scholarly journals Alleviating Distortion and Improving the Young’s Modulus in Two-Photon Polymerization Fabrications

Micromachines ◽  
2018 ◽  
Vol 9 (12) ◽  
pp. 615 ◽  
Author(s):  
Chow-Shing Shin ◽  
Tzu-Jui Li ◽  
Chih-Lang Lin

Two-photon polymerization enables the extremely high resolution three-dimensional printing of micro-structures. To know the mechanical properties, and better still, to be able to adjust them is of paramount importance to ensuring the proper structural integrity of the printed products. In this work, the Young’s modulus is measured on two-photon polymerized micro-cantilever bars. Optimizing the scanning trajectory of the laser focus points is important in alleviating distortion of the printed bars. By increasing the laser power and decreasing the inter-voxel distances we can double the Young’s modulus. Post-curing with ultraviolet light can approximately quadruple the Young’s modulus. However, the resulting modulus is still only about 0.3% of that of the bulk polymerized material.

2016 ◽  
Vol 100 ◽  
pp. 93-99
Author(s):  
Maria Guadalupe del Rocio Herrera Salazar ◽  
Hiroyuki Akiyama ◽  
Tadachika Nakayama ◽  
Hisayuki Suematsu ◽  
Koichi Niihara

In this paper we presented the synthesis of TEOS with photoresist in order to use it like a hybrid material for 3D printer on the micrometer scale by means of the two-photon polymerization process, in which two photon are absorbed simultaneously by the material using an ultrafast laser causing its polymerization. We analyzed the mix of TEOS and photoresist with UV-VIS and FTIR spectrometers, checking that complies with two important conditions: has an optical transmission at 780 nm and absorbs at 390 nm. Finally we fabricated micro-structures with a new hybrid material; TEOS does not absorb the laser in this system and does not interfere with the formation of a three-dimensional structure. After formation the 3D microstructure, samples were heated to form the SiO. These samples of microstructures were observed under digital microscope and SEM.


Author(s):  
Toshiyuki Sawa ◽  
Yuya Hirayama ◽  
He Dan

The stress wave propagation and stress distribution in scarf adhesive joints have been analyzed using three-dimensional finite element method (FEM). The FEM code employed was LS-DYNA. An impact tensile loading was applied to the joint by dropping a weight. The effect of the scarf angle, Young’s modulus of the adhesive and adhesive thickness on the stress wave propagations and stress distributions at the interfaces have been examined. As the results, it was found that the point where the maximum principal stress becomes maximum changes between 52 degree and 60 degree under impact tensile loadings. The maximum value of the maximum principal stress increases as scarf angle decreases, Young’s modulus of the adhesive increases and adhesive thickness increases. In addition, Experiments to measure the strains and joint strengths were compared with the calculated results. The calculated results were in fairly good agreements with the experimental results.


2020 ◽  
Vol 9 (1) ◽  
pp. 1118-1136
Author(s):  
Zhenjia Huang ◽  
Gary Chi-Pong Tsui ◽  
Yu Deng ◽  
Chak-Yin Tang

AbstractMicro/nano-fabrication technology via two-photon polymerization (TPP) nanolithography is a powerful and useful manufacturing tool that is capable of generating two dimensional (2D) to three dimensional (3D) arbitrary micro/nano-structures of various materials with a high spatial resolution. This technology has received tremendous interest in cell and tissue engineering and medical microdevices because of its remarkable fabrication capability for sophisticated structures from macro- to nano-scale, which are difficult to be achieved by traditional methods with limited microarchitecture controllability. To fabricate precisely designed 3D micro/nano-structures for biomedical applications via TPP nanolithography, the use of photoinitiators (PIs) and photoresists needs to be considered comprehensively and systematically. In this review, widely used commercially available PIs are first discussed, followed by elucidating synthesis strategies of water-soluble initiators for biomedical applications. In addition to the conventional photoresists, the distinctive properties of customized stimulus-responsive photoresists are discussed. Finally, current limitations and challenges in the material and fabrication aspects and an outlook for future prospects of TPP for biomedical applications based on different biocompatible photosensitive composites are discussed comprehensively. In all, this review provides a basic understanding of TPP technology and important roles of PIs and photoresists for fabricating high-precision stimulus-responsive micro/nano-structures for a wide range of biomedical applications.


