scholarly journals Graphene Nanoplatelets Impact on Concrete in Improving Freeze-Thaw Resistance

2019 ◽  
Vol 9 (17) ◽  
pp. 3582 ◽  
Author(s):  
Guofang Chen ◽  
Mingqian Yang ◽  
Longjun Xu ◽  
Yingzi Zhang ◽  
Yanze Wang

Graphene nanoplatelets (GNP) is a newly nanomaterial with extraordinary properties. This paper investigated the effect of GNP on the addition on freeze–thaw (F–T) resistance of concrete. In this experimental study, water to cement ratio remained unchanged, a control mixture without GNP materials and the addition of GNP was ranging from 0.02% to 0.4% by weight of ordinary Portland cement was prepared. Specimens were carried out by the rapid freeze-thaw test, according to the current Chinese standard. The workability, compressive strength, visual deterioration and mass loss of concrete samples were evaluated. Scanning electron microscopy also applied in order to investigate the micromorphology inside of the concrete. The results showed that GNP concrete has a finer pore structure than ordinary concrete; moreover, the workability of GNP concrete reduced, and the compressive strength of specimens was enhanced within the appropriate range of GNP addition; in addition, GNP concrete performed better than the control concrete in the durability of concrete exposed to F-T actions. Specimens with 0.05% GNP exhibited the highest compressive property after 200 F–T cycles compared with other samples.

2016 ◽  
Vol 2016 ◽  
pp. 1-9 ◽  
Author(s):  
Ming-kai Zhou ◽  
Zhan-ao Liu ◽  
Xiao Chen

The influences of fines content, methylene blue (MB) value, and lithology of crushed sand (CS) on frost durability and strength of concrete were investigated, and the frost durability and strength of crushed sand concrete (CSC) and river sand concrete (RSC) were compared. The results show that inclusion of fines improves CSC compressive strength and reduces frost durability of C30 CSC when fines content reaches 10%, whereas it has little negative influence on frost durability of C60 CSC. Increasing MB value does not negatively affect compressive strength of C30 CSC but decreases compressive strength of C60 CSC and frost durability of CSC, and the reduction is more pronounced when MB value exceeds 1.0. Lithology has no prominent influence on frost durability and compressive strength of CSC within the lithologies (dolomite, limestone, granite, basalt, and quartz) studied. Though compressive strength of CSC is a little higher than RSC under equal water to cement ratio, frost durability of CSC is no better than RSC especially for C30 CSC, and air-entraining agent is suggested for enhancing frost durability of C30 CSC exposed to freezing environment.


Author(s):  
Xiaosa Yuan ◽  
Li Zhang ◽  
Xinxiao Chen ◽  
Fang Liu

Abstract To study the effects of graphene oxide (GO), fly ash, and steel fiber on the mechanical properties and durability of concrete, the mechanical properties, frost resistance, and internal pore structure of modified concrete are investigated by compression tests, freeze–thaw cycle tests, and industrial computed tomography (CT) tests. The test results show that the compressive strength of concrete with GO is better than that of mixed concrete, concrete mixed with only steel fiber, and ordinary concrete. Further, it is strongest at all ages when the GO content is 0.03%; the compressive strength of mixed concrete with 30% of fly ash is generally better than that with 15% and 45% of fly ash. In general, the frost resistance of concrete with only GO is better than that of ordinary concrete. With the increase in fly ash content, the internal porosity of concrete decreases, and its compressive strength increases accordingly; as GO increases, the porosity decreases and then increases, with the lowest porosity and the highest compressive strength of concrete at 0.03% of GO. With an increase in porosity, the mass loss and relative dynamic elastic modulus of concrete increase after 100 freeze–thaw cycles, which indicates that porosity directly affects the frost resistance of concrete.


