scholarly journals Fabrication of Nanosize ZnO and Zn1−xFexO Powder for Infrared Absorption by Flame Aerosol Synthesis

Crystals ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 904
Author(s):  
Hui Tian ◽  
Lei Wang ◽  
Taisheng Yang ◽  
Zili Zhang

In this study, nanosized ZnO and Zn1−xFexO powders were synthesized using the flame aerosol synthesis (FAS) method. The microstructure of the ZnO powder shows a significant difference with different precursor concentrations. By adding Fe to the precursor, nanosized Zn1−xFexO powder (x = 0~0.1) can be easily fabricated. The phase formation, microstructure, and infrared absorption properties were systematically investigated by XRD, SEM, TEM, and IR. With the substitution of Fe into the Zn site, lattice distortion occurred, resulting in excellent infrared absorption properties. Compared to other conventional synthesis methods, the FAS method has the advantages of high yield, high crystallinity, and low cost; furthermore, nanosized powder is easily obtained. The FAS method is believed to be one of the best choices for the large-scale production of ZnO and Zn1−xFexO powders.

2011 ◽  
Vol 311-313 ◽  
pp. 2106-2109
Author(s):  
Xi Mei Liu ◽  
Yu Hu ◽  
Li Hua Feng

An efficient and practical protocol for the preparation of 1,3-diallyloxy-2-propanol has been developed by one-pot reaction between epichlorohydrin and allyl alcohol in the presence of KOH without solvent at room temperature. This preliminary approach provides an environmentally-friendly synthetic route to 1,3-diallyloxy-2-propanol with many advantages, i. e., low cost, high yield, easy purification, mild reaction conditions, and large scale production.


Materials ◽  
2021 ◽  
Vol 14 (7) ◽  
pp. 1706
Author(s):  
Zacharias Viskadourakis ◽  
Argiri Drymiskianaki ◽  
Vassilis M. Papadakis ◽  
Ioanna Ioannou ◽  
Theodora Kyratsi ◽  
...  

In the current study, polymer-based composites, consisting of Acrylonitrile Butadiene Styrene (ABS) and Bismuth Antimony Telluride (BixSb2−xTe3), were produced using mechanical mixing and hot pressing. These composites were investigated regarding their electrical resistivity and Seebeck coefficient, with respect to Bi doping and BixSb2-xTe3 loading into the composite. Experimental results showed that their thermoelectric performance is comparable—or even superior, in some cases—to reported thermoelectric polymer composites that have been produced using other complex techniques. Consequently, mechanically mixed polymer-based thermoelectric materials could be an efficient method for low-cost and large-scale production of polymer composites for potential thermoelectric applications.


2020 ◽  
Author(s):  
Diletta Morelli Venturi ◽  
Filippo Campana ◽  
Fabio Marmottini ◽  
Ferdinando Costantino ◽  
Luigi Vaccaro

<p>Zirconium based Metal-Organic Framework UiO-66 is to date considered one of the benchmark compound among stable MOFs and it has attracted a huge attention for its employment in many strategic applications. Large scale production of UiO-66 for industrial purposes requires the use of safe and green solvents, fulfilling the green chemistry principles and able to replace the use of <i>N,N</i>-Dimethyl-Formamide (DMF), which, despite its toxicity, is still considered the most efficient solvent for obtaining UiO-66 of high quality. Herein we report on a survey of about 40 different solvents with different polarity, boiling point and acidity, used for the laboratory scale synthesis of high quality UiO-66 crystals. The solvents were chosen according the European REACH Regulation 1907/2006 among those having low cost, low toxicity and fully biodegradable. Concerning MOF synthesis, the relevant parameters chosen for establishing the quality of the results obtained are the degree are the crystallinity, microporosity and specific surface area, yield and solvent recyclability. Taking into account also the chemical physical properties of all the solvents, a color code was assigned in order to give a final green assessment for the UiO-66 synthesis. Defectivity of the obtained products, the use of acidic modulators and the use of alternative Zr-salts have been also taken into consideration. Preliminary results lead to conclude that GVL (γ-valerolactone) is among the most promising solvents for replacing DMF in UiO-66 MOF synthesis. </p>


2021 ◽  
Vol 2115 (1) ◽  
pp. 012026
Author(s):  
Sonam Solanki ◽  
Gunendra Mahore

Abstract In the current process of producing vermicompost on a large-scale, the main challenge is to keep the worms alive. This is achieved by maintaining temperature and moisture in their living medium. It is a difficult task to maintain these parameters throughout the process. Currently, this is achieved by building infrastructure but this method requires a large initial investment and long-run maintenance. Also, these methods are limited to small-scale production. For large-scale production, a unit is developed which utilises natural airflow with water and automation. The main aim of this unit is to provide favourable conditions to worms in large-scale production with very low investment and minimum maintenance in long term. The key innovation of this research is that the technology used in the unit should be practical and easy to adopt by small farmers. For long-term maintenance of the technology lesser number of parts are used.


