scholarly journals Potential of Briquette Produced with Torrefied Agroforestry Biomass to Generate Energy

Forests ◽  
2020 ◽  
Vol 11 (12) ◽  
pp. 1272
Author(s):  
Gabriel Reis Portilho ◽  
Vinicius Resende de Castro ◽  
Angélica de Cássia Oliveira Carneiro ◽  
José Cola Zanuncio ◽  
Antonio José Vinha Zanuncio ◽  
...  
Keyword(s):  
Energy Density ◽  
Sugarcane Bagasse ◽  
Compaction Pressure ◽  
Calorific Value ◽  
High Energy ◽  
Raw Material ◽  
High Energy Density ◽  
Fixed Carbon ◽  
Volatile Material ◽  
Material Content

Agroforestry industries, such as sugar-alcohol, food, and logging, produce large quantities of waste, used to generate energy from direct burning. The application of other processes, such as torrefaction and briquetting, can increase the profits from the use of agro-industrial waste for energy generation. Briquetting is an alternative for using these wastes, allowing the compaction of the biomass, generating a biofuel with high energy density, and which is more homogeneous and easier to store and transport. The objective of this study was to evaluate the physical and chemical properties of four biomass types (wastes from sawed eucalypt and pine wood, coffee pruning wastes, and sugarcane bagasse) torrefied at 300 °C and compacted (briquetting) at pressures of 6.21, 8.27, and 10.34 MPa. The torrefaction increased the fixed carbon content, ash, and calorific value, and reduced the volatile material content and hygroscopic equilibrium moisture of the biomasses. The volatile material content was lower and the fixed carbon higher in the coffee pruning waste, the ash content higher in the sugarcane bagasse, and the calorific value higher in the pine and eucalypt wood. The briquetting and the torrefaction processes increased the biomass bulk density, and the useful calorific value, respectively, and consequently the energy density of the briquettes produced with torrefied raw material under high pressure. The mechanical properties of the briquettes produced with all materials increased with the compaction pressure. Torrefaction and briquetting increased the energy potential of the biomasses evaluated to produce energy from clean technology.

scholarly journals Exploring the Economic Potential of Sodium-Ion Batteries

Batteries ◽  
2019 ◽  
Vol 5 (1) ◽  
pp. 10 ◽  
Author(s):  
Jens Peters ◽  
Alexandra Peña Cruz ◽  
Marcel Weil
Keyword(s):  
Energy Density ◽  
High Energy ◽  
Sodium Ion ◽  
Raw Material ◽  
High Energy Density ◽  
Carbon Anode ◽  
Sodium Ion Batteries ◽  
Hard Carbon ◽  
Promising Alternative ◽  
Material Costs

Sodium-ion batteries (SIBs) are a recent development being promoted repeatedly as an economically promising alternative to lithium-ion batteries (LIBs). However, only one detailed study about material costs has yet been published for this battery type. This paper presents the first detailed economic assessment of 18,650-type SIB cells with a layered oxide cathode and a hard carbon anode, based on existing datasheets for pre-commercial battery cells. The results are compared with those of competing LIB cells, that is, with lithium-nickel-manganese-cobalt-oxide cathodes (NMC) and with lithium-iron-phosphate cathodes (LFP). A sensitivity analysis further evaluates the influence of varying raw material prices on the results. For the SIB, a cell price of 223 €/kWh is obtained, compared to 229 €/kWh for the LFP and 168 €/kWh for the NMC batteries. The main contributor to the price of the SIB cells are the material costs, above all the cathode and anode active materials. For this reason, the amount of cathode active material (e.g., coating thickness) in addition to potential fluctuations in the raw material prices have a considerable effect on the price per kWh of storage capacity. Regarding the anode, the precursor material costs have a significant influence on the hard carbon cost, and thus on the final price of the SIB cell. Organic wastes and fossil coke precursor materials have the potential of yielding hard carbon at very competitive costs. In addition, cost reductions in comparison with LIBs are achieved for the current collectors, since SIBs also allow the use of aluminum instead of copper on the anode side. For the electrolyte, the substitution of lithium with sodium leads to only a marginal cost decrease from 16.1 to 15.8 €/L, hardly noticeable in the final cell price. On the other hand, the achievable energy density is fundamental. While it seems difficult to achieve the same price per kWh as high energy density NMC LIBs, the SIB could be a promising substitute for LFP cells in stationary applications, if it also becomes competitive with LFP cells in terms of safety and cycle life.

