scholarly journals Cement Equivalence of Metakaolin for Workability, Cohesiveness, Strength and Sorptivity of Concrete

Materials ◽  
2020 ◽  
Vol 13 (7) ◽  
pp. 1646 ◽  
Author(s):  
J.J. Chen ◽  
Q.H. Li ◽  
P.L. Ng ◽  
L.G. Li ◽  
A.K.H. Kwan
Keyword(s):  
Ordinary Portland Cement ◽  
Performance Testing ◽  
Cementitious Materials ◽  
Cementitious Material ◽  
Mix Design ◽  
Cube Strength ◽  
Slump Flow ◽  
Equivalent Mass ◽  
Equivalent Factor ◽  
Strength And Durability

A series of concrete mixes with metakaolin (MK) content ranging from 0 to 30% and water/cementitious materials (W/CM) ratio varying from 0.30 to 0.50 were produced for performance testing. The results showed that adding MK up to 20% as ordinary Portland cement (OPC) replacement best improved the 28-day and 70-day cube strengths, whereas adding MK up to 30% as OPC replacement always increased the cohesiveness and decreased the sorptivity, but impaired the workability. Moreover, the cement equivalent factor (CEF), i.e. the equivalent mass of OPC per mass of MK added, for each performance attribute, including workability and cohesiveness, was evaluated. Whilst the actual CEF of MK was generally higher at a higher W/CM ratio and lower at a higher MK content, overall, the average CEFs were found to be 1.98, 2.17, 3.83, 1.93, 2.12, and 4.70 for slump, flow, cohesiveness, 28-day cube strength, 70-day cube strength, and sorptivity coefficient, respectively. These CEF values indicated that the MK is a highly effective cementitious material for improving the cohesiveness, strength, and durability. Moreover, it has been demonstrated that the CEFs for workability and cohesiveness are useful parameters in aiding the mix design of MK concrete.

Behaviour of different cementitious material formulations in sewer networks

2014 ◽  
Vol 69 (7) ◽  
pp. 1502-1508 ◽  
Author(s):  
J. Herisson ◽  
M. Guéguen-Minerbe ◽  
E. D. van Hullebusch ◽  
T. Chaussadent
Keyword(s):  
Ordinary Portland Cement ◽  
Environmental Parameters ◽  
Cementitious Materials ◽  
Cementitious Material ◽  
Material Degradation ◽  
Protective Mechanisms ◽  
Chemical Mechanisms ◽  
Sewer Network ◽  
Aluminate Cement ◽  
Sewer Networks

Sewer networks are subjected to degradation, including biodeterioration of materials, in the presence of biogenic sulfuric acid, leading to costly repairs. To ensure durable structures, it is essential to select the best adapted materials. Two cementitious materials based on ordinary Portland cement (OPC) or calcium aluminate cement (CAC), were subjected to biodeterioration in the headspace of an operating sewer network. After a few month OPC materials started to deteriorate whereas CAC materials were still intact. The better durability of CAC materials is due to the presence of alumina providing a combination of protective mechanisms. On-site environmental parameters were monitored and analysed in the context of the biological and chemical mechanisms involved in material degradation. These data will eventually feed into the development of a representative, reproducible and accelerated laboratory test.

scholarly journals High Quality Concrete Comprising of Several Mix of ACM’s

2020 ◽  
Vol 16 (1) ◽  
pp. 138-147
Author(s):  
Mohankumar N. Bajad
Keyword(s):  
Concrete Strength ◽  
High Strength ◽  
Cementitious Materials ◽  
Mix Design ◽  
Small Scale ◽  
Chloride Permeability ◽  
High Quality ◽  
Concrete Mix Design ◽  
Granulated Blast Furnace Slag ◽  
Strength And Durability

AbstractConcrete has today requesting execution prerequisites. The concrete strength emergency which started to pull in open consideration constrained the specialists to investigate the strength of concrete. Legitimate mix design and cautious development utilizing the best accessible materials and developments are significant to finish quality concrete structures. In the utmost current decade, the usage of Additional Cementing Materials (ACMs) has become a vital piece of high quality and superior concrete mix design. One of the significant changes is the presentation of small-scale innovation for concrete with fine and ultrafine cementitious materials. It is currently believable to achieve astounding molecule pressing and subsequently conform to the exhibition requests both in new and in the solidified states. In the prevailing examination the ACMs utilized are Fly ash, silica fume, Ground Granulated Blast Furnace Slag and Metakaolin which are prescribed by IS 456:2000 to recover the strength and durability of concrete. This paper shows the presentation of M30 to M90 grade of concrete with superplasticizer utilizing Rapid Chloride Permeability Test. Suitable mix of these ACMs can be utilized practically to advancement the chloride opposition of standard to high strength concrete mixes.

