scholarly journals A Strategy to Synthesize Multilayer Graphene in Arc-Discharge Plasma in a Semi-Opened Environment

Materials ◽  
2019 ◽  
Vol 12 (14) ◽  
pp. 2279 ◽  
Author(s):  
Hai Tan ◽  
Deguo Wang ◽  
Yanbao Guo
Keyword(s):  
Discharge Plasma ◽  
Arc Discharge ◽  
Chemical Reduction ◽  
Chemical Properties ◽  
Chemical Vapor ◽  
Chemical Components ◽  
Multilayer Graphene ◽  
Whole Process ◽  
Hazardous Chemical ◽  
Physical And Chemical

Graphene, as the earliest discovered two-dimensional (2D) material, possesses excellently physical and chemical properties. Vast synthetic strategies, including chemical vapor deposition, mechanical exfoliation, and chemical reduction, are proposed. In this paper, a method to synthesize multilayer graphene in a semi-opened environment is presented by introducing arc-discharge plasma technology. Compared with previous technologies, the toxic gases and hazardous chemical components are not generated in the whole process. The synthesized carbon materials were characterized by transmission electron microscopy, atomic force microscopy, X-ray diffraction, and Raman spectra technologies. The paper offers an idea to synthesize multilayer graphene in a semi-opened environment, which is a development to produce graphene with arc-discharge plasma.

Silver Nanoparticles Supported on Ordered Mesoporous Carbon for Formaldehyde Electrooxidation

2011 ◽  
Vol 110-116 ◽  
pp. 508-513
Author(s):  
Ling Bin Kong ◽  
Ru Tao Wang ◽  
Xiao Wei Wang ◽  
Zhen Sheng Yang ◽  
Yong Chun Luo ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Mesoporous Carbon ◽  
Chemical Reduction ◽  
Chemical Properties ◽  
Ordered Mesoporous Carbon ◽  
Alkaline Solutions ◽  
Cyclic Voltammograms ◽  
Peak Current Density ◽  
Ordered Mesoporous ◽  
Physical And Chemical

Metal nanocatalysts, as the anodic materials, have become increasingly important in fuel cells due to their unique physical and chemical properties. Here we report the ordered mesoporous carbon (CMK-3) supported silver nanocatalysts have been prepared through the wet chemical reduction by using the reduction of formaldehyde. The electrochemical properties of the Ag/CMK-3 nanocatalysts for formaldehyde oxidation are studied by cyclic voltammograms (CV) and chronoamperometric curves (i-t) in alkaline aqueous solutions. The results show that the peak current density (from CV) of the Ag/CMK-3 electrode is 112 mA cm-2, above 2 times higher than that of Ag/XC-72 at the same Ag loading (14.15 μg cm-2). Furthermore, the i-t curves demonstrate that the Ag/CMK-3 nanocatalysts are efficient and stable electrocatalysts for anodic oxidation of formaldehyde in alkaline solutions. Our results indicate that the application potential of Ag/CMK-3 nanocatalysts with the improved electrocatalytic activity has far reaching effects on fuel cells and sensors.

Triclinic boron nanosheets high-efficient electrocatalysts for water splitting

2021 ◽  
Author(s):  
Maoping Xu ◽  
Rui Wang ◽  
Kan Bian ◽  
Chuang Hou ◽  
Yaxing Wu ◽  
...  
Keyword(s):  
Active Sites ◽  
Theoretical Calculations ◽  
Chemical Properties ◽  
Chemical Vapor ◽  
Energy Storage And Conversion ◽  
High Efficient ◽  
Long Time ◽  
Time Cycle ◽  
Metal Properties ◽  
Physical And Chemical

Abstract Recently, two-dimensional (2D) boron nanosheets have been predicted to exhibit exceptional physical and chemical properties, which is expected to be widely used in advanced electronics, optoelectronic, energy storage and conversion devices. However, the experimental application of 2D boron nanosheets in hydrogen evolution reactiuon (HER) has not been reported. Here, we have grown ultrathin boron nanosheets on tungsten foils via chemical vapor deposition (CVD). The prepared triclinic boron nanosheets are highly crystalline, which perfectly match the structure in the previous theoretical calculations. Notably, the boron nanosheets show excellent HER performance. The Tafel slope is only 64 mV/dec-1 and the nanosheets can maintain good stability under long-time cycle in acidic solution. The improvement of performance is mainly due to the metal properties and a large number of exposed active sites on the boron nanosheets, which is confirmed by first-principle calculations.

scholarly journals Modelling of Time-Dependent Wellbore Collapse in Hard Brittle Shale Formation under Underbalanced Drilling Condition

Geofluids ◽  
2019 ◽  
Vol 2019 ◽  
pp. 1-21
Author(s):  
Shanpo Jia ◽  
Zhiqiang Xiao ◽  
Bisheng Wu ◽  
Caoxuan Wen ◽  
Lufeng Jia
Keyword(s):  
Immersion Time ◽  
Progressive Failure ◽  
Drilling Fluid ◽  
Progressive Collapse ◽  
Failure Process ◽  
Chemical Properties ◽  
Whole Process ◽  
Drilling Condition ◽  
Shale Formation ◽  
Physical And Chemical

