scholarly journals Effect of KyAl4(Si8-y) O20(OH)4 Calcined Based-Clay on the Microstructure and Mechanical Performances of High-Performance Concrete

Crystals ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 1152
Author(s):  
David O. Nduka ◽  
Babatunde J. Olawuyi ◽  
Olabosipo I. Fagbenle ◽  
Belén G. Fonteboa

The work described in this paper has been performed to determine the potential use of meta-illite (KyAl4(Si8-y) O20(OH)4) calcined clay (MCC) as a supplementary cementitious material (SCM) in a binary Portland cement (PC) for high-performance concrete (HPC) production. To obtain the properties of the cementitious materials, the chemical composition, mineral phases, morphology, calcination efficiency and physical properties were quantitatively analysed using the advanced techniques of X-ray fluorescence (XRF), scanning electron microscopy/energy dispersive X-ray (SEM/EDX), X-ray diffraction (XRD), Fourier transform infrared/attenuated total reflection (FTIR/ATR), thermogravimetric analysis (TGA), laser particle sizing and Brunauer–Emmett–Teller (BET) nitrogen absorption method. The MCC’s effect on the workability and mechanical properties (compressive, splitting tensile and flexural strengths) and microstructure (morphology and crystalline phases) of hardened MCC-based HPCs were determined. The XRF result shows that the oxide composition of MCC confirmed the pozzolanic material requirements with recorded high useful oxides content. At the same time, the SEM image presents particles of broad, solid masses with a wider surface area of irregular shape. The XRD results show that the MCC was majorly an illite-based clay mineral calcined at a maximum temperature of 650 °C, as revealed by the TGA. The MCC addition increases the slump flow of HPCs at 5–15% cement replacement. The MCC incorporation at 10% cement replacement best improved the porosity of HPCs at a later age resulting in increased mechanical and microstructural properties of tested samples. Therefore, it is recommended that MCC addition within 10% cement replacement be adopted for low W/B Class I HPC at no deleterious results on mechanical and microstructural properties of the concrete.

Crystals ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 75
Author(s):  
David O. Nduka ◽  
Babatunde J. Olawuyi ◽  
Olabosipo I. Fagbenle ◽  
Belén G. Fonteboa

The present study examines the durability properties of Class 1 (50–75 MPa) high-performance concrete (HPC) blended with rice husk ash (RHA) as a partial replacement of CEM II B-L, 42.5 N. Six HPC mixes were prepared with RHA and used as 5%, 10%, 15%, 20%, 25%, and 30% of CEM II alone and properties are compared with control mix having only CEM II. The binders (CEM II and RHA) were investigated for particle size distribution (PSD), specific surface area (SSA), oxide compositions, mineralogical phases, morphology, and functional groups using advanced techniques of laser PSD, Brunauer–Emmett–Teller (BET), X-ray fluorescence (XRF), X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared/attenuated total reflection (FTIR/ATR), respectively, to understand their import on HPC. Durability properties, including water absorption, sorptivity, and chemical attack of the HPC samples, were investigated to realise the effect of RHA on the HPC matrix. The findings revealed that the durability properties of RHA-based HPCs exhibited an acceptable range of values consistent with relevant standards. The findings established that self-produced RHA would be beneficial as a cement replacement in HPC. As the RHA is a cost-effective agro-waste, a scalable product of RHA would be a resource for sustainable technology.


Cerâmica ◽  
2017 ◽  
Vol 63 (367) ◽  
pp. 387-394 ◽  
Author(s):  
T. M. Mendes ◽  
W. L. Repette ◽  
P. J. Reis

Abstract The use of nanoparticles in ultra-high strength concretes can result in a positive effect on mechanical performance of these cementitious materials. This study evaluated mixtures containing 10 and 20 wt% of silica fume, for which the optimum nano-silica content was determined, i.e. the quantity of nano-silica that resulted on the higher gain of strength. The physical characterization of raw materials was done in terms of particle size distribution, density and specific surface area. Chemical and mineralogical compositions of materials were obtained through fluorescence and X-ray diffraction. The mechanical performance was evaluated by compressive strength, flexural strength and dynamic elastic modulus measurements. The microstructural analysis of mixtures containing nano-silica was performed by X-ray diffraction, thermogravimetry, mercury intrusion porosimetry and scanning electron microscopy. Obtained results indicate an optimum content of nano-silica of 0.62 wt%, considering compressive and flexural strengths. This performance improvement was directly related to two important microstructural aspects: the packing effect and pozzolanic reaction of nano-silica.


