scholarly journals Interstitials in f.c.c. High Entropy Alloys

Metals ◽  
2020 ◽  
Vol 10 (5) ◽  
pp. 695 ◽  
Author(s):  
Ian Baker
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Yield Strength ◽  
Room Temperature ◽  
Sharp Decrease ◽  
Slight Reduction ◽  
Strength Increase ◽  
High Entropy Alloys ◽  
High Entropy ◽  
Carbon Doped

The effects of interstitials on the mechanical properties of single-phase f.c.c. high entropy alloys (HEAs) have been assessed based on a review of the literature. It is found that in nearly all studies, carbon increases the yield strength, in some cases by more than in traditional alloys. This suggests that carbon can be an excellent way to strengthen HEAs. This strength increase is related to the lattice expansion from the carbon. The effects on other mechanical behavior is mixed. Most studies show a slight reduction in ductility due to carbon, but a few show increases in ductility accompanying the yield strength increase. Similarly, some studies show little or modest increases in work-hardening rate (WHR) due to carbon, whereas a few show a substantial increase. These latter effects are due to changes in deformation mode. For both undoped and carbon doped CoCrFeMnNi, the room temperature ductility decreases slightly with decreasing grain size until ~2–5 µm, below which the ductility appears to decrease rapidly. The room temperature WHR also appears to decrease with decreasing grain size in both undoped and carbon-doped CoCrFeMnNi and in nitrogen-doped medium entropy alloy NiCoCr, and, at least for the undoped HEA, shows a sharp decrease at grain sizes <2 µm. Interestingly, carbon has been shown to almost double the Hall–Petch strengthening in CoCrFeMnNi, suggesting the segregation of carbon to the grain boundaries. There have been few studies on the effects of other interstitials such as boron, nitrogen and hydrogen. It is clear that more research is needed on interstitials both to understand their effects on mechanical properties and to optimize their use.

Grain Size Dependence of Tensile Properties in Cu-Sn Thin Foils (Experimental Study)

2015 ◽  
Vol 736 ◽  
pp. 19-23
Author(s):  
Taek Kyun Jung ◽  
Hyo Soo Lee ◽  
Hyouk Chon Kwon
Keyword(s):  
Mechanical Properties ◽  
Heat Treatment ◽  
Experimental Study ◽  
Grain Size ◽  
Yield Strength ◽  
Room Temperature ◽  
Size Dependence ◽  
Yield Drop ◽  
Thin Foils ◽  
Vacuum Atmosphere

This study was carried out to investigate the effects of grain size on mechanical properties in Cu-Sn foil with a thickness of 30 um. The grain size was varied from approximately 7 um to 50 um using heat treatment at 773 K for 2 h to 24 h in a vacuum atmosphere. Tensile test was carried out at room temperature with strain rate of 1mm/min. Typical yield drop phenomenon was observed. Mechanical properties were found to be strongly affected by microstructural features including grain size. The yield strength and tensile strength gradually decreased with increasing the grain size. The strain to fracture also decreased by grain growth. These results could be explained by not only the grain size dependence of yield strength but also the ratio of thickness to grain size dependence of yield strength.

scholarly journals Tensile Strength and Creep Resistance in Nanocrystalline Cu, Pd and Ag

1990 ◽  
Vol 206 ◽  
Author(s):  
G. W. Nieman ◽  
J. R. Weertman ◽  
R. W. Siegel
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Tensile Strength ◽  
Yield Strength ◽  
Creep Resistance ◽  
Room Temperature ◽  
True Strain ◽  
Constant Load ◽  
Creep Tests ◽  
Grain Sizes

ABSTRACTMeasurements of tensile strength and creep resistance have been made on bulk samples of nanocrystalline Cu, Pd and Ag consolidated from powders by cold compaction. Samples of Cu-Cu2O have also been tested. Yield strength for samples with mean grain sizes of 5–80 nm and bulk densities on the order of 95% of theoretical density are increased 2–5 times over that measured in pure, annealed samples of the same composition with micrometer grain sizes. Ductility in the nanocrystalline Cu has exceeded 6% true strain, however, nanocrystalline Pd samples were much less ductile. Constant load creep tests performed at room temperature at stresses of >100 MPa indicate logarithmic creep. The mechanical properties results are interpreted to be due to grain size-related strengthening and processing flaw-related weakening.

