scholarly journals Preparation and Characterization of Hydroxyapatite Coating on AZ31 Magnesium Alloy Induced by Carboxymethyl Cellulose-Dopamine

Materials ◽  
2021 ◽  
Vol 14 (8) ◽  
pp. 1849
Author(s):  
Yanxia Yang ◽  
Yuanzhi Wu ◽  
Yu Wei ◽  
Tian Zeng ◽  
Baocheng Cao ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Carboxymethyl Cellulose ◽  
Az31 Alloy ◽  
Chloride Ions ◽  
Hydroxyapatite Coating ◽  
X Ray ◽  
Implant Materials ◽  
Good Biocompatibility

Magnesium and its alloys have become potential implant materials in the future because of light weight, mechanical properties similar to natural bone, good biocompatibility, and degradability in physiological environment. However, due to the rapid corrosion and degradation of magnesium alloys in vivo, especially in the environment containing chloride ions, the application of magnesium alloys as implant materials has been limited. Therefore, improving the corrosion resistance of magnesium alloy and ensuring good biocompatibility is the main focus of the current research. In this study, hydroxyapatite coating was prepared on magnesium alloy surface using carboxymethyl cellulose-dopamine hydrogel as inducer to improve corrosion resistance and biocompatibility. Surface characterization techniques (scanning electron microscopy, Fourier-transformed infrared spectroscopy, energy dispersive X-ray spectroscopy- and X-ray diffraction) confirmed the formation of hydroxyapatite on the surface of AZ31 alloy. Corrosion resistance tests have proved the protective effect of Carboxymethyl cellulose-Dopamine/hydroxyapatite (CMC-DA/HA) coating on the surface of AZ31 alloy. According to MC3T3-E1 cell viability and Live/Dead staining, the coating also showed good biocompatibility. The results will provide new ideas for the biological application of magnesium alloys.

Surface Modification on Magnesium Alloys by Coating with Magnesium Fluorides

2005 ◽  
Vol 475-479 ◽  
pp. 505-508 ◽  
Author(s):  
T. Ohse ◽  
Harushige Tsubakino ◽  
Atsushi Yamamoto
Keyword(s):  
Corrosion Resistance ◽  
Surface Modification ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Az31 Alloy ◽  
Immersion Test ◽  
Low Ph ◽  
Nacl Solution ◽  
Filiform Corrosion ◽  
A New Technique

A new technique has been developed for improving corrosion resistance on magnesium alloys. Specimens of AZ31 magnesium alloy were dipped into molten salt of NaBF4 at 723 K for various times, and then cooled, rinsed with water, and dried in air. Corrosion resistance in the surface treated specimens was evaluated by salt immersion test using 1 % NaCl solution as a time for occurring filiform corrosion. On an un-treated AZ31 alloy, the time for starting the filiform corrosion was about 1.2 ks, while on the surface treated specimen, the time was prolonged into about 1300 ks. Moreover, the surface treated specimen showed corrosion resistance in low pH solutions, such as 1 % HNO3 and HCl solutions.

scholarly journals Improved Corrosion Resistance of Magnesium Alloy in Simulated Concrete Pore Solution by Hydrothermal Treatment

Scanning ◽  
2020 ◽  
Vol 2020 ◽  
pp. 1-7 ◽  
Author(s):  
Ye Wang ◽  
Guosong Wu ◽  
Jiapeng Sun
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Hydrothermal Treatment ◽  
Building Materials ◽  
Pore Solution ◽  
Chloride Ions ◽  
Al Alloy ◽  
Natural Immunity ◽  
X Ray ◽  
Building Engineering

Magnesium alloys are considered for building materials in this study due to their natural immunity to corrosion in alkaline concrete pore solution. But, chloride ions attack often hinders the application of most metals. Therefore, it is necessary to conduct a preliminary corrosion evaluation and attempt to find an effective way to resist the attack of chloride ions in concrete pore solution. In our study, hydrothermal treatment is carried out to modify Mg-9.3 wt. % Al alloy. After the treatment in NaOH solution for 10 h, scanning electron microscopy (SEM) reveals that a layer of dense coating with a thickness of about 5 μm is formed on Mg alloy. Energy dispersive X-ray spectroscopy (EDS), X-ray photoelectron spectroscopy (XPS), and X-ray Diffraction (XRD) are combined to analyze the coating, and it is thereby confirmed that the coating is mainly composed of Mg(OH)2. As expected, both immersion test and electrochemical corrosion test show that the coated magnesium alloy has a better corrosion resistance than the uncoated one in simulated concrete pore solution with and without chloride ions. In summary, it indicates that hydrothermal treatment is a feasible method to improve the corrosion resistance of Mg alloys used for building engineering from the perspective of corrosion science.

