scholarly journals Multidimensional Analysis of Time-Resolved Charged Particle Imaging Experiments

2018 ◽  
Vol 8 (8) ◽  
pp. 1227 ◽  
Author(s):  
Vincent Loriot ◽  
Luis Bañares ◽  
Rebeca de Nalda
Keyword(s):  
Charged Particle ◽  
Center Of Mass ◽  
Relevant Information ◽  
Chem Phys ◽  
Multidimensional Analysis ◽  
Multidimensional Data ◽  
Time Resolved ◽  
Fitting Procedure ◽  
Energy And Angular Distributions ◽  
Particle Imaging

We present a tutorial to realize a multidimensional fitting procedure capable of extracting all the relevant information contained in a sequence of charged particle images acquired as a function of time in femtosecond pump–probe experiments. The images are reproduced using a 3D fitting method, which provides the velocity (or center-of-mass kinetic energy) and angular distributions contained in the images and their time evolution. A detailed example of the method is shown through the analysis of the time-resolved predissociation dynamics of CH3I on the B-band origin (Gitzinger et al., J. Chem. Phys.2010, 133, 234313). We show that the multidimensional approach is essential for the analysis of complex images that contain several overlapping contributions where reduced dimensionality analyses cannot provide a reliable description of the features present in the image sequence. This methodology can be generalized to many types of multidimensional data analysis.

scholarly journals Multidimensional Analysis of Time-Resolved Charged Particle Imaging Experiments

2018 ◽  
Author(s):  
Vincent Loriot ◽  
Luis Bañares ◽  
Rebeca de Nalda
Keyword(s):  
Charged Particle ◽  
Center Of Mass ◽  
Relevant Information ◽  
Chem Phys ◽  
Multidimensional Analysis ◽  
Multidimensional Data ◽  
Time Resolved ◽  
Fitting Procedure ◽  
Energy And Angular Distributions ◽  
Particle Imaging

We present a tutorial to realize a multidimensional fitting procedure capable of extracting all the relevant information contained in a sequence of charged particle images acquired as a function of time in femtosecond pump-probe experiments. The images are reproduced using a 3D fitting method, which provides the velocity (or center-of-mass kinetic energy) and angular distributions contained in the images and their time evolution. A detailed example of the method is shown through the analysis of the time-resolved predissociation dynamics of CH3I on the B-band origin [Gitzinger et al., J. Chem. Phys. 133, 234313 (2010)]. We show that the multidimensional approach is essential for the analysis of complex images that contain several overlapping contributions where reduced dimensionality analyses cannot provide a reliable description of the features present in the image sequence. This methodology can be generalized to many types of multidimensional data analysis.

scholarly journals Ultrafast proton release reaction and primary photochemistry of phycocyanobilin in solution observed with fs-time-resolved mid-IR and UV/Vis spectroscopy

2021 ◽  
Author(s):  
Maximilian Theiß ◽  
Merten Grupe ◽  
Tilman Lamparter ◽  
Maria Andrea Mroginski ◽  
Rolf Diller
Keyword(s):  
Density Functional ◽  
Transient Absorption ◽  
Vibrational Analysis ◽  
Density Functional Theory Calculations ◽  
Chem Phys ◽  
Molecular Structures ◽  
Ir Absorption ◽  
Time Resolved ◽  
Time Constants ◽  
Vis Spectroscopy

AbstractDeactivation processes of photoexcited (λex = 580 nm) phycocyanobilin (PCB) in methanol were investigated by means of UV/Vis and mid-IR femtosecond (fs) transient absorption (TA) as well as static fluorescence spectroscopy, supported by density-functional-theory calculations of three relevant ground state conformers, PCBA, PCBB and PCBC, their relative electronic state energies and normal mode vibrational analysis. UV/Vis fs-TA reveals time constants of 2.0, 18 and 67 ps, describing decay of PCBB*, of PCBA* and thermal re-equilibration of PCBA, PCBB and PCBC, respectively, in line with the model by Dietzek et al. (Chem Phys Lett 515:163, 2011) and predecessors. Significant substantiation and extension of this model is achieved first via mid-IR fs-TA, i.e. identification of molecular structures and their dynamics, with time constants of 2.6, 21 and 40 ps, respectively. Second, transient IR continuum absorption (CA) is observed in the region above 1755 cm−1 (CA1) and between 1550 and 1450 cm−1 (CA2), indicative for the IR absorption of highly polarizable protons in hydrogen bonding networks (X–H…Y). This allows to characterize chromophore protonation/deprotonation processes, associated with the electronic and structural dynamics, on a molecular level. The PCB photocycle is suggested to be closed via a long living (> 1 ns), PCBC-like (i.e. deprotonated), fluorescent species.

scholarly journals Time-Resolved Quadrupole Mass Spectrometric Studies on Pulsed Laser Ablation of TiO2

1999 ◽  
Vol 18 (3) ◽  
pp. 99-109 ◽  
Author(s):  
Yongxin Tang ◽  
Zhenhui Han ◽  
Qizong Qin
Keyword(s):  
Laser Ablation ◽  
Continuous Wave ◽  
Center Of Mass ◽  
Pulsed Laser ◽  
Pulsed Laser Ablation ◽  
Ionic Species ◽  
Mass Spectrometric ◽  
Quadrupole Mass ◽  
Time Resolved ◽  
Ambient Oxygen