Effect of hafnium addition on a Ni-Al-Co Alloy

1990 ◽  
Vol 48 (4) ◽  
pp. 940-941
Author(s):  
L. S. Lin ◽  
G. W. Levan ◽  
S. M. Russell ◽  
C. C. Law
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Yield Strength ◽  
Grain Boundaries ◽  
Ternary Alloy ◽  
Room Temperature ◽  
Gamma Prime ◽  
Room Temperature Ductility ◽  
Appreciable Increase ◽  
Hf Addition

Recent efforts at P&W have shown that the addition of cobalt to binary NiAl results in an appreciable increase in room temperature ductility. One version of this ternary alloy, designated VIM A, has a composition of Ni-30 at.% Al-35 at.% Co. The addition of 0.5 at.% Hf to this alloy (designated VIM AH) results in an improvement in yield strength at 760°C. Room temperature properties were not found to be significantly affected by the Hf addition. This discussion will focus on the microstructures of alloys VIM A and VIM AH and their relationship to the mechanical properties observed in compression at room temperature and 760°C.The addition of hafnium reduced the grain size of VIM AH alloy. After room temperature compression, both alloys show an ordered bcc (B2) matrix and precipitates which are distributed primarily along grain boundaries. These precipitates were identified by microdiffraction to be ordered fcc (L12) gamma prime for VIM A and hexagonal (A3) for VIM AH.

Effects of a Thermal Coating Process on X100 UOE Line Pipe

2005 ◽  
Author(s):  
Chris Timms ◽  
Duane DeGeer ◽  
Martin McLamb
Keyword(s):  
Heat Treatment ◽  
Yield Strength ◽  
Room Temperature ◽  
High Strength ◽  
Economic Benefits ◽  
Slight Reduction ◽  
Strength Increase ◽  
Coating Process ◽  
Line Pipe ◽  
Heat Treated

The increased demand for high strength linepipe for onshore and offshore pipeline systems has been well documented over the past few years. The economic benefits have been demonstrated, and solutions have been developed to address the technical issues facing high strength linepipe use. However, there are still a few unanswered questions, one of which is addressed in this paper: what is the effect of thermal treatment during the pipeline coating process on the material behaviour of high strength linepipe? This paper presents the results of a thermal coupon study investigating the effects of low temperature heat treatment on the tensile and compressive stress strain curves of samples taken from X100 linepipe. Thirty axial test coupons and thirty circumferential test coupons were machined from a 52 inch diameter, 21 mm wall thickness UOE X100 linepipe. Some of the coupons were maintained in the as-received condition (no heat treatment) while others were heat-treated in a manner that simulates a coating plant induction heat treatment process. All coupons were subsequently tested in tension or compression, either at room temperature or at −18°C. This study has provided a number of interesting results. In regards to material strength, the heat treatment increased the tensile and compressive yield strengths in the longitudinal and circumferential coupons. Axial tensile, axial compressive and circumferential tensile yield strength increases ranged from 5 to 10%. Circumferential compressive yield strength increases ranged from 14 to 24%. A Y/T ratio increase of approximately 7% was observed for all heat-treated tensile coupons. The coupon tests conducted at −18°C were only slightly different than their room temperature counterparts; with an average yield strength increase of 4% in all directions and orientations and a slight reduction in Y/T ratio.

Microstructure and Mechanical Properties Investigation of New Al10Cr12Mn28Fe(50-x)Ni(x) High Entropy Alloys

2020 ◽  
Vol 998 ◽  
pp. 9-14
Author(s):  
Ahmed W. Abdel-Ghany ◽  
Sally Elkatatny ◽  
Mohamed Abdel Hady Gepreel
Keyword(s):  
Mechanical Properties ◽  
Yield Strength ◽  
Compressive Yield Strength ◽  
High Entropy Alloys ◽  
High Ductility ◽  
Cast Material ◽  
High Entropy ◽  
Arc Melting ◽  
Microstructure And Mechanical Properties ◽  
Cast Alloys

In the present study, two newly developed non-equiatomic high entropy Al10Cr12Mn28Fe(50-x)Ni(x) alloys (x= 20 & 15 at%, namely: Ni20 & Ni15, respectively) are investigated. The studied HEAs were designed based on thermodynamic principles to maintain high ductility and improve strength. Ingots were prepared using arc-melting then microstructure examinations and mechanical properties for the as-cast alloys were done. The mechanical properties were enhanced for the as-cast material, compared with previously introduced HEAs of the same system, namely Al5Cr12Mn28Fe35Ni20, (Al5) and Al10Cr12Mn23Fe35Ni20, (Al10). Al10Cr12Mn28Fe30Ni20 (Ni20) HEA generally shows the highest compressive yield strength which was improved by ∼7% when compared with previously introduced Al10.

scholarly journals Microstructure and Room Temperature Mechanical Properties of Different 3 and 4 Element Medium Entropy Alloys from HfNbTaTiZr System