2020 ◽  
Author(s):  
Diletta Morelli Venturi ◽  
Filippo Campana ◽  
Fabio Marmottini ◽  
Ferdinando Costantino ◽  
Luigi Vaccaro

<p>Zirconium based Metal-Organic Framework UiO-66 is to date considered one of the benchmark compound among stable MOFs and it has attracted a huge attention for its employment in many strategic applications. Large scale production of UiO-66 for industrial purposes requires the use of safe and green solvents, fulfilling the green chemistry principles and able to replace the use of <i>N,N</i>-Dimethyl-Formamide (DMF), which, despite its toxicity, is still considered the most efficient solvent for obtaining UiO-66 of high quality. Herein we report on a survey of about 40 different solvents with different polarity, boiling point and acidity, used for the laboratory scale synthesis of high quality UiO-66 crystals. The solvents were chosen according the European REACH Regulation 1907/2006 among those having low cost, low toxicity and fully biodegradable. Concerning MOF synthesis, the relevant parameters chosen for establishing the quality of the results obtained are the degree are the crystallinity, microporosity and specific surface area, yield and solvent recyclability. Taking into account also the chemical physical properties of all the solvents, a color code was assigned in order to give a final green assessment for the UiO-66 synthesis. Defectivity of the obtained products, the use of acidic modulators and the use of alternative Zr-salts have been also taken into consideration. Preliminary results lead to conclude that GVL (γ-valerolactone) is among the most promising solvents for replacing DMF in UiO-66 MOF synthesis. </p>


2020 ◽  
Vol 21 (13) ◽  
pp. 4808 ◽  
Author(s):  
Simon Gutbier ◽  
Florian Wanke ◽  
Nadine Dahm ◽  
Anna Rümmelin ◽  
Silke Zimmermann ◽  
...  

Tissue-resident macrophages are key players in inflammatory processes, and their activation and functionality are crucial in health and disease. Numerous diseases are associated with alterations in homeostasis or dysregulation of the innate immune system, including allergic reactions, autoimmune diseases, and cancer. Macrophages are a prime target for drug discovery due to their major regulatory role in health and disease. Currently, the main sources of macrophages used for therapeutic compound screening are primary cells isolated from blood or tissue or immortalized or neoplastic cell lines (e.g., THP-1). Here, we describe an improved method to employ induced pluripotent stem cells (iPSCs) for the high-yield, large-scale production of cells resembling tissue-resident macrophages. For this, iPSC-derived macrophage-like cells are thoroughly characterized to confirm their cell identity and thus their suitability for drug screening purposes. These iPSC-derived macrophages show strong cellular identity with primary macrophages and recapitulate key functional characteristics, including cytokine release, phagocytosis, and chemotaxis. Furthermore, we demonstrate that genetic modifications can be readily introduced at the macrophage-like progenitor stage in order to interrogate drug target-relevant pathways. In summary, this novel method overcomes previous shortcomings with primary and leukemic cells and facilitates large-scale production of genetically modified iPSC-derived macrophages for drug screening applications.


RSC Advances ◽  
2015 ◽  
Vol 5 (47) ◽  
pp. 37830-37836 ◽  
Author(s):  
Wei Wei ◽  
Linlin Guo ◽  
Xiaoyang Qiu ◽  
Peng Qu ◽  
Maotian Xu ◽  
...  

Although many routes have been developed that can efficiently improve the electrochemical performance of LiFePO4 cathodes, few of them meet the urgent industrial requirements of large-scale production, low cost and excellent performance.


2015 ◽  
Vol 1116 ◽  
pp. 45-50
Author(s):  
Tarek I.A. Mashreki ◽  
Mohammad Afzaal

Nanocomposites containing inorganic semiconductor nanomaterials are of tremendous interest for low-cost 3rd generation solar cells. A variety of possible materials and structures could be potentially used to reduce processing costs which is highly attractive for large scale production of solar cells. Controlling the morphology and surface chemistry of nanomaterials remains a key challenge that has major knock-on effects in devices. Herein, an attempt is made to highlight some of the challenges and the possible solutions for depositing high quality thin film composites for solar cell devices.


CrystEngComm ◽  
2018 ◽  
Vol 20 (21) ◽  
pp. 2989-2995 ◽  
Author(s):  
Weikun Chen ◽  
Pinqiang Dai ◽  
Chunfu Hong ◽  
Chan Zheng ◽  
Weiguo Wang ◽  
...  

We demonstrate a green method based on sonochemistry for large-scale production of akaganéite nanoparticles and assemblies in low cost.


2021 ◽  
Vol 20 (1) ◽  
Author(s):  
Alejandro Torres-Haro ◽  
Jorge Verdín ◽  
Manuel R. Kirchmayr ◽  
Melchor Arellano-Plaza

AbstractAstaxanthin is a carotenoid with a number of assets useful for the food, cosmetic and pharmaceutical industries. Nowadays, it is mainly produced by chemical synthesis. However, the process leads to an enantiomeric mixture where the biologically assimilable forms (3R, 3′R or 3S, 3′S) are a minority. Microbial production of (3R, 3′R) astaxanthin by Xanthophyllomyces dendrorhous is an appealing alternative due to its fast growth rate and easy large-scale production. In order to increase X. dendrorhous astaxanthin yields, random mutant strains able to produce from 6 to 10 mg/g dry mass have been generated; nevertheless, they often are unstable. On the other hand, site-directed mutant strains have also been obtained, but they increase only the yield of non-astaxanthin carotenoids. In this review, we insightfully analyze the metabolic carbon flow converging in astaxanthin biosynthesis and, by integrating the biological features of X. dendrorhous with available metabolic, genomic, transcriptomic, and proteomic data, as well as the knowledge gained with random and site-directed mutants that lead to increased carotenoids yield, we propose new metabolic engineering targets to increase astaxanthin biosynthesis.


Sign in / Sign up

Export Citation Format

Share Document