In recent years, the lithologic traps in a mid-depth formation are the focus of oil or gas exploration and development for eastern oilfields in China. The Shahejie Formation develops thick hard brittle shale, and the wellbore instability problem is prominent due to obvious hydration effect for long immersion time during drilling. Through the analysis of laboratory tests and field test results of physical and chemical properties and microstructure and mechanical properties of hard brittle shale, the instability mechanism is discussed for the wellbore in the shale formation. To simulate the whole process of progressive collapse of a wellbore in a hard brittle shale formation, a coupled hydraulic-mechanical-chemical (HMC) model is developed and this model is compiled with ABAQUS software as the solver. Then the coupled HMC model is applied to simulate the progressive evolution process of wellbore collapse in a hard brittle shale formation, and the influence of different parameters on the progressive failure of the wellbore is analysed. The results show that the wellbore enlargement rate increases with the drilling fluid immersion time and the influence of different parameters on the wellbore enlargement rate is different. The water absorption diffusion coefficient and the activity of the drilling fluid have the most obvious influence on the expansion of the wellbore, and the sensitivity is strong. The permeability of shale has little effect on the wellbore enlargement rate. The calculated progressive failure process of the wellbore is basically consistent with that of the actual drilling.

Graphene Research in China

2013 ◽  
Vol 1505 ◽  
Author(s):  
Kexin Chen
Keyword(s):  
Chemical Properties ◽  
Chemical Vapor ◽  
Dimensional Structure ◽  
Chemical Vapor Deposition Growth ◽  
Wide Range ◽  
The Status ◽  
Potential Applications ◽  
Number Of Publications ◽  
Physical And Chemical ◽  
And Chemical Properties

ABSTRACTGraphene, a monolayer of sp2-bonded carbon atoms, has been attracting worldwide interests because of its unique two-dimensional structure, various fascinating properties and a wide range of intriguing potential applications. The graphene research is very active in China and has been developing rapidly in the past few years, which covers nearly all the areas related to graphene including theories, synthesis, physical and chemical properties, and applications. Over 100 research institutions have been involved in graphene research with fast-growing project supports. In this paper, the status of graphene research in China is first discussed based on the number of publications and patents as well as the institutions involved. Then the projects and fundings from both government and companies for graphene research are briefly introduced. Finally, the highlights of graphene research in China are reviewed, which include chemical vapor deposition growth and transfer, mass production, and assembly of graphene, and its applications in energy storage, sensing, composites and solar cells.

Polluted aquifers: identification and characterisation by statistical analysis

2010 ◽  
Vol 61 (2) ◽  
pp. 331-337 ◽  
Author(s):  
Analía Boemo ◽  
Haydée Musso ◽  
Irene Lomniczi
Keyword(s):  
Principal Component Analysis ◽  
Hierarchical Clustering ◽  
Chemical Properties ◽  
Principal Component ◽  
Component Analysis ◽  
Underground Water ◽  
Chemical Components ◽  
Eastern Area ◽  
Western Area ◽  
Physical And Chemical

Hierarchical clustering and principal component analysis applied to chemical components and physicochemical properties of well water proved to be a useful tool for identification and characterisation of aquifers. Underground water of Lerma Valley (Salta, Argentina) was examined for its physical and chemical properties by sampling 46 wells located in two adjacent areas separated by hills, one of them polluted with boron since 1991. Hierarchical clustering splits sampled sites into two main clusters, corresponding to the two areas, establishing the fact that the aquifers should be considered as two different entities in spite of their common recharge area. Values of boron concentration in the eastern area decreased in most of the wells since the pollution sources were eradicated, while four of them experienced a substantial increase, proof of the slow self-recovery of the aquifer. The use of principal component analysis provided evidence of the incipient boron pollution of the aquifer of the western area.

Plasma-Activated CVD for the Production of Protective Layers in Optics, Electronics and Mechanical Engineering

1987 ◽  
Vol 93 ◽  
Author(s):  
Knut Enke ◽  
Michael Geisler ◽  
Jörg Kieser ◽  
Wolf-Dieter Münz
Keyword(s):  
Chemical Properties ◽  
Chemical Vapor ◽  
Capacitive Coupling ◽  
Plasma Cvd ◽  
Cathode Voltage ◽  
Protective Layers ◽  
Deposition Parameters ◽  
Metal Organic ◽  
Organic Process ◽  
Physical And Chemical

ABSTRACTConventional chemical vapor deposition (CVD) has historically utilized high melting temperature substrates. Recently there has been an increased desire to coat temperaturesensitive materials such as aluminum, glass, steel, and even plastic. Thus “cold” CVDprocesses, most using plasma excitation, have been developed. In these processes gas molecules or atoms are excited by dc or ac glow discharge, thereby allowing the possibility of keeping substrates at room temperature.This paper describes plasma CVD reactors using capacitive coupling of r.f. voltage to an asymmetrical arrangement of electrodes. Using organic or metal-organic process gases and mixtures of them with inorganic gases, deposition takes place on the reactor walls, the anode, and the cathode. In this paper the emphasis is on deposition on negatively selfbiased substrate holders. Physical and chemical properties of plasma-CVD grown layers depend on about six process parameters, the most important of which are cathode voltage, gas pressure, choice of gases, and mixing ratio of gases. Map-like representations show the dependence of coating properties on deposition parameters. Layer materials discussed include amorphous hydrogenated carbon (a-C:H). WCx, SiOx:H, SiCxOy:H. and SnOx:H.

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