Entropy ◽  
2019 ◽  
Vol 21 (2) ◽  
pp. 114 ◽  
Author(s):  
Jiří Zýka ◽  
Jaroslav Málek ◽  
Jaroslav Veselý ◽  
František Lukáč ◽  
Jakub Čížek ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
Tensile Testing ◽  
Room Temperature ◽  
High Entropy Alloys ◽  
Lower Strength ◽  
X Ray ◽  
High Entropy ◽  
Elongation To Failure ◽  
Zero Values ◽  
Bcc Phase

Refractory high entropy alloys (HEA) are promising materials for high temperature applications. This work presents investigations of the room temperature tensile mechanical properties of selected 3 and 4 elements medium entropy alloys (MEA) derived from the HfNbTaTiZr system. Tensile testing was combined with fractographic and microstructure analysis, using scanning electron microscope (SEM), wavelength dispersive spectroscope (WDS) and X-Ray powder diffraction (XRD). The 5 element HEA alloy HfNbTaTiZr exhibits the best combination of strength and elongation while 4 and 3 element MEAs have lower strength. Some of them are ductile, some of them brittle, depending on microstructure. Simultaneous presence of Ta and Zr in the alloy resulted in a significant reduction of ductility caused by reduction of the BCC phase content. Precipitation of Ta rich particles on grain boundaries reduces further the maximum elongation to failure down to zero values.

Microstructure and Mechanical Properties of Mg-1Mn-0.6Ce Alloy Containing Yttrium

2011 ◽  
Vol 391-392 ◽  
pp. 638-641
Author(s):  
G.H. Su ◽  
Y. Sun ◽  
Zhan Yi Cao
Keyword(s):  
Mechanical Properties ◽  
Grain Size ◽  
Magnesium Alloy ◽  
Yield Strength ◽  
Mass Fraction ◽  
Room Temperature ◽  
Precipitation Strengthening ◽  
Casting Method ◽  
Microstructure And Mechanical Properties ◽  
Cast Alloys

Mg-1Mn-0.6Ce-xY (x=0, 1, 2 and 3, mass fraction, %) magnesium alloys were prepared by casting method. And the influences of yttrium on microstructure and mechanical properties of the Mg-1Mn-0.6Ce magnesium alloy were investigated. The results reveal that the addition of yttrium to the Mg-1Mn-0.6Ce alloy could reduce the grain size of the as-cast alloys and improve mechanical properties during the investigated temperature range. The Mg-1Mn-0.6Ce-1Y alloy exhibits maximum ultimate strength, yield strength, elongation and the values are 152 MPa, 72 MPa and 13.4% and enhanced about 23.1%, 63.6% and 38.1% compared with those of Mg-1Mn-0.6Ce alloy at room temperature, respectively. The improvement of mechanical properties are attributed to the grain refinement and the precipitation strengthening generated by the Mg12Ce phase particles and the fine Mg24Y5 precipitations.

scholarly journals High-entropy alloys: Structure, mechanical properties, deformation mechanisms and application

2021 ◽  
Vol 64 (4) ◽  
pp. 249-258
Author(s):  
K. A. Osintsev ◽  
V. E. Gromov ◽  
S. V. Konovalov ◽  
Yu. F. Ivanov ◽  
I. A. Panchenko
Keyword(s):  
Mechanical Properties ◽  
Phase Composition ◽  
Yield Strength ◽  
High Strength ◽  
Mechanical Tests ◽  
High Entropy Alloys ◽  
High Entropy ◽  
Temperature Range ◽  
Deformation Curves ◽  
Fcc Lattice

The article considers a brief review of the foreign publications on the study of the structure, phase composition and properties of five-component high-entropy alloys (HEAs) in different structural states in a wide temperature range over the past two decades. HEAs attract the attention of scientists with their unique and unusual properties. The difficulties of comparative analysis and generalization of data are noted due to different methods of obtaining HEAs, modes of mechanical tests for uniaxial compression and tension, sizes and shapes of the samples, types of thermal treatments, and phase composition (bcc and fcc crystal lattices). It is noted that the HEA with a bcc lattice has mainly high strength and low plasticity, and the HEA  with a fcc lattice has low strength and increased plasticity. A significant increase in the properties of the FeMnCoCrNi HEA with a fcc lattice can be achieved by alloying with boron and optimizing the parameters of thermal mechanical treatment at alloying with carbon in the amount of 1 % (at.). The deformation curves analyzed in the temperature range –196 ÷ 800 °C indicate an increase in the yield strength with a decrease in the grain size from 150 to 5 microns. As the temperature decreases, the yield strength and elongation increase. The effect of deformation rate on the mechanical properties is an increase in the ultimate strength and yield strength, which is most noticeable at high rates of 10–2 ÷ 103 s–1. The features of HEAs deformation behavior in the mono- and poly-crystalline states are noted. The complex of high operational properties of HEAs makes it possible to use them in various industries. There are good prospects of using energy treatment to modify the surface layers and further improve HEAs properties.

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