scholarly journals The synthesis and application of 3-arylazo-4-phenylthieno[2, 3-c]isothiazole and ethyl 3-arylazo-4-phenylthieno[2, 3-c]isothiazole- 5-carboxylate

2005 ◽  
Vol 70 (6) ◽  
pp. 799-805 ◽  
Author(s):  
G.G. Pawar ◽  
P. Bineesh ◽  
P.S.R. Kumar ◽  
D.W. Rangnekar ◽  
V.R. Kanetkar

The paper describes the synthesis of 3-amino-4-phenylthieno_2,3-c_isothiazole and ethyl 3-amino-4-phenylthieno_2,3-c_isothiazole-5-carboxylate and their utilization to prepare a range of azo disperse dyes. These novel aryl azo dyes were studied with respect to their color and constitution relationship. The application of these dyes on a polyester fabric and their fastness properties were evaluated. These dyes were characterized by NMR, IR and visible absorption spectroscopy.

2005 ◽  
Vol 70 (11) ◽  
pp. 1249-1253 ◽  
Author(s):  
V.R. Kanetkar ◽  
R.R. Walavalkar

This paper describes the synthesis of 5-amino-6-cyano-2-phenylthieno[ 2,3-d]oxazole and its utilization for the preparation of a range of azo disperse dyes. These aryl azo disperse dyes were applied on polyester fabric and their fastness properties were evaluated. The dyes were characterized by NMR and IR spectroscopy. The visible absorption spectra of these dyes were Recorded.


2001 ◽  
Vol 66 (6) ◽  
pp. 367-376 ◽  
Author(s):  
Hari Maradiya ◽  
Vithal Patel

A series of disperse dyes has been synthesized by diazotisation of 2,6-dibromo-4-nitroaniline and coupled with various N-arylmaleimides. The dyes were characterized by IR spectral studies, visible absorption spectroscopy and elemental analysis. All the dyes were applied as disperse dyes on nylon, cellulose triacetate and polyester fabrics. These dyeswere found to give yellowish orange to deep brown shades with very good depth, levelness and brightness on different fabrics. The percentage dye bath exhaustion and fixation on fabrics were found to be very good. The light, washing, rubbing, perspiration and sublimation fastness properties of the dyed fabrics were found to be good to excellent.


2014 ◽  
Vol 2014 ◽  
pp. 1-7 ◽  
Author(s):  
Yusuf Y. Lams ◽  
P. O. Nkeonye ◽  
K. A. Bello ◽  
M. K. Yakubu ◽  
A. O. Lawal

The aim of this study was to synthesize disperse dyes in the derivative of 2-amino-4-chloro-5-formylthiazole by conventional diazotization and couplings with pyridone and resorcinol. The dyes were characterized by visible absorption spectroscopy, IR spectral studies, and 1H and 13C NMR. The pyridone and resorcinol substituted dyes exhausted well with good depth on 100% polyester fabrics with a shade of brown and purple colours, respectively. The heteroatom and the intrinsic conjugation in the thiazole structure results in high bathochromic shifts and lead to brightness of shades. The dyed fabrics showed very good to excellent wash fastness and moderate to good light and perspiration fastness properties.


2013 ◽  
Vol 2013 ◽  
pp. 1-5
Author(s):  
Mohamed F. Abdel-Megeed ◽  
Mohamed M. Azaam ◽  
Gamal A. El-Hiti

Diphenyl (4′-aminobiphenyl-4-ylamino)(pyridin-3-yl)methylphosphonate(1)was synthesized in 88% yield from reaction of pyridine-3-carboxaldehyde with benzidine and triphenylphosphite in the presence of titanium tetrachloride as a catalyst. Diazotization of1gave the corresponding diazonium salt2which was coupled with several hydroxyl or amino compounds to give the corresponding azo dyes3–8in 82–88% yields after crystallization. The dyes produced were applied to polyesters as disperse dyes and their fastness properties were elevated.


2021 ◽  
pp. 54-57
Author(s):  
Navinkumar A. Kucha ◽  
Manishkumar J. Tank ◽  
G. M. Malik

In this paper synthesis of some new mono azo disperse dyes based on 2-amino 5-(4'-nitro phenyl) 1,3,4-thiadiazole moiety has been reported. Preparation of mono azo disperse dyes via condensation and nally diazotization of substituted primary amine and condensed with N-(4-(4'-chlorophenyl)thiazol-2-yl)-2-((5-(4'-nitrophenyl)-1,3,4-thiadiazol-2-yl)amino)acetamide (RR) to 1 give a series of mono azo dyes (RR -RR ). All the dyes were characterized by IR, H NMR, UV-Visible and elemental analysis and their dyeing 1 15 performance evaluated using High Temperature High Pressure method (HTHP) at 130°C on polyester fabric. All dyes gave good to excellent fastness properties.


2011 ◽  
Vol 8 (3) ◽  
pp. 1218-1225 ◽  
Author(s):  
B. C. Dixit ◽  
D. M. Patel

Novel bisazo-bisazomethine disperse dyes were prepared by the coupling of diazotized solutions of various aromatic amines with 2,2'-{sulfonylbis [4,1-phenylene nitrilomethylylidene]} diphenol (SB). Above Schiff base was prepared by the condensation of 2-hydroxybenzaldehyde with 4,4’-sulphonyl- dianiline (Dapson). The resultant dyes were characterized by elemental analysis, IR and1H NMR spectral studies. The UV Visible absorption spectral data were investigated in dimethylformamide (DMF) and are discussed in terms of structural property relationship. Their dyeing performance as disperse dyes has been assessed on polyester fabrics. The results show that a better hue was obtained on polyester fabrics and have mild to moderate fastness properties.


2020 ◽  
Vol 85 (10) ◽  
pp. 1253-1264
Author(s):  
Umar Ameuru ◽  
Mohammed Yakubu ◽  
Kasali Bello ◽  
Peter Nkeonye ◽  
Azim Halimehjani

A series of monoazo disperse dyes were synthesized by coupling diazotized 4-amino-N-dodecyl-1,8-naphthalimide with N,N-dialkyl anilines and naphthol derivatives. The synthesized intermediates and the dyes were characterized using FTIR, 1H-NMR, 13C-NMR, mass spectroscopy and elemental analysis (CHN). Visible absorption spectra of the dyes were examined in solvents of different polarities. The electronic absorption spectra cover a wavelength (?max) range of 515-535 nm in DMF at uniformly absorption intensity between 1.59-3.00?104 L mol-1 cm-1. The dyes gave deep and bright intense hues of light violet, maroon, pink and neon red on polyester fabrics. The dyes generally showed good washing and perspiration rating but poor to moderate light fastness properties on woven polyester fabric and could be recommended for commercial outlets.


2014 ◽  
Vol 51 (4) ◽  
pp. 043002 ◽  
Author(s):  
汤斌 Tang Bin ◽  
魏彪 Wei Biao ◽  
毛本将 Mao Benjiang ◽  
赵敬晓 Zhao Jingxiao ◽  
冯鹏 Feng Peng

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