrode ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Li Ion ◽  
Type Composite

The findings point to a means of guided formation of MgH2–CoO conversion-type nanocomposite electrode for all-solid-state Li-ion batteries.

Enhancement of ionic conductivity of a composite polymer electrolyte via surface functionalization of SSZ-13 zeolite for all-solid-state Li-ion batteries

2021 ◽  
Author(s):  
Jae Hyun Kim ◽  
Hasan Jamal ◽  
Firoz Khan ◽  
Suyeon Hyun ◽  
Sang Won Min
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Polymer Electrolyte ◽  
Surface Functionalization ◽  
Liquid Electrolyte ◽  
Composite Polymer Electrolyte ◽  
Li Ion Batteries ◽  
Composite Polymer ◽  
Safety Issues ◽  
Li Ion

To mitigate the safety issues of liquid electrolyte-based Li-ion batteries, there is a growing interest in the development of solid-state electrolytes (SSEs) based Li-metal batteries. Regrettably, most SSEs have low...

A photo-curable gel electrolyte ink for 3D-printable quasi-solid-state lithium-ion batteries

2021 ◽  
Author(s):  
Yoshiyuki Gambe ◽  
Hiroaki Kobayashi ◽  
Kazuyuki Iwase ◽  
Sven Stauss ◽  
Itaru Honma
Keyword(s):  
Ionic Liquids ◽  
Solid State ◽  
Silica Nanoparticles ◽  
Lithium Ion Batteries ◽  
Uv Irradiation ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Gel Electrolytes ◽  
3D Printed ◽  
Li Ion

We demonstrate gel electrolytes composed of ionic liquids, silica nanoparticles, and UV-resins, that can be 3D-printed and cured by UV-irradiation. The electrolyte maintains its high Li-ion conductivity, enabling quasi-solid-state Li-ion batteries.

scholarly journals Correlation of Mechanical and Electrical Behavior of Polyethylene Oxide-Based Solid Electrolytes for All-Solid State Lithium-Ion Batteries

Batteries ◽  
2019 ◽  
Vol 5 (1) ◽  
pp. 26 ◽  
Author(s):  
Fabian Peters ◽  
Frederieke Langer ◽  
Nikolai Hillen ◽  
Katharina Koschek ◽  
Ingo Bardenhagen ◽  
...  
Keyword(s):  
Solid State ◽  
Ionic Conductivity ◽  
Mechanical Strength ◽  
Solid Electrolytes ◽  
Large Scale ◽  
Lithium Ion ◽  
Scale Production ◽  
Li Ion Batteries ◽  
Scanning Calorimetry ◽  
Li Ion

Mechanical and electrochemical stability are key issues for large-scale production of solid state Li-ion batteries. Polymer electrolytes can provide good ionic conductivity, but mechanical strength needs to be improved. In this study, we investigate the correlation of mechanical and electrical properties of poly (ethylene oxide) (PEO)-based solid electrolytes for Li-ion batteries. The influence of alumina and LiClO4 addition are investigated. Differential scanning calorimetry (DSC) is used to study the thermal behavior of salt-free and salt-containing samples and to identify the melting temperature. Dynamic mechanical analysis reveals the elastic properties as a function of temperature. Electrochemical properties are investigated using impedance spectroscopy. It is found that addition of alumina increases mechanical strength, while LiClO4 decreases it. Addition of LiClO4 and Al2O3 increases ionic conductivity and improves mechanical properties. However, there is no overlapping window of high mechanical strength and high ionic conductivity.

A new approach for synthesizing bulk-type all-solid-state lithium-ion batteries

2019 ◽  
Vol 7 (16) ◽  
pp. 9748-9760 ◽  
Author(s):  
Linchun He ◽  
Chao Chen ◽  
Masashi Kotobuki ◽  
Feng Zheng ◽  
Henghui Zhou ◽  
...  
Keyword(s):  
Energy Storage ◽  
Solid State ◽  
Energy Density ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Energy Storage Devices ◽  
New Approach ◽  
Storage Devices ◽  
Safety Issues ◽  
Li Ion

All-solid-state Li-ion batteries (ASSLiB) have been considered to be the next generation energy storage devices that can overcome safety issues and increase the energy density by replacing the organic electrolyte with inflammable solid electrolyte.

A Si-doped flexible self-supporting comb-like polyethylene glycol copolymer (Si-PEG) film as a polymer electrolyte for an all solid-state lithium-ion battery

2017 ◽  
Vol 5 (46) ◽  
pp. 24444-24452 ◽  
Author(s):  
Xiaoxiao Ji ◽  
Huihui Zeng ◽  
Xianjing Gong ◽  
Fangchang Tsai ◽  
Tao Jiang ◽  
...  
Keyword(s):  
Polyethylene Glycol ◽  
Solid State ◽  
Lithium Ion Battery ◽  
Polymer Electrolyte ◽  
Low Temperatures ◽  
Lithium Ion ◽  
Li Ion Batteries ◽  
Si Doped ◽  
Li Ion

A Si-doped PEG-based crosslinked comb-like copolymer is an excellent polymer electrolyte for Li-ion batteries at low temperatures.

New high-energy-density GeTe-based anodes for Li-ion batteries

2019 ◽  
Vol 7 (7) ◽  
pp. 3278-3288 ◽  
Author(s):  
Ki-Hun Nam ◽  
Geon-Kyu Sung ◽  
Jeong-Hee Choi ◽  
Jong-Sang Youn ◽  
Ki-Joon Jeon ◽  
...  
Keyword(s):  
Solid State ◽  
Energy Density ◽  
Lithium Ion Batteries ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Li Ion Batteries ◽  
Electrochemical Behaviors ◽  
Germanium Telluride ◽  
Li Ion

A layered germanium telluride (GeTe) and its C-modified nanocomposite (GeTe–C) are synthesized by a simple solid-state synthesis technique, and their electrochemical behaviors for rechargeable lithium-ion batteries (LIBs) are evaluated.

scholarly journals Dunaliella Salinas based Sn–carbon anode for high-performance Li-ion batteries

RSC Advances ◽  
2021 ◽  
Vol 11 (61) ◽  
pp. 38796-38803
Author(s):  
Yuhua Yang ◽  
Yecheng Dong ◽  
Ziwei Zhang ◽  
Zhichao Xi ◽  
Junhuai Xiang ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
High Capacity ◽  
Lithium Ion ◽  
Carbon Anode ◽  
Rate Performance ◽  
Li Ion Batteries ◽  
Environmental Friendliness ◽  
Li Ion ◽  
Long Life

Long life, high capacity, environmental friendliness and good rate performance are the most important elements in the research of lithium ion batteries (LIBs).

scholarly journals Facile Synthesis of Al-Stabilized Lithium Garnets by Solution-Combustion Technique for All Solid-State Batteries

2021 ◽  
Author(s):  
Pavan Badami ◽  
Stefan Smetaczek ◽  
Andreas Limbeck ◽  
Daniel Rettenwander ◽  
Candace K. Chan ◽  
...  
Keyword(s):  
Solid State ◽  
Lithium Batteries ◽  
Liquid Electrolyte ◽  
Li Ion Batteries ◽  
Solution Combustion ◽  
Solid State Batteries ◽  
Li Ion ◽  
Ceramic Electrolytes ◽  
Combustion Technique ◽  
Lithium Garnets

Solid-state lithium batteries (SSLBs) with ceramic electrolytes are proposed to result in improved energy density and safety compared to liquid electrolyte-based Li-ion batteries. Among the various inorganic ceramic electrolytes, Li7La3Zr2O12...

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