scholarly journals Comparison between OCl−-Injection and In Situ Electrochlorination in the Formation of Chlorate and Perchlorate in Seawater

2019 ◽  
Vol 9 (2) ◽  
pp. 229 ◽  
Author(s):  
Jongchan Yi ◽  
Yongtae Ahn ◽  
Moongi Hong ◽  
Gi-Hyeon Kim ◽  
Nisha Shabnam ◽  
...  

To prevent biofouling from occurring in the cooling systems of coastal power plants, chlorine is often added to the cooling water. In this study, we have evaluated the fate of the total residual oxidants and the formation of inorganic chlorination byproducts including ClO3− and ClO4− during in situ electrochlorination with seawater. Then, the results were compared with those during direct OCl−-injection to seawater. The in situ electrochlorination method based on Ti/RuO2 electrodes produced much less ClO3−, while a similar level of total residual oxidants could be achieved with a reaction time of 5 min. Moreover, no ClO4− was observed, while the direct OCl−-injection system could still result in the production of ClO4−. The less or no production of ClO3− or ClO4− by the electrochlorination of seawater was mainly attributed to two reasons. First, during the electrolysis, the less amount of OCl− is available for ClO3− formation. Secondly, the formation of ClO3− or ClO4− is affected by the electrode material. In other words, if the electrode material is carefully chosen, the production of harmful reaction byproducts can be prevented or minimized. In short, based on the results from our study, electrochlorination technology proves to be a marine environmentally friendly method for controlling biofouling in the pipes of the cooling system in a coastal power plant.

1983 ◽  
Vol 15 (10) ◽  
pp. 15-30
Author(s):  
R. Gasparini

This paper resumés some of the main findings and conclusions of a study group on cooling water problems (1) set up by UNIPEDE (2). The paper represents only the personal point of view of the author, in particular as chairman of the above mentioned group. The basic aim of the work was the study of the effects of the discharge of cooling water in the receiving water bodies (rivers, lakes and coastal waters). This type of assessment permits a more balanced and pragmatic approach to aspects such as thermal pollution, entrainment, impingement and pollution by antifouling agents. The first part of the paper deals with the problem of damage to organisms entering a cooling system. An important factor in assessing the meaning of such aspect is the growing evidence that there is no reduction in fish population of the receiving water body associated with the operation of modern power plants despite the catch in the once through-cooling systems due to entrainment and impingement, that can be minimized, but not avoided. The second part deals with the different methods of fouling prevention in power plants, with their possible environmental effects in the receiving water bodies. The third part is a comprehensive review of the results of aquatic impact studies at power plants, that is the results of many experimental investigations carried out in the field to evaluate the effects of the operation of once through cooling systems sited on rivers, lakes, or coastal waters.


2020 ◽  
pp. 75-86
Author(s):  
Sergio Antonio Camargo ◽  
Lauro Correa Romeiro ◽  
Carlos Alberto Mendes Moraes

The present article aimed to test changes in cooling water temperatures of males, present in aluminum injection molds, to reduce failures due to thermal fatigue. In order to carry out this work, cooling systems were studied, including their geometries, thermal gradients and the expected theoretical durability in relation to fatigue failure. The cooling system tests were developed with the aid of simulations in the ANSYS software and with fatigue calculations, using the method of Goodman. The study of the cooling system included its geometries, flow and temperature of this fluid. The results pointed to a significant increase in fatigue life of the mold component for the thermal conditions that were proposed, with a significant increase in the number of cycles, to happen failures due to thermal fatigue.


Author(s):  
Nicola Palestra ◽  
Giovanna Barigozzi ◽  
Antonio Perdichizzi

The paper presents the results of an investigation on inlet air cooling systems based on cool thermal storage, applied to combined cycle power plants. Such systems provide a significant increase of electric energy production in the peak hours; the charge of the cool thermal storage is performed instead during the night time. The inlet air cooling system also allows the plant to reduce power output dependence on ambient conditions. A 127MW combined cycle power plant operating in the Italian scenario is the object of this investigation. Two different technologies for cool thermal storage have been considered: ice harvester and stratified chilled water. To evaluate the performance of the combined cycle under different operating conditions, inlet cooling systems have been simulated with an in-house developed computational code. An economical analysis has been then performed. Different plant location sites have been considered, with the purpose to weigh up the influence of climatic conditions. Finally, a parametric analysis has been carried out in order to investigate how a variation of the thermal storage size affects the combined cycle performances and the investment profitability. It was found that both cool thermal storage technologies considered perform similarly in terms of gross extra production of energy. Despite this, the ice harvester shows higher parasitic load due to chillers consumptions. Warmer climates of the plant site resulted in a greater increase in the amount of operational hours than power output augmentation; investment profitability is different as well. Results of parametric analysis showed how important the size of inlet cooling storage may be for economical results.