Materials ◽  
2019 ◽  
Vol 12 (10) ◽  
pp. 1619 ◽  
Author(s):  
Yawen Tan ◽  
Huaxin Chen ◽  
Zhendi Wang ◽  
Cheng Xue ◽  
Rui He

Modified cement mortar was prepared by incorporating a superabsorbent polymer (SAP) with two kinds of dosing state, dry powdery SAP and swelled SAP (where the SAP has been pre-wetted in tap water), respectively. The mechanical properties, drying shrinkage and freeze–thaw resistance of the mortars were compared and analyzed with the variation of SAP content and entrained water-to-cement ratios. Additionally, the effect of SAP on the microstructure of mortar was characterized by scanning electron microscopy (SEM). The results indicate that agglomerative accumulation is formed in the voids of mortar after water desorption from SAP and there are abundant hydration products, most of which are C-S-H gels, around the SAP voids. The incorporation of the powdery SAP increases the 28 d compressive strength of the mortars by about 10% to 50%, while for the incorporation of swelled SAP, the 28 d compressive strength of the mortar can be increased by about −26% to 6%. At a dosage of 0.1% SAP and an entrained water–cement ratio of 0.06, the powdery SAP and the swelled SAP can reduce the mortar shrinkage rate by about 32.2% and 14.5%, respectively. Both the incorporation of powdery and swelled SAP has a positive effect on the freeze–thaw resistance of cement mortar. In particular, for powdery SAP with an entrained water-to-cement ratio of 0.06, the mass loss rate after 300 cycles is still lower than 5%.


2012 ◽  
Vol 548 ◽  
pp. 48-53
Author(s):  
Y.M. Liew ◽  
H. Kamarudin ◽  
A.M. Mustafa Al Bakri ◽  
M. Binhussain ◽  
Luqman Musa ◽  
...  

This paper describes the synthesis of calcined kaolin geopolymeric powder from the alkaline activation of calcined kaolin followed by solidification and pulverizing process. The geopolymeric powder was used by just adding water to produce resulted geopolymer paste. In this paper, the effect of water-to-geopolymeric powder ratios on the properties of the resulted geopolymer paste was studied. This water-to-geopolymer powder ratio was similar to that of water-to-cement ratio in the case of ordinary Portland cement (OPC). However, the concept used here was based on geopolymerization process. The compressive strength, setting time and SEM analysis of the resulted geopolymer pastes were conducted. Highest strength was achieved at water-to-geopolymer powder ratio of 0.22. The resulted geopolymer paste could be handled up to 120 minutes and reached final setting after about 4 hours of setting. Microstructure showed the formation of geopolymeric gel after the addition of water to the geopolymeric powder.


2013 ◽  
Vol 6 (1) ◽  
pp. 50-61
Author(s):  
Amer M. Ibrahem ◽  
Shakir A. Al-Mishhadani ◽  
Zeinab H.Naji

This investigation aimed to study the effect of nano metakaolin ( NMK ) on some properties (compressive strength ,splitting tensile strength & water absorption ) of concrete. The nano metakaolin (NMK) was prepared by thermal activation of kaolin clay for 2 hours at 750 Ċ. The cement used in this investigation consists of ordinary Portland cement (OPC). The OPC was partially substituted by NMK of ( 3, 5 & 10%) by weight of cement. The C45 concrete was prepared , using water/cement ratio ( W/c) of (0.53) .The Water absorption was tested at 28 days while the tests (compressive strength ,splitting tensile strength) were tested at ages of (7, 28, 60,& 90) days . The compressive strength and splitting tensile strength of concrete with NMK were higher than that of reference concrete with the same W/c ratio.The improvement in the compressive strength when using NMK was (42.2, 55.8 , 63.1% ) at age 28 days for ( 3%, 5%, &10% ) replacement of NMK respectively whereas the improvement in the splitting tensile strength was (0% , 36% & 46.8 %) at age of 28 days when using (3%, 5%, &10% ) NMK respectively. The improvement in the water absorption was (16.6%, 21.79%, &25.6 ) when using (3, 5, &10% )NMK.


