scholarly journals Effect of Alloying Elements on the Mechanical Properties of Mo3Si

Metals ◽  
2021 ◽  
Vol 11 (1) ◽  
pp. 129
Author(s):  
Wei Bi ◽  
Shunping Sun ◽  
Shaoyi Bei ◽  
Yong Jiang

Molybdenum silicides are attractive high-temperature structural materials because of their excellent thermal stability and outstanding oxidation resistance at high temperatures. First-principles calculations were employed to investigate the effect of alloying elements (Cr, Nb, V, W, Al, Ga, and Ge) on the mechanical properties of Mo3Si. The structural stabilities of doped Mo3Si were calculated, showing that the Pm-3n structure was stable at the investigated low-doping concentration. The calculated elastic constants have also evaluated some essential mechanical properties of doped Mo3Si. Cr- and V-doping decreased the elastic modulus, while Al- and Nb-doping slightly increased the shear and Young’s modulus of Mo3Si. Furthermore, V-, Al- and Nb-doping decreased the B/G and Poisson ratio, suggesting that these elements could form strong covalent bonds, and decrease shear deformation and alloy ductility. Based on the three-dimensional contours and two-dimensional projection of the elastic modulus, Cr- and V-doping exhibited a significant influence on the anisotropy of the shear and Young’s modulus. According to charge density and density of states, the electronic structures of alloyed Mo3Si were further analyzed to reveal the doping effects.

Author(s):  
Enboa Wu ◽  
Albert J. D. Yang ◽  
Ching-An Shao ◽  
C. S. Yen

Nondestructive determination of Young’s modulus, coefficient of thermal expansion, Poisson ratio, and thickness of a thin film has long been a difficult but important issue as the film of micrometer order thick might behave differently from that in the bulk state. In this paper, we have successfully demonstrated the capability of determining all these four parameters at one time. This novel method includes use of the digital phase-shifting reflection moire´ (DPRM) technique to record the slope of wafer warpage under temperature drop condition. In the experiment, 1-um thick aluminum was sputtered on a 6-in silicon wafer. The convolution relationship between the measured data and the mechanical properties was constructed numerically using the conventional 3D finite element code. The genetic algorithm (GA) was adopted as the searching tool for search of the optimal mechanical properties of the film. It was found that the determined data for Young’s modulus (E), Coefficient of Thermal Expansion (CTE), Poisson ratio (ν), and thickness (h) of the 1.00 um thick aluminum film were 104.2Gpa, 38.0 ppm/°C, 0.38, and 0.98 um, respectively, whereas that in the bulk state were measured to be E=71.4 Gpa, CTE=23.0 ppm/°C, and ν=0.34. The significantly larger values on the Young’s modulus and the coefficient of thermal expansion determined by this method might be attributed to the smaller dislocation density due to the thin dimension and formation of the 5-nm layer of Al2O3 formed on top of the 1-um thick sputtered film. The Young’s Modulus and the Poisson ratio of this nano-scale Al2O3 film were then determined. Their values are consistent with the physical intuition of the microstructure.


2015 ◽  
Vol 112 (21) ◽  
pp. 6533-6538 ◽  
Author(s):  
Shilpa N. Raja ◽  
Andrew C. K. Olson ◽  
Aditya Limaye ◽  
Kari Thorkelsson ◽  
Andrew Luong ◽  
...  

With the availability of nanoparticles with controlled size and shape, there has been renewed interest in the mechanical properties of polymer/nanoparticle blends. Despite the large number of theoretical studies, the effect of branching for nanofillers tens of nanometers in size on the elastic stiffness of these composite materials has received limited attention. Here, we examine the Young's modulus of nanocomposites based on a common block copolymer (BCP) blended with linear nanorods and nanoscale tetrapod Quantum Dots (tQDs), in electrospun fibers and thin films. We use a phenomenological lattice spring model (LSM) as a guide in understanding the changes in the Young's modulus of such composites as a function of filler shape. Reasonable agreement is achieved between the LSM and the experimental results for both nanoparticle shapes—with only a few key physical assumptions in both films and fibers—providing insight into the design of new nanocomposites and assisting in the development of a qualitative mechanistic understanding of their properties. The tQDs impart the greatest improvements, enhancing the Young's modulus by a factor of 2.5 at 20 wt.%. This is 1.5 times higher than identical composites containing nanorods. An unexpected finding from the simulations is that both the orientation of the nanoscale filler and the orientation of X-type covalent bonds at the nanoparticle-ligand interface are important for optimizing the mechanical properties of the nanocomposites. The tQD provides an orientational optimization of the interfacial and filler bonds arising from its three-dimensional branched shape unseen before in nanocomposites with inorganic nanofillers.


