scholarly journals Effective Design of Cr-Co-Ni-Ta Eutectic Medium Entropy Alloys with High Compressive Properties Using Combined CALPHAD and Experimental Approaches

2021 ◽  
Vol 11 (13) ◽  
pp. 6102
Author(s):  
Taiwen Huang ◽  
Jiachen Zhang ◽  
Jun Zhang ◽  
Lin Liu
Keyword(s):  
Solid Solution ◽  
Plastic Strain ◽  
Compression Strength ◽  
Volume Fraction ◽  
Laves Phase ◽  
Valence Electron Concentration ◽  
Solid Solution Strengthening ◽  
Binary Diagram ◽  
High Plastic Strain ◽  
The Stability

Alloy design of Cr-Co-Ni-Ta eutectic medium entropy alloys (EMEAs) was performed through a CALPHAD method coupled with experimental study, with the aim to attain high phase stability as well as excellent mechanical properties. Based on calculated pseudo-binary diagram, CrCoNiTax (x = 0.1, 0.3, 0.4, 0.5, 0.7) medium entropy alloys were investigated. Two phases, FCC solid solution and Laves phase, were identified in the alloys. With increasing Ta content, the volume fraction of hard and brittle Laves phase increased, microstructure changed from hypoeutectic (Ta0.1, Ta0.3) to eutectic (Ta0.4) and then to hypereutectic (Ta0.5, Ta0.7). The stability of phases was assessed by considering the thermodynamic parameter Ω and valence electron concentration (VEC). The eutectic phases become stable when 1.42 < Ω < 0.74 and 7.5 < VEC < 8.25. In addition, based on nanoindentation, the results indicated that solid solution strengthening in γ phase was significantly enhanced, eutectic phase in CrCoNiTa0.4 EMEA was found to process the highest microhardness and elastic modulus. Finally, the hardness of alloys was positively correlated with the content of Ta and the plastic strain of alloys obviously decreased, while the compression strength firstly increased and then decreased. CrCoNiTa0.4 was the most promising alloy with the highest compression strength (2502 MPa) and high plastic strain (20.6%).

Decomposition of solid solution in an alloy under high plastic strain

2001 ◽  
Vol 46 (5) ◽  
pp. 569-572 ◽  
Author(s):  
N. M. Vlasov ◽  
A. S. Gontar’ ◽  
V. A. Zaznoba
Keyword(s):  
Solid Solution ◽  
Plastic Strain ◽  
Decomposition Of Solid Solution ◽  
High Plastic Strain ◽  
High Plastic

scholarly journals On the Microstructure and Isothermal Oxidation at 800 and 1200 °C of the Nb-24Ti-18Si-5Al-5Cr-5Ge-5Sn (at.%) Silicide-Based Alloy

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 722 ◽  
Author(s):  
Ofelia Hernández-Negrete ◽  
Panos Tsakiropoulos
Keyword(s):  
Solid Solution ◽  
Oxidation Resistance ◽  
Volume Fraction ◽  
Coefficient Of Thermal Expansion ◽  
Cast Alloy ◽  
Isothermal Oxidation ◽  
Valence Electron Concentration ◽  
Scale Spallation ◽  
Substrate Interface ◽  
Oxidation In Air

The research presented in this paper aspired to understand how the simultaneous addition of Ge and Sn in an Hf-free Nb-silicide-based alloy affected its oxidation resistance. Results are presented for the Nb-24Ti-18Si-5Al-5Cr-5Ge-5Sn alloy (at.%) which was studied in the as-cast and heat-treated (1400 °C/100 h) conditions and after isothermal oxidation in air at 800 and 1200 °C. There was macrosegregation in the cast alloy, in which the Nbss formed at a low volume fraction and was not stable after heat treatment at 1400 °C. The βNb5Si3, A15-Nb3Sn, and C14-NbCr2 were stable phases. The alloy did not undergo pest oxidation at 800 °C, and there was no spallation of its scale at 1200 °C. There was enrichment in Ge and Sn in the substrate below the scale/substrate interface, where the compounds Nb3Sn, Nb5Sn2Si, (Ti,Nb)6Sn5, and Nb5Ge3 were formed. After the oxidation at 1200 °C, the solid solution in the bulk of the alloy was very Ti-rich (Ti,Nb)ss. Improvement of oxidation resistance at both temperatures was accompanied by a decrease and increase, respectively, of the alloy parameters VEC (valence electron concentration) and δ, in agreement with the alloy design methodology NICE (Niobium Intermetallic Composite Elaboration). The elimination of scale spallation at 1200 °C was attributed (a) to the formation of Ti-rich (Ti,Nb)ss solid solution and (Ti,Nb)6Sn5, respectively, in the bulk and below the scale, (b) to the low concentration of Cr in the scale, (c) to the absence of GeO2 in the scale, (d) to the formation of αAl2O3 in the scale, and (e) to the presence (i) of Nb5Ge3 below the scale/substrate interface and (ii) of oxides in the scale, namely, SiO2, Al2O3, TiO2, and SnO2, and Ti2Nb10O29,TiNb2O7, and AlNbO4, respectively, with a range of intrinsic thermal shock resistances and coefficient of thermal expansion (CTE) values that reduced stresses in the scale and the substrate below it.