2021 ◽  
Vol 143 (10) ◽  
Author(s):  
Ketki M. Lichade ◽  
Yayue Pan

Abstract This study successfully integrates acoustic patterning with the Two-Photon Polymerization (TPP) process for printing nanoparticle–polymer composite microstructures with spatially varied nanoparticle compositions. Currently, the TPP process is gaining increasing attention within the engineering community for the direct manufacturing of complex three-dimensional (3D) microstructures. Yet the full potential of TPP manufactured microstructures is limited by the materials used. This study aims to create and demonstrate a novel acoustic field-assisted TPP (A-TPP) process, which can instantaneously pattern and assemble nanoparticles in a liquid droplet, and fabricate anisotropic nanoparticle–polymer composites with spatially controlled particle–polymer material compositions. It was found that the biggest challenge in integrating acoustic particle patterning with the TPP process is that nanoparticles move upon laser irradiation due to the photothermal effect, and hence, the acoustic assembly is distorted during the photopolymerization process. To cure acoustic assembly of nanoparticles in the resin through TPP with the desired nanoparticle patterns, the laser power needs to be carefully tuned so that it is adequate for curing while low enough to prevent the photothermal effect. To address this challenge, this study investigated the threshold laser power for polymerization of TPP resin (Pthr) and photothermal instability of the nanoparticle (Pthp). Patterned nanoparticle–polymer composite microstructures were fabricated using the novel A-TPP process. Experimental results validated the feasibility of the developed acoustic field-assisted TPP process on printing anisotropic composites with spatially controlled material compositions.


Micromachines ◽  
2020 ◽  
Vol 11 (2) ◽  
pp. 112 ◽  
Author(s):  
Linyu Yan ◽  
Dong Yang ◽  
Qihuang Gong ◽  
Yan Li

Femtosecond laser direct writing through two-photon polymerization has been widely used in precision fabrication of three-dimensional microstructures but is usually time consuming. In this article, we report the rapid fabrication of continuous surface Fresnel lens array through femtosecond laser three-dimensional focal field engineering. Each Fresnel lens is formed by continuous two-photon polymerization of the two-dimensional slices of the whole structure with one-dimensional scan of the corresponding two-dimensional engineered intensity distribution. Moreover, we anneal the lens array to improve its focusing and imaging performance.


2017 ◽  
Vol 19 (35) ◽  
pp. 23887-23897 ◽  
Author(s):  
Arzu Çolak ◽  
Jingjing Wei ◽  
Imad Arfaoui ◽  
Marie-Paule Pileni

The Young's modulus of three-dimensional self-assembled Ag nanocrystals, as so-called supracrystals, is correlated with the type of coating agent as well as the nanocrystal morphology.


2021 ◽  
Vol 25 (1) ◽  
pp. 88-98
Author(s):  
Mokhtar Messaad ◽  
Messoud Bourezane ◽  
Mohamed Latrache ◽  
Amina Tahar Berrabah ◽  
Djamel Ouzendja

Abstract Concrete dams are considered as complex construction systems that play a major role in the context of both economic and strategic utilities. Taking into account reservoir and foundation presence in modeling the dam-reservoir-foundation interaction phenomenon leads to a more realistic evaluation of the total system behavior. The article discusses the dynamic behavior of dam-reservoir-foundation system under seismic loading using Ansys finite element code. Oued Fodda concrete dam, situated at Chlef, in North-West of Algeria, was chosen as a case study. Parametric study was also performed for different ratios between foundation Young's modulus and dam Young's modulus E f /E d (which varies from 0.5 to 4). Added mass approach was used to model the fluid reservoir. The obtained results indicate that when dam Young's modulus and foundation Young's modulus are equal, the foundation soil leads to less displacements in the dam body and decreases the principal stresses as well as shear stresses.


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