Nanoscale ◽  
2019 ◽  
Vol 11 (32) ◽  
pp. 15184-15194 ◽  
Author(s):  
Ajit K. Katiyar ◽  
Ashwini Ann Davidson ◽  
Houk Jang ◽  
Yun Hwangbo ◽  
Byeori Han ◽  
...  

The mechanical properties of ultrathin Si nanomembranes having thicknesses of 2 to 35 nm have been investigated by determining biaxial Young's modulus. The nanomembrane sample with thickness of 2 nm showed very low modulus value of 3.25 GPa.


2020 ◽  
Vol 54 (29) ◽  
pp. 4575-4590 ◽  
Author(s):  
Amin Hamed Mashhadzadeh ◽  
Abdolhossein Fereidoon ◽  
Morteza Ghorbanzadeh Ahangari

In current work, we developed mechanical properties of PVC (polyvinyl chloride)/graphene nanocomposite theoretically and experimentally. In our theoretical model, a multi-scale finite element model was used to predict Young’s modulus of the stated nanocomposite. The molecular structure of pristine graphene was treated using the density functional theory (DFT) method. By assuming graphene as a space-frame structure that preserves the discrete nature of graphene, they were modeled by the use of three-dimensional elastic beam elements for the Carbon-Carbon covalent bonds and point mass elements for the atoms. Then interfacial van der Waals interaction that exists between PVC and graphene was modeled using the general form of Lennard–Jones potential and simulated by a nonlinear truss rod model. The Lennard–Jones parameters and van der Waals forces were determined versus separation distance for the stated nonlinear truss rod via the DFT method. Finally, we prepared PVC/graphene samples with different weight percentages of graphene nanoplatelets experimentally using the melt-mixing procedure. Our computational modeling demonstrated that the magnitudes of Young’s modulus PVC/graphene were close to the experimentally obtained results until 1 wt% with an average difference of about 25%. Finally, we justified the obtained mechanical results by investigating the morphology of experimental samples using Transmission electron microscopy (TEM) and Scanning Electron Microscopy (SEM) images.


2016 ◽  
Vol 78 (5-2) ◽  
Author(s):  
Rohana Hassan ◽  
Syed Syazaril Amri Syed Mubarat ◽  
Anizahyati Alisibramulisi

Young’s Modulus and Poisson’s ratio are the mechanical properties that need to be determined for the production of engineering design or information for the numerical analysis of timber. In this study, Merpauh, Kapur and Sesenduk species were selected. This experimental investigation focuses on the elastic properties of those timber species. The Modulus of Elasticity (MOE) and Poisson’s ratio were determined by means of tensile tests. In addition, Modulus of Rigidity (MOR), tensile strength capacity and its moisture contents were also determined. The deformation during testing was measured by means of mechanical extensometer. The MOE of the studied species range from 36.7 N/mm2 to 119.2 N/mm2, whereas Poisson’s ratio values show less variability. The result of the study also shows that the mechanical properties for the species are related. The larger the density value, the larger value of stress and strain will be. Thus, the value of Poisson ratio will also increase, respectively.


Materials ◽  
2021 ◽  
Vol 14 (12) ◽  
pp. 3310
Author(s):  
Aleksander Duda ◽  
Tomasz Siwowski

Waste tyre-derived products (TDP) are used in some engineering applications and thereby reduce the potential impact on the environment, for example, as lightweight materials in geotechnical engineering projects. One of TDPs is the baling of whole waste tyres to produce rectilinear, lightweight, permeable bales of high bale-to-bale or bale-to-soil friction. The use of lightweight tyre bales in road construction has the potential to satisfy the demand for low-cost materials exhibiting such a beneficial property. This paper presents a laboratory study on the mechanical properties of tyre bales. The laboratory tests included measurement and evaluation of full-scale tyre bales to determine basic values for the geometry and unit weight, compressibility characteristics of tyre bales, including Young’s modulus and Poisson ratio, shear strength along the tyre–tyre and tyre–soil surfaces, creep and stiffness degradation under cyclic load. The respective test procedures and results of these tests are presented in the paper. The paper provides the mechanical properties of tyre bales required for geotechnical projects, as follows: the unit weight—0.515 Mg/m3, the Young’s modulus—826 kPa, the Poison’s ratio—0.11, the dry tyre–tyre interface: cohesion of 0.03 kPa and friction angle of 46.0°, the wet tyre–soil interface: cohesion 0.77 kPa and a friction angle of 29.6°, creep deformation of 6.1% of the average height of the bale, and no stiffness degradation of tyre bales under cyclic load. These results could be directly applied for the designing and construction of the tyre-baled structures.