Study on Sulphate Resistance of Often-Used Cementitious Material of High Performance Concrete for Marine

2012 ◽  
Vol 450-451 ◽  
pp. 94-101
Author(s):  
Kun Peng Gu ◽  
Cheng Qi Wang
Keyword(s):  
Corrosion Resistance ◽  
Portland Cement ◽  
High Performance ◽  
Ordinary Portland Cement ◽  
High Performance Concrete ◽  
Cementitious Materials ◽  
Resistance Coefficient ◽  
Cementitious Material ◽  
Corrosion Mechanism ◽  
Better Than

Corrosion resistance coefficient and expansion ratio of different cementitious materials are tested under the sulphate corrosion experimental condition, sulphate resistance of often-used cementitious material of high performance concrete for marine is studied and evaluated. The results show that sulphate resistance of portland cement is better than ordinary portland cement, and both of them are low, often-used cementitious material of high performance concrete for marine have certain sulphate resistance, which are better than ordinary portland cement and portland cement, and some of them have strong or very strong sulphate resistance. The evaluation results of the sulphate resistance of often-used cementitious material of high performance concrete for marine are not unanimous completely by corrosion resistance coefficient method and expansion rate method. Sulphate corrosion mechanism of different kinds of cementitious material is analyzed.

scholarly journals A Review of the Mechanical Properties and Durability of Ecological Concretes in a Cold Climate in Comparison to Standard Ordinary Portland Cement-Based Concrete

Materials ◽  
2020 ◽  
Vol 13 (16) ◽  
pp. 3467
Author(s):  
Ankit Kothari ◽  
Karin Habermehl-Cwirzen ◽  
Hans Hedlund ◽  
Andrzej Cwirzen
Keyword(s):  
Carbon Dioxide ◽  
Portland Cement ◽  
Ordinary Portland Cement ◽  
Cementitious Materials ◽  
Cold Climate ◽  
Supplementary Cementitious Materials ◽  
Short Exposure ◽  
Chemical Admixtures ◽  
Composite Cements ◽  
Alkali Activated

Most of the currently used concretes are based on ordinary Portland cement (OPC) which results in a high carbon dioxide footprint and thus has a negative environmental impact. Replacing OPCs, partially or fully by ecological binders, i.e., supplementary cementitious materials (SCMs) or alternative binders, aims to decrease the carbon dioxide footprint. Both solutions introduced a number of technological problems, including their performance, when exposed to low, subfreezing temperatures during casting operations and the hardening stage. This review indicates that the present knowledge enables the production of OPC-based concretes at temperatures as low as −10 °C, without the need of any additional measures such as, e.g., heating. Conversely, composite cements containing SCMs or alkali-activated binders (AACs) showed mixed performances, ranging from inferior to superior in comparison with OPC. Most concretes based on composite cements require pre/post heat curing or only a short exposure to sub-zero temperatures. At the same time, certain alkali-activated systems performed very well even at −20 °C without the need for additional curing. Chemical admixtures developed for OPC do not always perform well in other binder systems. This review showed that there is only a limited knowledge on how chemical admixtures work in ecological concretes at low temperatures and how to accelerate the hydration rate of composite cements containing high amounts of SCMs or AACs, when these are cured at subfreezing temperatures.

scholarly journals Coupled Preparation of Ferronickel and Cementitious Material from Laterite Nickel Ores

Materials ◽  
2020 ◽  
Vol 13 (21) ◽  
pp. 4992
Author(s):  
Ruimeng Shi ◽  
Xiaoming Li ◽  
Yaru Cui ◽  
Junxue Zhao ◽  
Chong Zou ◽  
...  
Keyword(s):  
Direct Reduction ◽  
Cementitious Materials ◽  
Tricalcium Silicate ◽  
Cementitious Material ◽  
Raw Material ◽  
Tricalcium Aluminate ◽  
Thermodynamic Conditions ◽  
Nickel Ores ◽  
Main Components ◽  
Factsage Software

Nickel slags can be produced through ferronickel preparation by the pyrometallurgical processing of laterite nickel ores; however, such techniques are underutilized at present, and serious environmental problems arise from the stockpiling of such nickel ores. In this study, a modification to the process of ferronickel preparation by the direct reduction of carbon bases in laterite nickel ores is proposed. The gangue from the ore is used as a raw material to prepare a cementitious material, with the main components of tricalcium silicate and tricalcium aluminate. By using FactSage software, thermodynamic calculations are performed to analyze the reduction of nickel and iron and the effect of reduction on the formation of tricalcium silicate and tricalcium aluminate. The feasibility of a coupled process to prepare ferronickel and cementitious materials by the direct reduction of laterite nickel ore and gangue calcination, respectively, is discussed under varying thermodynamic conditions. Different warming strategies are applied to experimentally verify the coupled reactions. The coupled preparation of ferronickel and cementitious materials with calcium silicate and calcium aluminate as the main phases in the same experimental process is realized.