Physical and Mechanical Properties of Two-Phase Zr-Cr-Mn Alloys

1998 ◽  
Vol 552 ◽  
Author(s):  
A. Goldberg ◽  
D. E. Luzzi
Keyword(s):  
Mechanical Properties ◽  
Volume Fraction ◽  
Physical And Mechanical Properties ◽  
Laves Phase ◽  
Two Phase ◽  
Tem Analysis ◽  
Atomic Size ◽  
Solid Solution Strengthening ◽  
Solution Strengthening ◽  
Mn Content

ABSTRACTThe Zr-Cr-Mn system is used to explore the effect of a lowered SFE on the room temperature mechanical properties of a Laves phase using elements of similar atomic size. The ternary Zr-Cr-Mn diagram in the region from 0 to 12 at. % Mn is first determined and it is shown that Mn substitutes only for Cr in the Laves phase. TEM analysis of the density of stacking fault energy related defects such as annealing twins indicates that Mn substitution for Cr in ZrCr2 lowers the SFE of the cubic Laves phase. Mechanical testing of the two phase alloys is used to explore the effects of Mn content and the volume fraction of each phase on the ductility and fracture behavior in compression. It is found that the mechanical properties are well-described by a model incorporating solid solution strengthening in a ductile-brittle two phase alloy.

Modelling of the Influence of Laves Phase on the Creep Properties in 9% Cr Steels

2007 ◽  
Author(s):  
Hans Magnusson ◽  
Rolf Sandstro¨m
Keyword(s):  
Solid Solution ◽  
Creep Strength ◽  
Solute Drag ◽  
Laves Phase ◽  
Solid Solution Hardening ◽  
Moving Frame ◽  
Creep Properties ◽  
Solid Solution Strengthening ◽  
Solution Strengthening ◽  
Multi Component System

Nucleation and growth of Laves phase are calculated for a multi-component system. Coarsening of MX, M23C6 and Laves are also determined. The influence on creep strength is discussed by analysing particle hardening and solid solution strengthening. A model for particle size distribution is presented in order to determine the amount of dislocations that can climb across particles or generate Orowan loops. The model for solid solution hardening is based on a solution of Fick’s second law with a moving frame of reference for the concentration profiles around a climbing dislocation. This is done in order to determine the slowdown in dislocations velocity due to solute drag. The results show a loss in creep strength as the Laves phase grows.

scholarly journals A Study of the Effect of 5 at.% Sn on the Micro-Structure and Isothermal Oxidation at 800 and 1200 °C of Nb-24Ti-18Si Based Alloys with Al and/or Cr Additions

Materials ◽  
2020 ◽  
Vol 13 (1) ◽  
pp. 245 ◽  
Author(s):  
Zhen Xu ◽  
Claire Utton ◽  
Panos Tsakiropoulos
Keyword(s):  
Design Methodology ◽  
Isothermal Oxidation ◽  
Oxidation Behaviour ◽  
Laves Phase ◽  
Valence Electron Concentration ◽  
Micro Structure ◽  
Scale Spallation ◽  
Intermetallic Composite ◽  
The Stability ◽  
Al Additions

This paper presents the results of a systematic study of Nb-24Ti-18Si based alloys with 5 at.% Sn addition. Three alloys of nominal compositions (at.%), namely Nb-24Ti-18Si-5Cr-5Sn (ZX4), Nb-24Ti-18Si-5Al-5Sn (ZX6), and Nb-24Ti-18Si-5Al-5Cr-5Sn (ZX8), were studied to understand how the increased Sn concentration improved oxidation resistance. In all three alloys there was macrosegregation, which was most severe in ZX8 and the primary βNb5Si3 transformed completely to αNb5Si3 after heat treatment. The Nbss was not stable in ZX6, the Nb3Sn was stable in all three alloys, and the Nbss and C14-NbCr2 Laves phase were stable in ZX4 and ZX8. The 5 at.% Sn addition suppressed pest oxidation at 800 °C but not scale spallation at 1200 °C. At both temperatures, a Sn-rich area with Nb3Sn, Nb5Sn2Si, and NbSn2 compounds developed below the scale. This area was thicker and continuous after oxidation at 1200 °C and was contaminated by oxygen at both temperatures. The contamination of the Nbss by oxygen was most severe in the bulk of all three alloys. Nb-rich, Ti-rich and Nb and Si-rich oxides formed in the scales. The adhesion of the latter on ZX6 at 1200 °C was better, compared with the alloys ZX4 and ZX8. At both temperatures, the improved oxidation was accompanied by a decrease and increase respectively of the alloy parameters VEC (Valence Electron Concentration) and δ, in agreement with the alloy design methodology NICE (Niobium Intermetallic Composite Elaboration). Comparison with similar alloys with 2 at.% Sn addition showed (a) that a higher Sn concentration is essential for the suppression of pest oxidation of Nb-24Ti-18Si based alloys with Cr and no Al additions, but not for alloys where Al and Cr are in synergy with Sn, (b) that the stability of Nb3Sn in the alloy is “assured” with 5 at.% Sn addition, which improves oxidation with/out the presence of the Laves phase and (c) that the synergy of Sn with Al presents the “best” oxidation behaviour with improved scale adhesion at high temperature.