scholarly journals Preparation of medical Mg–Zn alloys and the effect of different zinc contents on the alloy

2022 ◽  
Vol 33 (1) ◽  
Author(s):  
Yunpeng Hu ◽  
Xuan Guo ◽  
Yang Qiao ◽  
Xiangyu Wang ◽  
Qichao Lin
Keyword(s):  
Mechanical Properties ◽  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Corrosion Current Density ◽  
Bending Strength ◽  
Corrosion Current ◽  
Human Bone ◽  
Maximum Compressive Stress ◽  
Good Biocompatibility

AbstractIn recent years, along with the development and application of magnesium alloys, magnesium alloys have been widely used in automotive, aerospace, medicine, sports, and other fields. In the field of medical materials, magnesium not only has the advantage of light weight, high strength, and a density similar to that of human bone, but also has good biocompatibility and promotes the growth of human bone. However, the mechanical properties and corrosion resistance of magnesium alloys need to be further improved to meet the requirements for human biodegradable implants. In this study, three alloys (mass fractions: Mg–10Zn, Mg–20Zn, and Mg–30Zn (wt.%)) were prepared using powder metallurgy by homogeneously mixing powders of the above materials in a certain amount with magnesium as the substrate through the addition of zinc elements, which also have good biocompatibility. The effect of zinc on the microstructure, mechanical properties, wear performance, and corrosion resistance of magnesium–zinc alloys was studied when the zinc content was different. The results show that compared with the traditional magnesium alloy using powder metallurgy, prepared magnesium alloy has good resistance to compression and bending, its maximum compressive stress can reach up to 318.96 MPa, the maximum bending strength reached 189.41 MPa, and can meet the mechanical properties of the alloy as a human bone-plate requirements. On the polarization curve, the maximum positive shift of corrosion potential of the specimens was 73 mv and the maximum decrease of corrosion-current density was 53.2%. From the comparison of the above properties, it was concluded that the three prepared alloys of which Mg–20% Zn had the best overall performance. Its maximum compressive stress, maximum bending strength, and corrosion-current density reached 318.96 MPa, 189.41 MPa and 2.08 × 10−5 A·cm−2 respectively, which are more suitable for use as human implant bone splints in human-body fluid environment.

Controlled release and corrosion protection by self-assembled colloidal particles electrodeposited onto magnesium alloys

2015 ◽  
Vol 3 (8) ◽  
pp. 1667-1676 ◽  
Author(s):  
Jiadi Sun ◽  
Ye Zhu ◽  
Long Meng ◽  
Wei Wei ◽  
Yang Li ◽  
...  
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Controlled Release ◽  
Magnesium Alloys ◽  
Corrosion Protection ◽  
Colloidal Particles ◽  
Self Assembled ◽  
Bioactive Agents

Self-assembled nanoparticles loaded with bioactive agents were electrodeposited to provide the magnesium alloy with controlled release and corrosion resistance properties.

The Superstructure in the a Phase of Silver-Magnesium Alloys

1950 ◽  
Vol 3 (2) ◽  
pp. 284
Author(s):  
LM Clarebrough ◽  
JF Nicholas
Keyword(s):  
Electrical Resistivity ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
X Ray ◽  
Silver Magnesium

X-ray and electrical resistivity studies of a silver-magnesium alloy containing 25 atomic per cent, of magnesium are described. From the results, it is concluded that a superlattice exists at this composition, the order-disorder transformation occurring between 386 and 389 �C.

Corrosion Resistance by Sodium Metavanadate for AZ91D Magnesium Alloy

2014 ◽  
Vol 575 ◽  
pp. 170-174 ◽  
Author(s):  
Toha Nor Fadzilah ◽  
S. Norbahiyah ◽  
Mohd Zain Mohamad Zamzuri
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Oxide Film ◽  
Corrosion Test ◽  
Energy Dispersive Spectrometry ◽  
Optical Microscope ◽  
X Ray ◽  
Sodium Metavanadate ◽  
Az91d Magnesium Alloy ◽  
Polarization Technique

An oxide film was prepared on AZ91D magnesium alloy by anodizing in solution containing sodium metavanadate (NaVO3). The corrosion resistance of the substrate was investigated at a fixed current density 10 mA/cm2for 5 mins with different concentration of solution in the range of 0 – 1.0 g/l. The surface morphology, phase structure and corrosion resistance of oxide film were studied by optical microscope, scanning electron microscope (SEM) and energy dispersive spectrometry (EDS) and X-ray diffractometer (XRD), potentiodynamic polarization technique and corrosion test.

