scholarly journals Facile Synthesis of Al-Stabilized Lithium Garnets by Solution-Combustion Technique for All Solid-State Batteries

2021 ◽  
Author(s):  
Pavan Badami ◽  
Stefan Smetaczek ◽  
Andreas Limbeck ◽  
Daniel Rettenwander ◽  
Candace K. Chan ◽  
...  

Solid-state lithium batteries (SSLBs) with ceramic electrolytes are proposed to result in improved energy density and safety compared to liquid electrolyte-based Li-ion batteries. Among the various inorganic ceramic electrolytes, Li7La3Zr2O12...

Author(s):  
Jing Wang ◽  
Xingkang Huang ◽  
Junhong Chen

Solid-state lithium batteries (SSLBs) are promising candidates for replacing traditional liquid-based Li-ion batteries and revolutionizing battery systems for electric vehicles and portable devices. However, longstanding issues such as form factors,...


2009 ◽  
Vol 189 (1) ◽  
pp. 365-370 ◽  
Author(s):  
J. Xie ◽  
N. Imanishi ◽  
T. Zhang ◽  
A. Hirano ◽  
Y. Takeda ◽  
...  

Molecules ◽  
2020 ◽  
Vol 25 (16) ◽  
pp. 3733 ◽  
Author(s):  
Rini Singh ◽  
Pooja Kumari ◽  
Manoj Kumar ◽  
Takayuki Ichikawa ◽  
Ankur Jain

Bismuth chalcogenide (Bi2X3; X = sulfur (S), selenium (Se), and tellurium (Te)) materials are considered as promising materials for diverse applications due to their unique properties. Their narrow bandgap, good thermal conductivity, and environmental friendliness make them suitable candidates for thermoelectric applications, photodetector, sensors along with a wide array of energy storage applications. More specifically, their unique layered structure allows them to intercalate Li+ ions and further provide conducting channels for transport. This property makes these suitable anodes for Li-ion batteries. However, low conductivity and high-volume expansion cause the poor electrochemical cyclability, thus creating a bottleneck to the implementation of these for practical use. Tremendous endeavors have been devoted towards the enhancement of cyclability of these materials, including nanostructuring and the incorporation of a carbon framework matrix to immobilize the nanostructures to prevent agglomeration. Apart from all these techniques to improve the anode properties of Bi2X3 materials, a step towards all-solid-state lithium-ion batteries using Bi2X3-based anodes has also been proven as a key approach for next-generation batteries. This review article highlights the main issues and recent advances associated with Bi2X3 anodes using both solid and liquid electrolytes.


Crystals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 408
Author(s):  
Katja Waetzig ◽  
Christian Heubner ◽  
Mihails Kusnezoff

All-solid-state batteries (ASSB) are considered promising candidates for future energy storage and advanced electric mobility. When compared to conventional Li-ion batteries, the substitution of Li-ion conductive, flammable liquids by a solid electrolyte and the application of Li-metal anodes substantially increase safety and energy density. The solid electrolyte Li1.3Al0.3Ti1.7(PO4)3 (LATP) provides high Li-ion conductivity of about 10−3 S/cm and is considered a highly promising candidate for both the solid electrolyte-separator and the ionically conductive part of the all-solid state composite cathode, consisting of the cathode material, the solid electrolyte, and an electron conductor. Co-sintering of the composite cathode is a sophisticated challenge, because temperatures above 1000 °C are typically required to achieve the maximum ionic conductivity of LATP but provoke reactions with the cathode material, inhibiting proper electrochemical functioning in the ASSB. In the present study, the application of sintering aids with different melting points and their impact on the sinterability and the conductivity of LATP were investigated by means of optical dilatometry and impedance spectroscopy. The microstructure of the samples was analyzed by SEM. The results indicate that the sintering temperature can be reduced below 800 °C while maintaining high ionic conductivity of up to 3.6 × 10−4 S/cm. These insights can be considered a crucial step forward towards enable LATP-based composite cathodes for future ASSB.


2014 ◽  
Vol 2 (48) ◽  
pp. 20552-20559 ◽  
Author(s):  
Marina S. Leite ◽  
Dmitry Ruzmetov ◽  
Zhipeng Li ◽  
Leonid A. Bendersky ◽  
Norman C. Bartelt ◽  
...  

The dynamic degradation of Al anodes in solid-state batteries is quantitatively measured by combining real-time scanning electron microscopy with electrochemical cycling.


2016 ◽  
Vol 4 (43) ◽  
pp. 17025-17032 ◽  
Author(s):  
Hyun Woo Kim ◽  
Palanisamy Manikandan ◽  
Young Jun Lim ◽  
Jin Hong Kim ◽  
Sang-cheol Nam ◽  
...  

Concerning the safety aspects of high-voltage Li-ion batteries, a pelletized hybrid solid electrolyte (HSE) was prepared by blending Li7La3Zr2O12 (LLZO) ceramic particles and an ionic liquid electrolyte (ILE) for use in pseudo-solid-state Li-ion batteries.


Author(s):  
Jae Hyun Kim ◽  
Hasan Jamal ◽  
Firoz Khan ◽  
Suyeon Hyun ◽  
Sang Won Min

To mitigate the safety issues of liquid electrolyte-based Li-ion batteries, there is a growing interest in the development of solid-state electrolytes (SSEs) based Li-metal batteries. Regrettably, most SSEs have low...


2018 ◽  
Vol 6 (13) ◽  
pp. 5296-5303 ◽  
Author(s):  
Hany El-Shinawi ◽  
Anna Regoutz ◽  
David J. Payne ◽  
Edmund J. Cussen ◽  
Serena A. Corr

All solid-state batteries based on NASICON-type LiM2(PO4)3 electrolyte phases are highly promising owing to their high ionic conductivities and chemical stabilities.


2018 ◽  
Vol 6 (8) ◽  
pp. 3304-3327 ◽  
Author(s):  
Joanna Conder ◽  
Cyril Marino ◽  
Petr Novák ◽  
Claire Villevieille

Imaging techniques are increasingly used to study Li-ion batteries and, in particular, post-Li-ion batteries such as Li–S batteries, Na-ion batteries, Na–air batteries and all-solid-state batteries. Herein, we review recent advances in the field made through the use of these techniques.


2015 ◽  
Vol 180 ◽  
pp. 37-42 ◽  
Author(s):  
Yiqiu Li ◽  
Zheng Wang ◽  
Yang Cao ◽  
Fuming Du ◽  
Cheng Chen ◽  
...  

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