TORREFACTION OF PALM BIOMASS BRIQUETTES AT DIFFERENT TEMPERATURE

2016 ◽  
Vol 78 (9-2) ◽  
Author(s):  
Hasan Mohd Faizal ◽  
M. Amin M. Jusoh ◽  
Mohd Rosdzimin Abdul Rahman ◽  
S. Syahrullail ◽  
Z. A. Latiff
Keyword(s):  
Moisture Content ◽  
Carbon Content ◽  
Compaction Pressure ◽  
Calorific Value ◽  
High Energy ◽  
Fixed Carbon ◽  
Gross Calorific Value ◽  
Fresh Fruit Bunch ◽  
Combustion Properties ◽  
Fixed Carbon Content

The climate change has driven towards transformation from the high energy dependence on fossil fuel to inexhaustible renewable energy such as solar, wind, mini hydro and biomass. In Malaysia, abundant of palm biomass residues are produced during the processing of fresh fruit bunch. Therefore it is inevitable to harness these bioenergy sources in order to prevent waste accumulation at adjacent to palm mills. In order to utilize such bioenergy sources and to cope with the fast growing demand of energy, combination technique of densification and torrefaction is one of the potential ways to be practised. In the present study, the physical and combustion properties of torrefied empty  fruit bunch (EFB) briquettes were investigated experimentally with constant nitrogen flow rate of 1 l/min , for various torrefaction temperatures (225-300). Before torrefaction process, EFB briquettes were initially produced under controlled condition with compaction pressure of 7 MPa and briquetting temperature of 150. In general, the torrefied EFB briquettes were successfully produced in the present study. The results show that an increase in torrefaction temperature from 225  to 300  causes a significant increase in gross calorific value (from around 17400 kJ/kg to 25000 kJ/kg), fixed carbon content (from 16.2% to 46.2%) and ash content (from 2.4% to 17.2%). On the other hand, relaxed density and volatile matter decrease, from 1017 kg/m3 to 590 kg/m3 and from 73.1% to 29.7%, respectively. As a conclusion, the gross calorific value and fixed carbon content are improved due to torrefaction. In addition, it was found that gross calorific value and moisture content of the torrefied EFB briquettes fulfil the requirement for commercial briquette production as stated by DIN51731 (gross calorific value>17500 kJ/kg and moisture content <10%). 

scholarly journals EFFECT OF PLANTING AGE AND SPACING ON ENERGY PROPERTIES OF Eucalyptus grandis W. Hill EX Maiden

2016 ◽  
Vol 40 (4) ◽  
pp. 749-758 ◽  
Author(s):  
Elder Eloy ◽  
Dimas Agostinho da Silva ◽  
Denise Schmidt ◽  
Rômulo Trevisan ◽  
Braulio Otomar Caron ◽  
...  
Keyword(s):  
Energy Density ◽  
Eucalyptus Grandis ◽  
Basic Density ◽  
Calorific Value ◽  
Ash Content ◽  
Fixed Carbon ◽  
Volatile Material ◽  
Gross Calorific Value ◽  
Energy Productivity ◽  
Fixed Carbon Content