scholarly journals Effect of High-Dispersible Graphene on the Strength and Durability of Cement Mortars

Materials ◽  
2021 ◽  
Vol 14 (4) ◽  
pp. 915
Author(s):  
Xiaoqiang Qi ◽  
Sulei Zhang ◽  
Tengteng Wang ◽  
Siyao Guo ◽  
Rui Ren
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Cement Mortar ◽  
Chloride Ion ◽  
Cementitious Materials ◽  
Chloride Ion Penetration ◽  
Cement Mortars ◽  
Strength And Durability ◽  
Durability Performance

Graphene’s outstanding properties make it a potential material for reinforced cementitious composites. However, its shortcomings, such as easy agglomeration and poor dispersion, severely restrict its application in cementitious materials. In this paper, a highly dispersible graphene (TiO2-RGO) with better dispersibility compared with graphene oxide (GO) is obtained through improvement of the graphene preparation method. In this study, both GO and TiO2-RGO can improve the pore size distribution of cement mortars. According to the results of the mercury intrusion porosity (MIP) test, the porosity of cement mortar mixed with GO and TiO2-RGO was reduced by 26% and 40%, respectively, relative to ordinary cement mortar specimens. However, the TiO2-RGO cement mortars showed better pore size distribution and porosity than GO cement mortars. Comparative tests on the strength and durability of ordinary cement mortars, GO cement mortars, and TiO2-RGO cement mortars were conducted, and it was found that with the same amount of TiO2-RGO and GO, the TiO2-RGO cement mortars have nearly twice the strength of GO cement mortars. In addition, it has far higher durability, such as impermeability and chloride ion penetration resistance, than GO cement mortars. These results indicate that TiO2-RGO prepared by titanium dioxide (TiO2) intercalation can better improve the strength and durability performance of cement mortars compared to GO.

Use of Superpave Technology for Design and Construction of Rubberized Asphalt Mixtures

1997 ◽  
Vol 1583 (1) ◽  
pp. 71-81 ◽  
Author(s):  
H. Barry Takallou ◽  
Hussain U. Bahia ◽  
Dario Perdomo ◽  
Robert Schwartz
Keyword(s):  
Fatigue Behavior ◽  
Permanent Deformation ◽  
Performance Testing ◽  
Fatigue Cracking ◽  
Asphalt Mixtures ◽  
Mix Design ◽  
Asphalt Rubber ◽  
Constant Height ◽  
Overlay Design ◽  
Gyratory Compaction

The effect of different mixing times and mixing temperatures on the performance of asphalt-rubber binder was evaluated. Four different types of asphalt-rubber binders and neat asphalt were characterized using the Strategic Highway Research Program (SHRP) binder method tests. Subsequently, mix designs were carried out using both the SHRP Levels I and II mix design procedures, as well as the traditional Marshall mix design scheme. Additionally, performance testing was carried out on the mixtures using the Superpave repetitive simple shear test at constant height (RSST-CH) to evaluate the resistance to permanent deformation (rutting) of the rubberized asphalt mixtures. Also, six rectangular beams were subjected to repeated bending in the fatigue tester at different microstrain levels to establish rubberized asphalt mixtures’ resistance to fatigue cracking under repeated loadings. The results indicate that the Superpave mix design produced asphalt-rubber contents that are significantly higher than values used successfully in the field. Marshall-used gyratory compaction could not produce the same densification trends. Superpave mixture analysis testing (Level II) was used successfully for rubberized asphalt mixtures. Results clearly indicated that the mixture selected exhibited acceptable rutting and fatigue behavior for typical new construction and for overlay design. Few problems were encountered in running the Superpave models. The results of the RSST-CH indicate that rubber-modified asphalt concrete meets the criteria for a maximum rut depth of 0.5 in.; and more consistent results were measured for fatigue performance analysis using the repeated four-point bending beam testing (Superpave optional torture testing). The cycles to failure were approximately 26,000 at 600 microstrain.

scholarly journals The use of a volcanic material as filler in self-compacting concrete production for lower strength applications