Author(s):  
Alan J. Bilanin ◽  
Andrew E. Kaufman ◽  
Warren J. Bilanin

Boiling Water Reactor pressure suppression pools have stringent housekeeping requirements, as well as restrictions on amounts and types of insulation and debris that can be present in the containment, to guarantee that suction strainers that allow cooling water to be supplied to the reactor during a Loss of Coolant Accident remain operational. By introducing “good debris” into the cooling water, many of these requirements/restrictions can be relaxed without sacrificing operational readiness of the cooling system.


2012 ◽  
Vol 16 (suppl. 2) ◽  
pp. 375-385 ◽  
Author(s):  
Mirjana Lakovic ◽  
Slobodan Lakovic ◽  
Milos Banjac

The paper presents a theoretical analysis of the cooling system of a 110 MW coal-fired power plant located in central Serbia, where eight evaporative towers cool down the plant. An updated research on the evaporative tower cooling system has been carried out to show the theoretical analysis of the tower heat and mass balance, taking into account the sensible and latent heat exchanged during the processes which occur inside these towers. Power plants which are using wet cooling towers for cooling condenser cooling water have higher design temperature of cooling water, thus the designed condensing pressure is higher compared to plants with a once-through cooling system. Daily and seasonal changes further deteriorate energy efficiency of these plants, so it can be concluded that these plants have up to 5% less efficiency compared to systems with once-through cooling. The whole analysis permitted to evaluate the optimal conditions, as far as the operation of the towers is concerned, and to suggest an improvement of the plant. Since plant energy efficiency improvement has become a quite common issue today, the evaluation of the cooling system operation was conducted under the hypothesis of an increase in the plant overall energy efficiency due to low cost improvement in cooling tower system.


2013 ◽  
Vol 34 (2) ◽  
pp. 253-267 ◽  
Author(s):  
Aiman Eid Al-Rawajfeh ◽  
Kamal Araj

Scaling and corrosion associated with the use of natural hard water in cooling towers during recirculation pose great problems from both economical and technical points of view, such as decreased system efficiency and increased frequency of chemical cleaning. Treated municipal wastewater (MWW) is a promising alternative to freshwater as power plant cooling system makeup water, especially in arid regions. In this work, hybrid systems of salt precipitation (SP), nanofiltration (NF) and reverse osmosis (RO) were investigated, as potential pretreatment processes for wastewater reuse as cooling water in the planned Jordan nuclear power plants. The As-Samra wastewater was used to calculate the potential of carbonate and sulfate scale formation. The results were compared to scale potentials from Palo Verde wastewater. Four cases were investigated; SP, NF, SP-RO and NF-RO. The SP pretreatment cases showed the highest monovalent to divalent ratio because of a high removal of Ca and Mg and addition of Na from the chemicals of the SP step. The NF pretreatment cases, showed the lowest calcium sulfate scale potential and this potential decreases with the % pretreatment. The scale amount increases very slightly with concentration times when the SP and NF product is desalinated by RO step.


Author(s):  
Dominik von Lavante ◽  
Dietmar Kuhn ◽  
Ernst von Lavante

The present paper describes a back-fit solution proposed by RWE Technology GmbH for adding passive cooling functions to existing nuclear power plants. The Fukushima accidents have high-lighted the need for managing station black-out events and coping with the complete loss of the ultimate heat sink for long time durations, combined with the unavailability of adequate off-site supplies and adequate emergency personnel for days. In an ideal world, a nuclear power plant should be able to sustain its essential cooling functions, i.e. preventing degradation of core and spent fuel pool inventories, following a reactor trip in complete autarchy for a nearly indefinite amount of time. RWE Technology is currently investigating a back-fit solution involving “self-propelling” cooling systems that deliver exactly this long term autarchy. The cooling system utilizes the temperature difference between the hotter reactor core or spent fuel pond with the surrounding ultimate heat sink (ambient air) to drive its coolant like a classical heat machine. The cooling loop itself is the heat machine, but its sole purpose is to merely achieve sufficient thermal efficiency to drive itself and to establish convective cooling (∼2% thermal efficiency). This is realized by the use of a Joule/Brayton Cycle employing supercritical CO2. The special properties of supercritical CO2 are essential for this system to be practicable. Above a temperature of 30.97°C and a pressure of 73.7bar CO2 becomes a super dense gas with densities similar to that of a typical liquid (∼400kg/m3), viscosities similar tothat of a gas (∼3×105Pas) and gas like compressibility. This allows for an extremely compact cooling system that can drive itself on very small temperature differences. The presented parametric studies show that a back-fitable system for long-term spent fuel pool cooling is viable to deliver excess electrical power for emergency systems of approximately 100kW. In temperate climates with peak air temperatures of up to 35°C, the system can power itself and its air coolers at spent fuel pool temperatures of 85°C, although with little excess electrical power left. Different back-fit strategies for PWR and BWR reactor core decay heat removal are discussed and the size of piping, heat exchangers and turbo-machinery are briefly evaluated. It was found that depending on the strategy, a cooling system capable of removing all decay heat from a reactor core would employ piping diameters between 100–150mm and the investigated compact and sealed turbine-alternator-compressor unit would be sufficiently small to be integrated into the piping.


