scholarly journals Angle-Resolved Photoemission Study on the Band Structure of Organic Single Crystals

Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 773
Author(s):  
Ke Wang ◽  
Ben Ecker ◽  
Yongli Gao

Angle-resolved photoemission spectroscopy (ARPES) is a vital technique, collecting data from both the energy and momentum of photoemitted electrons, and is indispensable for investigating the electronic band structure of solids. This article provides a review on ARPES studies of the electronic band structure of organic single crystals, including organic charge transfer conductors; organic semiconductors; and organo-metallic perovskites. In organic conductors and semiconductors, band dispersions are observed that are highly anisotropic. The Van der Waals crystal nature, the weak electron wavefunction overlap, as well as the strong electron-phonon coupling result in many organic crystals having indiscernible dispersion. In comparison, organo-metallic perovskite halides are characterized by strong s-p orbitals from the metal and halide at the top of the valence bands, with dispersions similar to those in inorganic materials.

2002 ◽  
Vol 507-510 ◽  
pp. 223-228 ◽  
Author(s):  
L. Plucinski ◽  
T. Strasser ◽  
B.J. Kowalski ◽  
K. Rossnagel ◽  
T. Boetcher ◽  
...  

2020 ◽  
Vol 8 (27) ◽  
pp. 9090-9132 ◽  
Author(s):  
Yasuo Nakayama ◽  
Satoshi Kera ◽  
Nobuo Ueno

Methodologies and experimental achievements for exploration into electronic band structures of organic semiconductor and hybrid perovskite single crystals are reviewed.


1987 ◽  
Vol 36 (9) ◽  
pp. 4681-4691 ◽  
Author(s):  
P. A. P. Lindberg ◽  
P. L. Wincott ◽  
L. I. Johansson ◽  
A. N. Christensen

2018 ◽  
Vol 924 ◽  
pp. 239-244 ◽  
Author(s):  
Walter M. Klahold ◽  
Wolfgang J. Choyke ◽  
Robert P. Devaty

We use thick, relatively high purity 4H SiC boule material to measure the wavelength modulated absorption spectrum with improved wavelength resolution and sensitivity with respect to previous work. We observe several small 0.6 ± 0.1 meV splittings, which we attribute to electron mass anisotropy and electron-hole exchange interaction. In addition, we identify several features in the absorption spectrum as signatures of nonparabolicity in the free exciton dispersion relations, the primary origin of which is likely the nonparabolic energy dispersion of the valence bands, as revealed by published band structure calculations based on density functional theory.


2013 ◽  
Vol 88 (15) ◽  
Author(s):  
C. Coletti ◽  
S. Forti ◽  
A. Principi ◽  
K. V. Emtsev ◽  
A. A. Zakharov ◽  
...  

1987 ◽  
Vol 192 (2-3) ◽  
pp. 353-365 ◽  
Author(s):  
P.A.P. Lindberg ◽  
L.I. Johansson ◽  
A.N. Christensen

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