Materials ◽  
2021 ◽  
Vol 14 (1) ◽  
pp. 215
Author(s):  
Dong Lu ◽  
Jing Zhong ◽  
Baobao Yan ◽  
Jing Gong ◽  
Ziye He ◽  
...  

It has been reported that iron tailing powder (ITP) has the potential to partially replace cement to prepare ultra-high-performance concrete (UHPC). However, the reactivity of ITP particles in concrete largely depends on the curing method. This study investigates the effects of curing conditions on the mechanical and microstructural properties of UHPC containing ITP. To achieve this objective, three research tasks are conducted, including (1) preparing seven concrete formulations by introducing ITP; (2) characterizing their mechanical performance under different curing regimes; and (3) analyzing their microstructure by XRD patterns, FTIR analysis, and SEM observation. The experimental results show that there is an optimum ITP dosage (15%) for their application. The concrete with 15% ITP under standard curing obtains 94.3 MPa at 7 days, their early-age strength could be even further increased by ~30% (warm-water curing) and ~35% (steamed curing). The steam curing regime stimulates the activity of ITP and refines the microstructure. This study demonstrates the potential of replacing Portland cement with ITP in UHPC production.


Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3781
Author(s):  
Tianyu Wang ◽  
Yahong Zhao ◽  
Baosong Ma ◽  
Cong Zeng

The acid–alkaline-inducd corrosive environments inside wastewater concrete pipelines cause concrete structural deterioration and substantial economic losses all over the world. High-performance concrete/mortar (HPC) was designed to have better resistance to corrosive environments, with enhanced service life. However, the durability of HPC in wastewater pipeline environments has rarely been studied. A high-performance mortar mixture (M) reinforced by supplemental materials (including fly ash and silica fume) and polyvinyl alcohol (PVA) fibers, together with a mortar mixture (P) consisting of cement, sand and water with similar mechanical performance, were both designed and exposed to simulated wastewater pipeline environments. The visual appearance, dimensional variation, mass loss, mechanical properties, permeable pore volume, and microstructure of the specimens were measured during the corrosion cycles. More severe deterioration was observed when the alkaline environment was introduced into the corrosion cycles. Test results showed that the M specimens had less permeable pore volume, better dimensional stability, and denser microstructure than the P specimens under acid–alkaline-induced corrosive environments. The mass-loss rates of the M specimens were 66.1–77.2% of the P specimens after 12 corrosion cycles. The compressive strength of the M specimens was 25.5–37.3% higher than the P specimens after 12 cycles under corrosive environments. Hence, the high-performance mortar examined in this study was considered superior to traditional cementitious materials for wastewater pipeline construction and rehabilitation.


2015 ◽  
Vol 21 (3) ◽  
Author(s):  
Lenka Scheinherrová ◽  
Anton Trník ◽  
Tereza Kulovaná ◽  
Pavel Reiterman ◽  
Igor Medveď ◽  
...  

2013 ◽  
Vol 634-638 ◽  
pp. 2738-2741
Author(s):  
Wei Huang ◽  
Tao Zhang ◽  
Yun Yun Xu

Concrete autogenous shrinkage phenomenon would adversely affect the mechanical properties and durability of concrete, this phenomenon is important. Autogenous shrinkage problem of low water-cement ratio of the with high mineral admixtures, cement-based cementitious materials was introduced. The main reason for high-performance concrete early cracking being autogenous shrinkage was pointed out. Based on the home and abroad research status of low water cement ratio of the cement paste and concrete autogenous shrinkage, especially for early autogenous shrinkage phenomenon, the mechanism of autogenous shrinkage and the measure method is presented, and the improvement measures and the possible problems the need for further research work is presented.


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