ABSTRACT This study aimed to determine the effect of planting age and spacing on energy properties of different compartments of the biomass of Eucalyptus grandis W. Hill ex Maiden, disseminated in different spacings: 2.0 x 1.0 m, 2.0 x 1.5 m, 3.0 x 1.0 m e 3.0 x 1.5 m, in the 1st, 3rd and 5th year after the planting. The present study was carried out as an experiment installed in an experimental design of randomized complete blocks in three replications. Variables determined were Biomass (BIO), Gross Calorific Value (GCV), Basic Density (BD), Energy Productivity (EP), Energy Density (ED), Fixed Carbon Content (FCC), Volatile Material Content (VMC), and Ash Content (AC). Ages have an effect on all studied variables, and in the 5th year after planting, the largest BIO, EP, BD, ED and FCC values are checked. The planting spacings induce different productions of BIO and EP, with a trend towards lower values with increasing planting spacing in all assessed periods. The compartments of trees influence BIO, GCV, FCC, VMC and AC variables. Regarding to energy, the higher the age and lower the planting spacing, the better the energy properties of biomass.

scholarly journals Physical, mechanical and energy characterization of wood pellets obtained from three common tropical species

PeerJ ◽  
2018 ◽  
Vol 6 ◽  
pp. e5504 ◽  
Author(s):  
Carrillo Parra Artemio ◽  
Ngangyo Heya Maginot ◽  
Colín-Urieta Serafín ◽  
Foroughbakhch Pournavab Rahim ◽  
Rutiaga Quiñones José Guadalupe ◽  
...  
Keyword(s):  
Energy Density ◽  
Resistance Index ◽  
Calorific Value ◽  
High Energy ◽  
Volatile Matter ◽  
Proximate Analysis ◽  
High Energy Density ◽  
Tropical Species ◽  
Wood Pellets ◽  
Material Sources

Background The need for energy sources with low greenhouse gas emissions and sustainable production encourages the search for alternative biomass sources. However, the use of biomass fuels faces the problem of storage, transport and lower energy densities. Low-density values can negatively affect energy density, leading to an increase in transportation and storage costs. Use of pellets as alternative biomass source is a way to reduce the volume of biomass by densification, which improves their energy quality. They are produced by diverse biomass resources and mainly from wood materials. In all cases, it is important to evaluate the fuel characteristics, to determine their suitability on the heating system and handling properties. Methods The present study determines and compares data from proximate analysis, calorific values, physical and mechanical properties of wood pellets produced from the common tropical species Acacia wrightii, Ebenopsis ebano and Havardia pallens. Data were obtained from pellets produced from each species chips collected from an experimental plantation and analyzed through ANOVA and Kruskal–Wallis test at 0.05 significance level. Results The results of diameter, length and length/diameter ratio didn’t show statistical differences (p > 0.05) among species. Acacia wrightii showed the highest density (1.2 g/cm3). Values on weight retained and compression test showed statistical differences (p = 0.05) among species. Havardia pallens was more resistant to compression strength than A. wrightii and Ebenopsis ebano. Statistical differences (p < 0.01) were also observed for the volatile matter and calorific value. E. ebano has the lowest volatile matter (72%), highest calorific value (19.6 MJ/kg) as well as the fixed carbon (21%). Discussion The pellets of the species studied have a high energy density, which makes them suitable for both commercial and industrial heating applications.A pellet with low compression resistance tends to disintegrate easily, due to moisture adsorption. The percentages obtained for the resistance index were higher than 97.5%, showing that the pellets studied are high-quality biofuels. Proximate analysis values also indicate good combustion parameters. Pellets of Acacia wrightii and Ebenopsis ebano are the more favorable raw material sources for energy purposes because of their high density, calorific value, low ash content and they also met majority of the international quality parameters.

