scholarly journals Synthesis and Characterization of Maleinized Rice Bran Oil Fatty Acids

2019 ◽  
pp. 49-56
Author(s):  
Deepti Shikha
Keyword(s):  
Fatty Acids ◽  
Rice Bran ◽  
Free Acid ◽  
Rice Bran Oil ◽  
Value Added ◽  
Acid Number ◽  
Dark Colour ◽  
Free Acid Content ◽  
Product Viscosity

Ricebran oil has higher percentage of free fatty acids which accounts for its use in various industries. In the present work rice bran fatty acids have been used for maleinization. In rice bran fatty acids maleic anhydride reacts with oleic acid without loss of unsaturation in the acid and formed succinic anhydride type adduct. Hydration of the maleinized product is performed to overcome from a number of technological difficulties such as increase in the product viscosity, abrupt and uncontrollable drop of the acid number and also gelation. Inspite of its high free acid content and dark colour, rice bran oil can be conveniently used in laundry soaps directly, but conversion of oil into distilled fatty acids provides various avenues for value added products. The absence of linolenic acid in rice bran fatty acids has an excellent advantage in providing non-yellowing characteristics. This property of rice bran fatty acids opens avnues for coating industries.

Synthesis of Methyl Ester from Rice Bran Oil through the Esterification Reaction

2020 ◽  
Vol 851 ◽  
pp. 164-171 ◽  
Author(s):  
Aman Santoso ◽  
Abdurrohman ◽  
Anugrah Ricky Wijaya ◽  
Dedek Sukarianingsih ◽  
Sumari ◽  
...  
Keyword(s):  
Refractive Index ◽  
Methyl Ester ◽  
Vegetable Oil ◽  
Rice Bran ◽  
Rice Bran Oil ◽  
Methyl Esters ◽  
Acid Number ◽  
Esterification Reaction

Vegetable oil is one of rice bran components. As triglycerides, vegetable oil can be converted to fatty acid and alkyl esters for further treatments. Synthesis of alkyl ester oil can be carried out by esterification or transesterification reaction, depending on the quality of the oil and the catalyst. The purposes of this study are 1) Rice bran oil isolation, 2) Oil esterification 3) Characterization and identification of the methyl ester that compose rice bran oil. The stages in this research are 1) Extraction of rice bran oil, 2) Synthesis of methyl ester from rice bran through esterification reaction, 3) Methyl ester characterization of rice bran oil and its potential test as biodiesel included determination of density, viscosity, refractive index, and acid number test, 4) The identification of synthesized methyl esters composition using GC-MS. The results showed that rice bran oil has a yield of 18.09%. Synthesis of methyl esters from rice bran oil through the esterification reaction with a catalyst acid yields 72.37%. The characters of the synthesized methyl ester are on the range of biodiesel quality standards, namely, the density is 0.850 g/mL, viscosity is 4.73 cSt, a refractive index is 1.45871, and an acid number is 0.76 g KOH/g methyl ester, therefore it is claimed that the synthesized methyl esters have the potential as biodiesel. The GC-MS result showed the presence of compounds methyl tetradecanoate (0.38%), methyl hexadecanoate (40.67%), methyl 9-octadecenoate (53.68%), methyl octadecanoate (5.02%), and methyl eicosanoate (0.14%).

scholarly journals Changes in Phenolics and Fatty Acids Composition and Related Gene Expression during the Development from Seed to Leaves of Three Cultivated Cardoon Genotypes

Antioxidants ◽  
2020 ◽  
Vol 9 (11) ◽  
pp. 1096
Author(s):  
Giulia Graziani ◽  
Teresa Docimo ◽  
Monica De Palma ◽  
Francesca Sparvoli ◽  
Luana Izzo ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Wide Spectrum ◽  
Sustainable Use ◽  
Fatty Acid Desaturase ◽  
Value Added ◽  
Industrial Applications ◽  
Transcriptional Analysis ◽  
Total Phenols ◽  
Superior Genotypes