2016 ◽  
Vol 869 ◽  
pp. 907-912 ◽  
Author(s):  
Diego Rafael Nespeque Correa ◽  
Mariana Luna Lourenço ◽  
Pedro Akira Bazaglia Kuroda ◽  
Marília Afonso Rabelo Buzalaf ◽  
Carlos Roberto Grandini

Ti and Ti-based alloys have favorable properties for biomedical applications, such as high specific strength, low Young’s modulus, excellent corrosion and wear resistance, and good biocompatibility. The addition of alloying elements and heat treatments can result in a good combination of properties. Mo and Zr are β-stabilizer elements that decrease the Young’s modulus and increase the mechanical strength and corrosion resistance. Oxygen is an interstitial element that can improve mechanical strength and prevent ω phase formation. In this study, we analyzed the influence of substitutional and interstitial elements, and some heat treatments in the crystalline structure, microstructure and selected mechanical properties (Vickers microhardness, Young’s modulus and internal friction) of Ti-15Zr-xMo (5, 10, 15 and 20 wt%) alloys. The alloys exhibited dependence on the alloying elements and heat treatments, which resulted in different structural and microstructural changes. The mechanical properties were dependent on phase transformations induced by the compositions and heat treatments.


2007 ◽  
Vol 329 ◽  
pp. 545-550 ◽  
Author(s):  
Dao Hui Xiang ◽  
Ming Chen ◽  
Y.P. Ma ◽  
Fang Hong Sun

Despite great advancements in diamond thin film growth and deposition techniques, determination of the residual stress and Young’s modulus for diamond films has continued to be a challenge. The bulge test is a potentially powerful tool for characterizing the mechanical properties of diamond film. In a bulge tester, pressure is applied on a thin membrane and the out-of-plane deflection of the membrane center is measured. The Young’s Modulus and the residual stress are simultaneously determined by using the load-deflection behavior of a membrane. By means of electron-enhanced hot filament chemical vapor deposition (HFCVD), a diamond film was deposited on silicon slice (100), and the free-standing window sample of diamond thin films was fabricated by means of photolithography and anisotropic wet etching. The deflection of the membranes is measured using a laser interferometry system. The elastic modulus and residual stress were measured using a self-designed bulge equipment. In addition, the distortion of diamond thin films under different pressure was simulated using finite element analysis and the contrast was made with experimental data. The research indicated that the Young’s Modulus of diamond thin films is 937.8GPa and the residual stress is -10.53MPa. The elastic modulus and the residual stress coincide with the report in the literature and the value tested by X-ray diffraction, respectively. This method uses a simple apparatus, and the fabrication of samples is very easy, and it has provided an effective means for precise measure the mechanical properties of other thin films.


2017 ◽  
Vol 885 ◽  
pp. 269-274
Author(s):  
Judit Kámán ◽  
Attila Bonyár

Considering the size of the natural appearance of the micro alloy components of a SAC solder joint, AFM was used to investigate their mechanical properties in the form of their natural appearance. Contact-mode point-spectroscopy was done to determine the elastic modulus and tapping-mode point-spectroscopy was done to investigate the tip-sample power dissipation.The measured Young’s modulus values of the Cu, IML, Ag3Sn and Sn components, were 125±9 GPa, 111±20 GPa, 67±11 GPa and 57±16 GPa, respectively. The dissipation measurements were accomplished by Si and diamond probes with different spring constants. The different characteristics of the results are discussed.


2019 ◽  
Vol 107 (2) ◽  
pp. 207 ◽  
Author(s):  
Jaroslav Čech ◽  
Petr Haušild ◽  
Miroslav Karlík ◽  
Veronika Kadlecová ◽  
Jiří Čapek ◽  
...  

FeAl20Si20 (wt.%) powders prepared by mechanical alloying from different initial feedstock materials (Fe, Al, Si, FeAl27) were investigated in this study. Scanning electron microscopy, X-ray diffraction and nanoindentation techniques were used to analyze microstructure, phase composition and mechanical properties (hardness and Young’s modulus). Finite element model was developed to account for the decrease in measured values of mechanical properties of powder particles with increasing penetration depth caused by surrounding soft resin used for embedding powder particles. Progressive homogenization of the powders’ microstructure and an increase of hardness and Young’s modulus with milling time were observed and the time for complete homogenization was estimated.


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