2017 ◽  
Vol 67 (325) ◽  
pp. 111 ◽  
Author(s):  
D. Burgos ◽  
A. Guzmán ◽  
K. M.A. Hossain ◽  
S. Delvasto
Keyword(s):  
Compressive Strength ◽  
Portland Cement ◽  
Cementitious Material ◽  
Total Weight ◽  
Self Compacting Concrete ◽  
Lower Strength ◽  
Volcanic Material ◽  
Fine Powders ◽  
Slump Flow ◽  
Concrete Production

This study evaluates the use of large amounts of fine powders (fillers) derived from a Colombian volcanic material into the production of self-compacting concrete (SCC) for lower strength applications. The effects on SCC properties were studied with the incorporation of up to 50% of volcanic material of Tolima (MVT) as a partial substitute of the total weight of Portland cement. The workability was determined through slump flow, V-funnel, and L-box test. The compressive strength results were analyzed statistically by MINITAB. These demonstrated that 30% (by total weight of cementitious material) was the maximum allowable percentage of MVT to be used in the production of SCCs. Based on this, mechanical and permeability properties of SCC MVT 30% were evaluated at 28, 90 y 360 curing days. SCC MVT 30% exhibited compressive strength of 21 and 27 MPa after 28 and 360 days of curing, respectively.

scholarly journals Rheology, Strength and Durability Characteristics of Alccofine Blended Fibre Reinforced Self Consolidating Concrete

2018 ◽  
Vol 7 (3.12) ◽  
pp. 209
Author(s):  
Bletty Baby ◽  
Jerry Anto ◽  
Basil Johny ◽  
Sreenath S
Keyword(s):  
Steel Fibre ◽  
Flow Characteristics ◽  
Strength Degradation ◽  
Fibre Content ◽  
Split Tensile Strength ◽  
Self Consolidating Concrete ◽  
Slump Flow ◽  
Strength Tests ◽  
Hardened Properties ◽  
Strength And Durability

In this study, observations were made on the effect of blending cement with fly ash and Alccofine on the fresh and hardened properties of micro steel fibre reinforced self-consolidating concrete (SCC). SCC mixes were prepared based on EFNARC guidelines. Blending has been done by replacing 5%, 10% and 15% of cement with Alccofine. Slump flow, L-box and V-funnel tests were conducted to study the flow characteristics of SCC. Compressive strength, split tensile strength, and flexural strength tests were performed to assess the strength characteristics. It was observed that the SCC with 10% replacement of cement with Alccofine showed better results than the other mixes. Further, the modification of the optimum blend with 10% Alccofine was made by adding variable percentages (0.5%, 1% and 1.5% by volume) of micro steel fibres and strength tests were conducted to optimise the fibre content. The strength degradation of the SCC with optimum Alccofine and fibre content exposed to alkaline, chloride and sulphate solutions was also studied.

scholarly journals Influence of Dimethacrylate Monomer on the Polymerization Efficacy of Resin-Based Dental Cements—FTIR Analysis

Polymers ◽  
2022 ◽  
Vol 14 (2) ◽  
pp. 247
Author(s):  
Aleksandra Maletin ◽  
Ivan Ristic ◽  
Tanja Veljovic ◽  
Bojana Ramic ◽  
Tatjana Puskar ◽  
...  
Keyword(s):  
Spectral Analysis ◽  
Clinical Practice ◽  
Chemical Structure ◽  
Cementitious Materials ◽  
Degree Of Polymerization ◽  
Cementitious Material ◽  
Ftir Analysis ◽  
Dental Cement ◽  
Polymerization Mechanism ◽  
The Difference

The degree of polymerization for dimethacrylate resin-based materials (BisGMA, TEGDMA, UDMA, HEMA) ranges from 55 to 75%. Literature data indicate that polymerization efficacy depends, among other factors, on the type of methacrylate resin comprising the material. The aim of this study was to evaluate the polymerization efficacy of four dental cement materials characterized by different polymerization mechanisms using FTIR analysis. In the present study, the FTIR method was adopted to analyze the degree of polymerization efficacy of four resin-based dental cement materials, two of which were self-cured and two were dual-cured cements. The IR spectral analysis was performed 24 h after the polymerization of the cementitious material. RelyX ARC cement exhibits the lowest polymerization efficacy (61.3%), while that of Variolink II (85.8%) and Maxcem Elite is the highest (90.1%). Although the efficacy of self-cured cements appears to be superior, the difference is not statistically significant (p = 0.280). Polymerization efficacy largely depends on the chemical structure of the material in terms of the presence of a particular methacrylate resin and less on the polymerization mechanism itself, i.e., whether it is a self-cured or dually cured dental cement. Thus, in clinical practice, cementitious materials with a higher proportion of TEGDMA compared with BisGMA are recommended.

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