scholarly journals Surface-Initiated Atom Transfer Radical Polymerization for the Preparation of Well-Defined Organic–Inorganic Hybrid Nanomaterials

Materials ◽  
2019 ◽  
Vol 12 (18) ◽  
pp. 3030 ◽  
Author(s):  
Monika Flejszar ◽  
Paweł Chmielarz
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Hybrid Nanomaterials ◽  
Inorganic Hybrid ◽  
Catalyst Complex ◽  
Wide Range ◽  
Potential Applications ◽  
Grafted Nanoparticles ◽  
Reversible Deactivation Radical Polymerization

Surface-initiated atom transfer radical polymerization (SI-ATRP) is a powerful tool that allows for the synthesis of organic–inorganic hybrid nanomaterials with high potential applications in many disciplines. This review presents synthetic achievements and modifications of nanoparticles via SI-ATRP described in literature last decade. The work mainly focuses on the research development of silica, gold and iron polymer-grafted nanoparticles as well as nature-based materials like nanocellulose. Moreover, typical single examples of nanoparticles modification, i.e., ZnO, are presented. The organic–inorganic hybrid systems received according to the reversible deactivation radical polymerization (RDRP) approach with drastically reduced catalyst complex concentration indicate a wide range of applications of materials including biomedicine and microelectronic devices.

Organic-Inorganic Hybrid Polymers from Atom Transfer Radical Polymerization and Poly(dimethylsiloxane)

2000 ◽  
pp. 270-283 ◽  
Author(s):  
Krzysztof Matyjaszewski ◽  
Peter J. Miller ◽  
Guido Kickelbick ◽  
Yoshiki Nakagawa ◽  
Steven Diamanti ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Hybrid Polymers ◽  
Inorganic Hybrid

Fabrication of amphiphilic fluorescent polylysine nanoparticles by atom transfer radical polymerization (ATRP) and their application in cell imaging

RSC Advances ◽  
2015 ◽  
Vol 5 (81) ◽  
pp. 65884-65889 ◽  
Author(s):  
Zengfang Huang ◽  
Xiqi Zhang ◽  
Xiaoyong Zhang ◽  
Shiqi Wang ◽  
Bin Yang ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Cell Imaging ◽  
High Potential ◽  
Atom Transfer ◽  
Potential Applications ◽  
Fluorescent Polymer

A novel amphiphilic Flu-Ply fluorescent polymer was successfully fabricated by ATRP method with high potential applications for bioimaging.

scholarly journals Advances in Internal Plasticization of PVC: Copper-Mediated Atom-Transfer Radical Polymerization from PVC Defect Sites To Form Acrylate Graft Copolymers

Synlett ◽  
2021 ◽  
Author(s):  
Rebecca Braslau ◽  
Longbo Li ◽  
Yanika Schneider ◽  
Adrienne B. Hoeglund
Keyword(s):  
Glass Transition ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Simple Procedure ◽  
Covalent Attachment ◽  
Atom Transfer ◽  
Transition Temperatures ◽  
Glass Transition Temperatures ◽  
Defect Sites ◽  
Wide Range

AbstractInternally plasticized PVC copolymers were prepared by grafting PVC with butyl acrylate and 2-(2-ethoxyethoxy)ethyl acrylate by atom-transfer radical polymerization, resulting in well-behaved polymers with a wide range of glass transition temperatures (–54 °C to 54 °C). When the grafted side chains made up more than 50% of the polymer by weight, the glass transition temperatures were below 0 °C. The covalent attachment of the plasticizing grafts requires one simple procedure starting from commercial PVC, making this strategy an industrially relevant and environmentally friendly alternative to the use of conventional small-molecule plasticizers.

scholarly journals Ultrasound-Mediated Atom Transfer Radical Polymerization (ATRP)

Materials ◽  
2019 ◽  
Vol 12 (21) ◽  
pp. 3600 ◽  
Author(s):  
Izabela Zaborniak ◽  
Paweł Chmielarz
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Industrial Applications ◽  
Polymer Chains ◽  
Advanced Materials ◽  
Atom Transfer ◽  
Molecular Weights ◽  
Current State ◽  
Wide Range ◽  
Complex Architectures

Ultrasonic agitation is an external stimulus, rapidly developed in recent years in the atom transfer radical polymerization (ATRP) approach. This review presents the current state-of-the-art in the application of ultrasound in ATRP, including an initially-developed, mechanically-initiated solution with the use of piezoelectric nanoparticles, that next goes to the ultrasonication-mediated method utilizing ultrasound as a factor for producing radicals through the homolytic cleavage of polymer chains, or the sonolysis of solvent or other small molecules. Future perspectives in the field of ultrasound in ATRP are presented, focusing on the preparation of more complex architectures with highly predictable molecular weights and versatile properties. The challenges also include biohybrid materials. Recent advances in the ultrasound-mediated ATRP point out this approach as an excellent tool for the synthesis of advanced materials with a wide range of potential industrial applications.

scholarly journals End Group Stability of Atom Transfer Radical Polymerization (ATRP)-Synthesized Poly(N-isopropylacrylamide): Perspectives for Diblock Copolymer Synthesis

Polymers ◽  
2019 ◽  
Vol 11 (4) ◽  
pp. 678 ◽  
Author(s):  
Herberg ◽  
Yu ◽  
Kuckling
Keyword(s):  
Mass Spectrometry ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Size Exclusion ◽  
Polymerization Process ◽  
Atom Transfer ◽  
Group Stability ◽  
Catalyst Complex ◽  
End Groups ◽  
End Group

Studies on the end group stability of poly(N-isopropylacrylamide) during the atom transfer radical polymerization (ATRP) process are presented. Polymerization of N-isopropylacrylamide was conducted in different solvents using a copper(I) chloride/Me6Tren catalyst complex. The influence of the ATRP solvent as well as the polymer purification process on the end group stability was investigated. For the first time, mass spectrometry results clearly underline the loss of ω end groups via an intramolecular cyclization reaction. Furthermore, an ATRP system based on a copper(I) bromide/Me6Tren catalyst complex was introduced, that showed not only good control over the polymerization process, but also provided the opportunity of block copolymerization of N-isopropylacrylamide with acrylates and other N-substituted acrylamides. The polymers were characterized using 1H-NMR spectroscopy and size exclusion chromatography. Polymer end groups were determined via ESI-TOF mass spectrometry enhanced by ion mobility separation (IMS).

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