Author(s):  
R. W. Card

A hybrid wet-dry cooling system can be designed for a large combined-cycle power plant. A well-designed hybrid cooling system will provide reasonable net generation year-round, while using substantially less water than a conventional wet cooling tower. The optimum design for the hybrid system depends upon climate at the site, the price of power, and the price of water. These factors vary on a seasonal basis. Two hypothetical power plants are modeled, using state-of-the-art steam turbines and hybrid cooling systems. The plants are designed for water-constrained sites incorporating typical weather data, power prices, and water prices. The principles for economic designs of hybrid cooling systems are demonstrated.


Author(s):  
Jaron J. Peck ◽  
Amanda D. Smith

Climate change can have a large effect on thermoelectric power generation. Typical thermoelectric power plants rely on water to cool steam in the condenser in order to produce electricity. Increasing global temperatures can increase average water temperatures as well as decrease the amount of water available for cooling due to evaporation. It is important to know how these parameters can affect power generation and efficiency of power systems, especially when assessing the water needs of a plant for a desired power output and whether a site can fulfill those needs. This paper explains the development of a model that shows how power and efficiency are affected due to changing water temperature and water availability for plants operating on a Rankine cycle. Both a general model of the simple Rankine cycle as well as modifications for regeneration and feedwater heating are presented. Power plants are analyzed for two different types of cooling systems: once-through cooling and closed circuit cooling with a cooling tower. Generally, rising temperatures in cooling water have been found to lower power generation and efficiency. Here, we present a method for quantifying power output and efficiency reductions due to changes in cooling water flow rates or water temperatures. Using specified plant parameters, such as boiler temperature and pressure, power and efficiency are modeled over a 5°C temperature range of inlet cooling water. It was found that over this temperature range, power decrease ranged from 2–3.5% for once through cooling systems, depending on the power system, and 0.7% for plants with closed circuit cooling. This shows that once-through systems are more vulnerable to changing temperatures than cooling tower systems. The model is also applied to Carbon Plant, a coal fired power plant in Utah that withdraws water from the Price River, to show how power and efficiency change as the temperature of the water changes using USGS data obtained for the Price River. The model can be applied to other thermoelectric power stations, whether actual or proposed, to investigate the effects of water conditions on projected power output and plant efficiency.


Author(s):  
Geoffrey Short ◽  
Addison K. Stark ◽  
Daniel Matuszak ◽  
James F. Klausner

Fresh water withdrawal for thermoelectric power generation in the U.S. is approximately 139 billion gallons per day (BGD), or 41% of total fresh water draw, making it the largest single use of fresh water in the U.S. Of the fresh water withdrawn for the power generation sector, 4.3 BGD is dissipated to the atmosphere by cooling towers and spray ponds. Dry-cooled power plants are attractive and sometimes necessary because they avoid significant withdrawal and consumption of freshwater resources that could otherwise be used for other purposes. This could become even more important when considering the potential effects of climate change (1). Additional benefits of dry-cooling include power plant site flexibility, reduced risk of water scarcity, and faster permitting (reducing project development time and cost). However, dry-cooling systems are known to be more costly and larger than their wet-cooling counterparts. Additionally, without the benefit of additional latent heat transfer through evaporation, the Rankine cycle condensing (cold) temperature for dry-cooling is typically higher than that for wet-cooling, affecting the efficiency of power production and the resultant levelized cost of electricity (LCOE). The Advanced Research Projects Agency - Energy (ARPA-E) has developed a technoeconomic analysis (TEA) model for the development of indirect dry-cooling systems employing steam condensation within a natural gas combined cycle power plant. The TEA model has been used to inform the Advanced Research in Dry-Cooling (ARID) Program on the performance metrics needed to achieve an economical dry-cooling technology. In order to assess the relationship between air-cooled heat exchanger (ACHX) performance, including air side heat transfer coefficient and pressure drop, and power plant economics, ARPA-E has employed a modified version of the National Energy Technology Laboratory (NETL) model of a 550 MW natural gas combined cycle (NGCC) plant employing an evaporative cooling system. The evaporative cooling system, including associated balance of system costs, was replaced with a thermodynamic model for an ACHX with the desired improved heat transfer performance and supplemental cooling and storage systems. Monte Carlo simulation determined an optimal ACHX geometry and associated ACHX cost. Allowing for an increase in LCOE of 5%, the maximum allowable additional cost of the supplemental cooling system was determined as a function of the degree of cooling of the working fluid required. This paper describes the methodologies employed in the TEA, details the results, and includes related models as supplemental material, while providing insight on how the open source tool might be used for thermal management innovation.


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