A HIGH ENERGY DENSITY ZINC/OXYGEN BATTERY SYSTEM

1966 ◽  
Author(s):  
S. CHODOSH ◽  
E. KATSOULIS ◽  
M. ROSANSKY
Keyword(s):  
Energy Density ◽  
High Energy ◽  
High Energy Density ◽  
Battery System

Efficient Co-Harvesting of Solar Energy and Low-Grade Heat by Molecular Photoswitches for High Energy Density, Long-Term Stable Solar Thermal Battery

2019 ◽  
Author(s):  
Zhao-Yang Zhang ◽  
Tao LI
Keyword(s):  
Energy Density ◽  
Solar Energy ◽  
High Performance ◽  
High Energy ◽  
Solar Thermal ◽  
High Energy Density ◽  
Low Grade ◽  
Thermal Battery ◽  
Low Grade Heat

Solar energy and ambient heat are two inexhaustible energy sources for addressing the global challenge of energy and sustainability. Solar thermal battery based on molecular switches that can store solar energy and release it as heat has recently attracted great interest, but its development is severely limited by both low energy density and short storage stability. On the other hand, the efficient recovery and upgrading of low-grade heat, especially that of the ambient heat, has been a great challenge. Here we report that solar energy and ambient heat can be simultaneously harvested and stored, which is enabled by room-temperature photochemical crystal-to-liquid transitions of small-molecule photoswitches. The two forms of energy are released together to produce high-temperature heat during the reverse photochemical phase change. This strategy, combined with molecular design, provides high energy density of 320-370 J/g and long-term storage stability (half-life of about 3 months). On this basis, we fabricate high-performance, flexible film devices of solar thermal battery, which can be readily recharged at room temperature with good cycling ability, show fast rate of heat release, and produce high-temperature heat that is >20<sup> o</sup>C higher than the ambient temperature. Our work opens up a new avenue to harvest ambient heat, and demonstrate a feasible strategy to develop high-performance solar thermal battery.

Efficient Co-Harvesting of Solar Energy and Low-Grade Heat by Molecular Photoswitches for High Energy Density, Long-Term Stable Solar Thermal Battery

2019 ◽  
Author(s):  
Zhao-Yang Zhang ◽  
Tao LI
Keyword(s):  
Energy Density ◽  
Solar Energy ◽  
High Performance ◽  
High Energy ◽  
Solar Thermal ◽  
High Energy Density ◽  
Low Grade ◽  
Thermal Battery ◽  
Low Grade Heat

Solar energy and ambient heat are two inexhaustible energy sources for addressing the global challenge of energy and sustainability. Solar thermal battery based on molecular switches that can store solar energy and release it as heat has recently attracted great interest, but its development is severely limited by both low energy density and short storage stability. On the other hand, the efficient recovery and upgrading of low-grade heat, especially that of the ambient heat, has been a great challenge. Here we report that solar energy and ambient heat can be simultaneously harvested and stored, which is enabled by room-temperature photochemical crystal-to-liquid transitions of small-molecule photoswitches. The two forms of energy are released together to produce high-temperature heat during the reverse photochemical phase change. This strategy, combined with molecular design, provides high energy density of 320-370 J/g and long-term storage stability (half-life of about 3 months). On this basis, we fabricate high-performance, flexible film devices of solar thermal battery, which can be readily recharged at room temperature with good cycling ability, show fast rate of heat release, and produce high-temperature heat that is >20<sup> o</sup>C higher than the ambient temperature. Our work opens up a new avenue to harvest ambient heat, and demonstrate a feasible strategy to develop high-performance solar thermal battery.

Si Nanowire Anode Prepared by Chemical Etching for High Energy Density Lithium-ion Battery

2013 ◽  
Vol 28 (11) ◽  
pp. 1207-1212 ◽  
Author(s):  
Jian-Wen LI ◽  
Ai-Jun ZHOU ◽  
Xing-Quan LIU ◽  
Jing-Ze LI
Keyword(s):  
Energy Density ◽  
Lithium Ion Battery ◽  
Chemical Etching ◽  
Lithium Ion ◽  
High Energy ◽  
High Energy Density ◽  
Si Nanowire
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