1990 ◽  
Vol 17 (1) ◽  
pp. 102-112
Author(s):  
T. Rezansoff ◽  
D. Stott

The influence of CaCl2 or a chloride-based accelerating admixture on the freeze–thaw resistance of concrete was evaluated. Three air entrained mix designs were investigated using ASTM C666-84, Standard Test Method for Resistance of Concrete to Rapid Freezing and Thawing. All mix designs were similar, using cement contents of 340–357 kg/m3 of concrete, except for the addition of either 2% calcium chloride or 2% High Early Pozzolith, while no accelerating admixture was added to the control mix. The entire test program was repeated four times with water-to-cement ratio of 0.46 and three times with the ratio of 0.43. For the Pozzolith-accelerated concrete, half the samples were coated with boiled linseed oil in all seven series. For the control (unaccelerated) concrete, half the samples were coated with boiled linseed oil in one series for each water-to-cement ratio. Performance was monitored using the dynamic modulus of elasticity as obtained from transverse resonant frequency measurements. Weight loss of the specimens was also measured. Only the control samples (no accelerators) showed sufficient durability to satisfy the standard of maintaining at least 60% of the original dynamic modulus after 300 cycles of alternate freezing and thawing. Sealing with linseed oil showed inconsistent improvement in the durability in the various test series when defined in terms of the dynamic modulus; however, weight losses were the lowest of all categories and surface scaling was minimal. Key words: concrete, durability, freeze–thaw testing, calcium chloride, admixtures, sealants, air void system.


2021 ◽  
Vol 888 ◽  
pp. 67-75
Author(s):  
Ariel Verzosa Melendres ◽  
Napoleon Solo Dela Cruz ◽  
Araceli Magsino Monsada ◽  
Rolan Pepito Vera Cruz

Chloride ingress into concrete from the surrounding environment can result in the corrosion of the embedded steel reinforcement and cause damage to the concrete. Superabsorbent polymer (SAP) with fine particle size was incorporated into the structure of concrete for controlling the chloride ingress and improving its compressive strength via promotion of internal curing. The SAP used in this study was evaluated for its absorbency property when exposed to cementitious environment such as aqueous solution of Ca (OH)2 and cement slurry. The results were compared to that in sodium chloride solution, the environment where absorbency of most of the SAP found in the market are well studied. Results showed that although SAP absorbency decreased with increasing concentration of Ca (OH)2 and cement, the results suggest that water containing cementitious materials are able to be absorbed by SAP. Chloride ingress into 28-day cured concrete specimens were determined using Rapid Chloride Penetration Test (RCPT) method employing 60V DC driving force. Concrete samples with size of 50 mm height x 100 mm diameter were prepared using a M25 mix design with 0.4 and 0.45 water to cement ratios and different percentages of SAP such as 0.05%, 0.1% and 0.15% with respect to cement mass. Results showed that concrete with 0.15% SAP gave the best result with 14% less chloride permeability than concrete with no SAP for a 0.4 water to cement ratio. Concrete samples for compressive strength tests with size of 200 mm height x 100 mm diameter were prepared using the same mix design and percentages of SAP and cured for 28 days. Results showed that the best results for compressive strength was found at 0.1% SAP at a 0.4 water to cement ratio which can be attributed to internal curing provided by SAP.