Cultivated cardoon (Cynara cardunculus var. altilis) has long been used as a food and medicine remedy and nowadays is considered a functional food. Its leaf bioactive compounds are mostly represented by chlorogenic acids and coumaroyl derivatives, known for their nutritional value and bioactivity. Having antioxidant and hepatoprotective properties, these molecules are used for medicinal purposes. Apart from the phenolic compounds in green tissues, cultivated cardoon is also used for the seed oil, having a composition suitable for the human diet, but also valuable as feedstock for the production of biofuel and biodegradable bioplastics. Given the wide spectrum of valuable cardoon molecules and their numerous industrial applications, a detailed characterization of different organs and tissues for their metabolic profiles as well as an extensive transcriptional analysis of associated key biosynthetic genes were performed to provide a deeper insight into metabolites biosynthesis and accumulation sites. This study aimed to provide a comprehensive analysis of the phenylpropanoids profile through UHPLC-Q-Orbitrap HRMS analysis, of fatty acids content through GC-MS analysis, along with quantitative transcriptional analyses by qRT-PCR of hydroxycinnamoyl-quinate transferase (HQT), stearic acid desaturase (SAD), and fatty acid desaturase (FAD) genes in seeds, hypocotyls, cotyledons and leaves of the cardoon genotypes “Spagnolo”, “Bianco Avorio”, and “Gigante”. Both oil yield and total phenols accumulation in all the tissues and organs indicated higher production in “Bianco Avorio” and “Spagnolo” than in “Gigante”. Antioxidant activity evaluation by DPPH, ABTS, and FRAP assays mirrored total phenols content. Overall, this study provides a detailed analysis of tissue composition of cardoon, enabling to elucidate value-added product accumulation and distribution during plant development and hence contributing to better address and optimize the sustainable use of this natural resource. Besides, our metabolic and transcriptional screening could be useful to guide the selection of superior genotypes.

Effect of calcium salt of fatty acids supplementation on performance of Malpura lambs

2015 ◽  
Vol 55 (9) ◽  
pp. 1123 ◽  
Author(s):  
R. S. Bhatt ◽  
A. Sahoo ◽  
A. K. Shinde ◽  
S. A. Karim
Keyword(s):  
Fatty Acids ◽  
Organic Matter ◽  
Rice Bran ◽  
Calcium Salt ◽  
Rice Bran Oil ◽  
Cholesterol Concentration ◽  
Blood Biochemical ◽  
Industrial Grade ◽  
Effect Of Treatment ◽  
Metabolisable Energy

Twenty-four Malpura lambs (28 days old) were distributed into three equal groups (four each from either sexes). They were fed ad libitum on three experimental diets containing graded levels of calcium salt of fatty acids (source: rice bran oil; Ca-FA) at 0 (T1), 20 (T2) and 40 (T3) g per kg of concentrate and dry roughage (Prosopis cineraria leaves) up to 6 months of age along with suckling of mother till weaning (3 months). Effect of Ca-FA supplementation on liveweight gain, feed and nutrient intake was not observed during pre-weaning (28–90 days), which however increased (P < 0.05) in T3 during post-weaning (90–180 days). There was an increase in organic matter intake and digestibility as well as metabolisable energy intake in Ca-FA-supplemented groups. Rumen ammonia-N and ciliate protozoa population was increased (P < 0.05) in T2 and T3 with a positive shift in rumen fermentation (increased propionate and decreased acetate). Blood biochemical analysis revealed effect of treatment and age (P < 0.05) for free fatty acids and cholesterol concentration. Ca-FA supplementation improved (P < 0.05) dressing percentage both at 2% and 4% CA-FA inclusions levels with no change in fat yield and composition. It is concluded that supplementation of Ca-FA prepared from industrial-grade rice bran oil in growing lamb rations improved gain, organic matter intake and digestibility during the post-weaning period and a linear response to the level of supplementation recommends Ca-FA at 40 g/kg for improved lamb performance.

Sesame Oil and Rice Bran Oil Ameliorates Adjuvant-Induced Arthritis in Rats: Distinguishing the Role of Minor Components and Fatty Acids

Lipids ◽  
2016 ◽  
Vol 51 (12) ◽  
pp. 1385-1395 ◽  
Author(s):  
Nayana Venugopal Yadav ◽  
Sadashivaiah ◽  
Breetha Ramaiyan ◽  
Pooja Acharya ◽  
Lokesh Belur ◽  
...  
Keyword(s):  
Fatty Acids ◽  
Rice Bran ◽  
Rice Bran Oil ◽  
Sesame Oil ◽  
Minor Components ◽  
Adjuvant Induced Arthritis

Characterization of extraction and separation of rice bran oil rich in EFA using SFE process

1999 ◽  
Vol 15 (1) ◽  
pp. 1-8 ◽  
Author(s):  
Hyung-Jin Kim ◽  
Seung-Bum Lee ◽  
Kyung-Ai Park ◽  
In-Kwon Hong
Keyword(s):  
Rice Bran ◽  
Rice Bran Oil ◽  
Extraction And Separation
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