Pulsed laser ablation of TiO2 at 355 nm and 532 nm has been investigated using an angleand time-resolved quadrupole mass spectrometric technique. The major ablated species include O (m/e = 16), O2 (m/e = 32), Ti (m/e = 48), TiO (m/e = 64) and TiO2 (m/e = 80). The time-of-flight (TOF) spectra of ablated species are measured for the ionic and neutral ablated species, and they can be fitted by a Maxwell – Boltzmann (M – B) distribution with a center-of-mass velocity. The measured angular distributions of the ionic species (O+ and Ti+) and the neutral species (O and Ti) can be fitted with cos⁡nθ and a cos⁡θ + (1−a)cos⁡nθ, respectively. In addition, a continuous wave oxygen molecular beam is introduced into the ablated plume, and the enhancement of the signal intensities of TiO is observed. It implies that the ablated Ti atoms/ions species can react with ambient oxygen molecules in the gas phase. In the meanwhile, the physicochemical mechanism of pulsed laser ablation of TiO2 is discussed.

scholarly journals Study of charged-particle multiplicity fluctuations in pp collisions with Monte Carlo event generators at the LHC

2020 ◽  
Vol 29 (09) ◽  
pp. 2050074
Author(s):  
E. Shokr ◽  
A. H. El-Farrash ◽  
A. De Roeck ◽  
M. A. Mahmoud
Keyword(s):  
Charged Particle ◽  
Particle Production ◽  
Local Density ◽  
Particle Density ◽  
Hadron Collider ◽  
Center Of Mass ◽  
Monte Carlo Event ◽  
Particle Multiplicity ◽  
Charged Particle Multiplicity ◽  
Proton Proton

Proton–Proton ([Formula: see text]) collisions at the Large Hadron Collider (LHC) are simulated in order to study events with a high local density of charged particles produced in narrow pseudorapidty windows of [Formula: see text] = 0.1, 0.2, and 0.5. The [Formula: see text] collisions are generated at center of mass energies of [Formula: see text], [Formula: see text], [Formula: see text], and [Formula: see text] TeV, i.e., the energies at which the LHC has operated so far, using PYTHIA and HERWIG event generators. We have also studied the average of the maximum charged-particle density versus the event multiplicity for all events, using the different pseudorapidity windows. This study prepares for the multi-particle production background expected in a future search for anomalous high-density multiplicity fluctuations using the LHC data.

Nonlinear fitting procedure for accurate time-resolved measurements in diffusive media

2009 ◽  
Author(s):  
Lorenzo Spinelli ◽  
Fabrizio Martelli ◽  
Alessandro Torricelli ◽  
Antonio Pifferi ◽  
Giovanni Zaccanti
Keyword(s):  
Time Resolved ◽  
Nonlinear Fitting ◽  
Fitting Procedure ◽  
Time Resolved Measurements

scholarly journals Motor cost affects the decision of when to shift gaze for guiding movement

2019 ◽  
Vol 122 (1) ◽  
pp. 378-388 ◽  
Author(s):  
F. Javier Domínguez-Zamora ◽  
Daniel S. Marigold
Keyword(s):  
Center Of Mass ◽  
Relevant Information ◽  
Lateral Direction ◽  
Foot Placement ◽  
Factors Affecting ◽  
Direct Gaze ◽  
Trial Basis ◽  
Motor Actions ◽  
The Cost ◽  
The Brain

Frequent gait modifications are often required to navigate our world. These can involve long or wide steps or changes in direction. People generally prefer to minimize the motor cost (or effort) of a movement, although with changes in gait this is not always possible. The decision of when and where to shift gaze is critical for controlling motor actions, since vision informs the brain about the available choices for movement—in this case, where to step. Here we asked how motor cost influences the allocation of gaze. To address this, we had participants walk and step to the center of sequential targets on the ground. We manipulated the motor cost associated with controlling foot placement by varying the location of one target in the lateral direction on a trial-to-trial basis within environments with different numbers of targets. Costlier steps caused a switch from a gaze strategy of planning future steps to one favoring visual feedback of the current foot placement when participants had to negotiate another target immediately after. Specifically, costlier steps delayed gaze shifts away from the manipulated target. We show that this relates to the cost of moving the leg and redirecting the body’s center of mass from target to target. Overall, our results suggest that temporal gaze decisions are affected by motor costs associated with step-to-step demands of the environment. Moreover, they provide insight into what affects the coordination between the eyes and feet for the control of stable and accurate foot placement while walking. NEW & NOTEWORTHY Changes in gait allow us to navigate our world. For instance, one may step long or wide to avoid a spilled drink. The brain can direct gaze to gather relevant information for making these types of motor decisions; however, the factors affecting gaze allocation in natural behaviors are poorly understood. We show how the motor cost associated with a step influences the decision of when to redirect gaze to ensure accurate foot placement while walking.

scholarly journals Charged-Particle Multiplicity Moments as Described by Shifted Gompertz Distribution in e+e−, pp¯, and pp Collisions at High Energies

2020 ◽  
Vol 2020 ◽  
pp. 1-24
Author(s):  
Aayushi Singla ◽  
M. Kaur
Keyword(s):  
Charged Particle ◽  
Phase Space ◽  
Center Of Mass ◽  
Particle Multiplicity ◽  
Charged Particle Multiplicity ◽  
Distribution Analysis ◽  
Factorial Moments ◽  
Hadronic Interactions ◽  
Gompertz Distribution ◽  
Full Phase Space

In continuation of our earlier work, in which we analysed the charged particle multiplicities in leptonic and hadronic interactions at different center-of-mass energies in full phase space as well as in restricted phase space using the shifted Gompertz distribution, a detailed analysis of the normalized moments and normalized factorial moments is reported here. A two-component model in which a probability distribution function is obtained from the superposition of two shifted Gompertz distributions, as introduced in our earlier work, has also been used for the analysis. This is the first analysis of the moments with the shifted Gompertz distribution. Analysis has also been performed to predict the moments of multiplicity distribution for the e+e− collisions at s=500 GeV at a future collider.

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