2018 ◽  
Vol 203 ◽  
pp. 06001
Author(s):  
Muhammad Bilal Waris ◽  
Hussain Najwani ◽  
Khalifa Al-Jabri ◽  
Abdullah Al-Saidy

To manage tyre waste and conserve natural aggregate resource, this research investigates the use of waste tyre rubber as partial replacement of fine aggregates in non-structural concrete. The research used Taguchi method to study the influence of mix proportion, water-to-cement ratio and tyre rubber replacement percentage on concrete. Nine mixes were prepared with mix proportion of 1:2:4, 1:5:4 and 1:2.5:3; water-to-cement ratio of 0.25, 0.35 and 0.40 and rubber to fine aggregate replacement of 20%, 30% and 40%. Compressive strength and water absorption tests were carried out on 100 mm cubes. Compressive strength was directly proportional to the amount of coarse aggregate in the mix. Water-to-cement ratio increased the strength within the range used in the study. Strength was found to be more sensitive to the overall rubber content than the replacement ratio. Seven out of the nine mixes satisfied the minimum strength requirement for concrete blocks set by ASTM. Water absorption and density for all mixes satisfied the limits applicable for concrete blocks. The study indicates that mix proportions with fine to coarse aggregate ratio of less than 1.0 and w/c ratio around 0.40 can be used with tyre rubber replacements of up to 30 % to satisfy requirements for non-structural concrete.


2013 ◽  
Vol 795 ◽  
pp. 664-668 ◽  
Author(s):  
Roshasmawi Abdul Wahab ◽  
Mohd Noor Mazlee ◽  
Shamsul Baharin Jamaludin ◽  
Khairul Nizar Ismail

In this study, the mixing of polystyrene (PS) beads and fly ash as a sand replacement material in foamed cement composites (FCC) has been investigated. Specifically, the mechanical properties such as compressive strength and flexural strength were measured. Different proportions of fly ash were added in cement composites to replace the sand proportion at 3 wt. %, 6 wt. %, 9 wt. % and 12 wt. % respectively. The water to cement ratio was fixed at 0.65 meanwhile ratios of PS beads used was 0.25 volume percent of samples as a foaming agent. All samples at different mixed were cured at 7 and 28 days respectively. Based on the results of compressive strength, it was found that the compressive strength was increased with the increasing addition of fly ash. Meanwhile, flexural strength was decreased with the increasing addition of fly ash up to 9 wt. %. The foamed cement composites with 12 wt. % of fly ash produced the highest strength of compressive strength meanwhile 3 wt. % of fly ash produced the highest strength of flexural strength.


2012 ◽  
Vol 2 (1) ◽  
pp. 21-28
Author(s):  
R. G. Solís ◽  
E. Moreno ◽  
E. Arjona

RESUMENLa resistencia del concreto depende de la calidad de la pasta de cemento y de las características de los agregados pétreos. La primera es controlada por la relación agua - cemento, mientras que las propiedades de los agregados generalmente no pueden ser manipuladas ya que se suele utilizar aquellos que están disponibles cerca de la construcción. En muchas regiones rocas con propiedades no deseables son utilizadas como agregado. Por lo tanto, el objetivo de este trabajo fue responder a la pregunta sobre cuál sería la máxima resistencia de diseño que se podría utilizar para concretos fabricados con un tipo específico de agregados obtenidos a partir de la trituración de roca caliza de alta absorción. Se probaron concretos con seis relaciones agua - cemento y dos tamaños de agregado grueso. Se concluyó que con los agregados estudiados es posible fabricar concretos de hasta 500 k/cm2 de f’c.Palabras clave: Absorción; agregados calizos; concreto; relación agua/cemento; resistencia.ABSTRACTConcrete strength depends on the cement paste quality and on the characteristics of the aggregates. The former is controlled by the water to cement ratio, while the properties of the aggregate, in general, cannot be manipulated as it is customary to employ the ones available near the construction site. In many regions rocks with no desirable properties are employed as aggregates. Therefore, the aim of this study was to answer the question about what would that be the maximum compressive strength attainable in concrete made with a specific type of aggregate obtained from crushed limestone of high absorption. Concrete mixtures involved six water to cement ratios and two sizes of coarse aggregate. It was concluded that with this type of aggregate it is possible to made concrete with compressive strength up to 500 k/cm2 of f’c.Key words: Absorption; compressive strength; concrete; limestone aggregate; water/cement ratio.


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