Effects of Erbium Addition on the Corrosion Resistance and Microstructure of AZ91 Magnesium Alloy

2011 ◽  
Vol 194-196 ◽  
pp. 1221-1224 ◽  
Author(s):  
Zhong Jun Wang ◽  
Yang Xu ◽  
Jing Zhu
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Discontinuous Precipitation ◽  
Az91 Magnesium Alloy ◽  
Continuous Precipitation ◽  
Az91 Magnesium ◽  
Precipitation Phase

The microstructures and corrosion resistance of AZ91 and AZ91+0.5 wt.% erbium (Er) magnesium alloys were studied, respectively. The results show that the Er addition in scrap AZ91 magnesium alloy can improve the corrosion resistance, markedly. The discontinuous precipitation phase (DPP) for Mg17Al12was retarded and the amount of DPP was decreased by 41% due to the formation of Al8ErMn4phase during solidification. The amount of continuous precipitation phase (CPP) in grains was decreased by 8% because of the formation of Al7ErMn5phase during solidification.

Corrosion and Protection of Magnesium Alloys

2015 ◽  
Vol 1120-1121 ◽  
pp. 1078-1082 ◽  
Author(s):  
Yang Yang Lv ◽  
Ling Feng Zhang
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Automotive Industry ◽  
Physical And Mechanical Properties ◽  
Current Status ◽  
Strain Rates ◽  
Metallic Materials ◽  
Az91 Magnesium Alloy ◽  
Az91 Magnesium

Magnesium alloy as a green material in the 21st century, because of its excellent physical and mechanical properties of metallic materials as an ideal in the automotive industry, electronic industry and aviation, aerospace and other industries[1]. However, poor corrosion resistance of magnesium alloys become an important issue hinder application of magnesium alloys[2]. So magnesium alloy corrosion problems and the current status of research paper reviews several magnesium alloy protection methods at home and abroad, and also highlighted with our latest laser shock (LSP) study of AZ91 magnesium alloy at high strain rates of corrosion resistance results.

scholarly journals Improvement of bio-compatible AZ61 magnesium alloy corrosion resistance by fluoride conversion coating

2016 ◽  
Vol 60 (5) ◽  
pp. 132-138 ◽  
Author(s):  
J. Drábiková ◽  
F. Pastorek ◽  
S. Fintová ◽  
P. Doležal ◽  
J. Wasserbauer
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Magnesium Alloys ◽  
Simulated Body Fluid Solution ◽  
Conversion Coating ◽  
Az61 Magnesium Alloy ◽  
Wrought Magnesium Alloy ◽  
Consequent Effect ◽  
Materials Used ◽  
Short Time

Abstract Magnesium and its alloys are perspective bio-degradable materials used mainly due to their mechanical properties similar to those of mammal bones. Potential problems in utilization of magnesium alloys as bio-materials may relate to their rapid degradation which is associated with resorption problems and intensive hydrogen evolution. These problems can be eliminated by magnesium alloys surface treatment. Therefore, this work aims with analysis of the influence of fluoride conversion coating on corrosion characteristics of magnesium alloy. Unconventional technique by insertion of wrought magnesium alloy AZ61 into molten Na[BF4] salt at temperature of 450 °C at different treatment times was used for fluoride conversion coating preparation. The consequent effect of the coating on magnesium alloy corrosion was analyzed by means of linear polarization in simulated body fluid solution at 37 ± 2 °C. The obtained results prove that this method radically improve corrosion resistance of wrought AZ61magnesium alloy even in the case of short time of coating preparation.

Laser Cladding of Zr55Al10Ni5Cu30/SiC Amorphous Composite Coatings on AZ91D Magnesium Alloy for Improvement of Corrosion Resistance

2011 ◽  
Vol 179-180 ◽  
pp. 757-761 ◽  
Author(s):  
Kai Jin Huang ◽  
Hou Guang Liu ◽  
Chang Rong Zhou
Keyword(s):  
Corrosion Resistance ◽  
Magnesium Alloy ◽  
Laser Cladding ◽  
Composite Coatings ◽  
Corrosion Property ◽  
Nacl Solution ◽  
X Ray Diffraction ◽  
X Ray ◽  
Good Corrosion Resistance ◽  
Az91d Magnesium Alloy

To improve the corrosion property of magnesium alloys, Zr-based amorphous composite coatings have been fabricated on AZ91D magnesium alloy by laser cladding using mixed powders Zr55Al10Ni5Cu30/SiC. The microstructure of the coating was characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The corrosion resistance of the coatings was tested in 3.5wt.% NaCl solution. The results show that the coatings mainly consist of amorphous and different crystalline phases. The coatings compared with AZ91D magnesium alloy exhibit good corrosion resistance because of the presence of the amorphous phase in the coatings.

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