Solid Solution Strengthening Behavior of 25Cr-20Ni Austenite Stainless Steel

2004 ◽  
Vol 261-263 ◽  
pp. 1209-1214
Author(s):  
I.D. Park ◽  
Seok Hwan Ahn ◽  
Ki Woo Nam
Keyword(s):  
Solid Solution ◽  
Stress Relaxation ◽  
Plastic Strain ◽  
Applied Stress ◽  
Abrupt Change ◽  
Relaxation Curve ◽  
Stress Relaxation Test ◽  
Free Flight ◽  
Solid Solution Strengthening ◽  
Solution Strengthening

The purpose of this paper is to investigate the effect of solid solution strengthening on the high temperature creep strength of STS310J1TB. To make clear the effect of solid solution strengthening, the stress abrupt change test was carried out to observe the instantaneous plastic strain and the stress relaxation test was carried out to investigate the ratio of solid solution strengthening to applied stress. The instantaneous plastic strain was observed in the stress abrupt change test of STS310S, while it was absent in STS310J1TB. This clearly indicates that the dislocations glide viscously in STS310J1TB, while they move in a free flight manner in STS310S. As a result of TEM observation, the dislocation structure of STS310J1TB is more uniform than that of STS310S. From the analysis of the stress relaxation curve, the effective stress to total applied stress was found to be about 16 %.

Fine Microstructure of a Mechanically Alloyed Oxide Dispersion Strengthened Nickel-Base Superalloy

1977 ◽  
Vol 35 ◽  
pp. 298-299
Author(s):  
Jordi Marti ◽  
Timothy E. Howson ◽  
David Kratz ◽  
John K. Tien
Keyword(s):  
Solid Solution ◽  
Volume Fraction ◽  
Stress Rupture ◽  
Oxide Dispersion Strengthened ◽  
Solid Solution Alloy ◽  
Oxide Dispersion ◽  
Creep And Stress Rupture ◽  
Mechanically Alloyed ◽  
Fine Microstructure ◽  
Nickel Base

The previous paper briefly described the fine microstructure of a mechanically alloyed oxide dispersion strengthened nickel-base solid solution. This note examines the fine microstructure of another mechanically alloyed system. This alloy differs from the one described previously in that it is more generously endowed with coherent precipitate γ forming elements A1 and Ti and it contains a higher volume fraction of the finely dispersed Y2O3 oxide. An interesting question to answer in the comparative study of the creep and stress rupture of these two ODS systems is the role of the precipitate γ' in the mechanisms of creep and stress rupture in alloys already containing oxide dispersoids.The nominal chemical composition of this alloy is Ni - 20%Cr - 2.5%Ti - 1.5% A1 - 1.3%Y203 by weight. The system receives a three stage heat treatment-- the first designed to produce a coarse grain structure similar to the solid solution alloy but with a smaller grain aspect ratio of about ten.

Effect of Titanium Carbide Particles on Mechanical Properties of Aluminum Matrix Composites

2017 ◽  
Vol 5 (2) ◽  
pp. 20-30
Author(s):  
Zaman Khalil Ibrahim
Keyword(s):  
Mechanical Properties ◽  
Titanium Carbide ◽  
Compression Strength ◽  
Volume Fraction ◽  
Aluminum Matrix ◽  
Aluminum Matrix Composites ◽  
Matrix Composites ◽  
Powder Metallurgy Technique ◽  
Carbide Particles ◽  
Properties Of Composites

In this research aluminum matrix composites (AMCs) was reinforced by titanium carbide (TiC) particles and was produced. Powder metallurgy technique (PM) has been used to fabricate AMCs reinforced with various amounts (0%, 4%, 8%, 12%, 16% and 20% volume fraction) of TiC particles to study the effect of different volume fractions on mechanical properties of the Al-TiC composites. Measurements of compression strength and hardness showed that mechanical properties of composites increased with an increase in volume fraction of TiC Particles. Al-20 % vol. TiC composites exhibited the best properties with hardness value (97HRB) and compression strength value (275Mpa).

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