scholarly journals Analytical Approach of Laser-Induced Breakdown Spectroscopy to Detect Elemental Profile of Medicinal Plants Leaves

2019 ◽  
Vol 19 (2) ◽  
pp. 430
Author(s):  
Abdul Jabbar ◽  
Mahmood Akhtar ◽  
Shaukat Mehmood ◽  
Koo Hendrick Kurniawan ◽  
Rinda Hedwig ◽  
...  

Laser ablation chemical and spectroscopic studies of Calotropis procera, Chenopodium ambrosioides, and Nerium indicum leaves was performed using 1064 nm Nd: YAG laser in air at different pressure and time delay. These medicinal plant’s leaves are used by local people for different diseases. The knowledge of medicinal and toxic metals in these plants is very important. We have presented time-resolved studies of different elements and how their lives change with different delay time. C, H, Si, Al, Fe, Cu, Ca, Mg, Na, K, N, O, Sr and Ba have been detected in all the three samples with a molecular form of Carbon and Nitrogen band. We have detected C, H, N, and O as a major element while, Fe, Cu, Mg, K and Ca as essential medicinal metals with other trace elements such as Si, Sr, Al and Ba in all the three plants leaves. We present 1 µs delay time is the best time for elements lifetime in time resolved studies. The behaviour of intensity with different pressures was also studied and it was concluded that 7 torr was the best pressure for the maximum value of intensity. In particular, the electron density and the temperatures of the plasma were reported. The temperature was calculated from the well-known Boltzmann plot method and electron density was estimated from the stark broadened profile of the Hα line.

2016 ◽  
Vol 78 (3) ◽  
Author(s):  
Nurul Shuhada Tan Halid ◽  
Roslinda Zainal ◽  
Yaacob Mat Daud

LIBS plasma produced by a 1064 nm Q-switched Nd:YAG laser in an atmospheric pressure was studied for the stainless steel sample. The laser output energy 150 mJ with pulse duration of 6 ns. The plasma emission spectrum was recorded by the LR1 Spectrometer connected to the fibre optic. The plasma temperature and electron density of each element were estimated by time-resolved spectroscopy of neutral atom and ion line emission. The plasma temperature was obtained from the Boltzmann plot method and their electron density was determined by using Saha-Boltzmann equation method. The preliminary qualitative LIBS analysis shows that several elements contained in the stainless steel. The element detected was Cu, Fe, Mn, Ni, and Cr. The results shows that Mn and Fe has the highest plasma temperature of 1.2 eV,  but the electron density of Mn was the highest with value 4.6x1020 cm-3, while the Cu has the lowest temperature that is 0.73 eV with the electron density 2.8x1017 cm-3. The results are discussed.


2018 ◽  
Vol 16 (36) ◽  
pp. 113-122
Author(s):  
Ali A-K. Hussain

In this work, the spectra of plasma glow produced by Nd:YAG laser operated at 1.064 μm on Al-Mg alloys with same molar ratio samples in air were analyzed by comparing the atomic lines of aluminum and magnesium with that of strong standard lines. The effect of laser energies on spectral lines, produced by laser ablation, were investigated using optical spectroscopy, the electron density was measured utilizing the Stark broadening of magnesium-aluminum lines and the electron temperature was calculated from the standard Boltzmann plot method. The results that show the electron temperature increases in magnesium and aluminum targets but decreases in magnesium: aluminum alloy target, also show the electron density increase all the aluminum, magnesium and mix both them, It was found that the lines intensities at different laser peak powers increase when the laser peak power increases then decreases when the power continues to increase.


2020 ◽  
pp. 000370282097304
Author(s):  
Amal A. Khedr ◽  
Mahmoud A. Sliem ◽  
Mohamed Abdel-Harith

In the present work, nanoparticle-enhanced laser-induced breakdown spectroscopy was used to analyze an aluminum alloy. Although LIBS has numerous advantages, it suffers from low sensitivity and low detection limits compared to other spectrochemical analytical methods. However, using gold nanoparticles helps to overcome such drawbacks and enhances the LIBS sensitivity in analyzing aluminum alloy in the current work. Aluminum was the major element in the analyzed samples (99.9%), while magnesium (Mg) was the minor element (0.1%). The spread of gold nanoparticles onto the Al alloy and using a laser with different pulse energies were exploited to enhance the Al alloy spectral lines. The results showed that Au NPs successfully improved the alloy spectral lines intensity by eight times, which could be useful for detecting many trace elements in higher matrix alloys. Under the assumption of local thermodynamic equilibrium, the Boltzmann plot was used to calculate the plasma temperature. Besides, the electron density was calculated using Mg and H lines at Mg(I) at 285.2 nm and Hα(I) at 656.2 nm, respectively. Three-dimensional contour mapping and color fill images contributed to understanding the behavior of the involved effects.


1992 ◽  
Vol 46 (9) ◽  
pp. 1382-1387 ◽  
Author(s):  
J. A. Aguilera ◽  
C. Aragón ◽  
J. Campos

Laser-induced breakdown spectroscopy has been used to determine carbon content in steel. The plasma was formed by focusing a Nd:YAG laser on the sample surface. With the use of time-resolved spectroscopy and generation of the plasma in nitrogen atmosphere, a precision of 1.6% and a detection limit of 65 ppm have been obtained. These values are similar to those of other accurate conventional techniques. Matrix effects for the studied steels are reduced to a small slope difference between the calibration curves for stainless and nonstainless steels.


2010 ◽  
Vol 244 (4) ◽  
pp. 042005 ◽  
Author(s):  
Nek M Shaikh ◽  
Y Tao ◽  
R A Burdt ◽  
S Yuspeh ◽  
N Amin ◽  
...  

2007 ◽  
Vol 62 (12) ◽  
pp. 1329-1334 ◽  
Author(s):  
Matthieu Baudelet ◽  
Myriam Boueri ◽  
Jin Yu ◽  
Samuel S. Mao ◽  
Vincent Piscitelli ◽  
...  

AIP Advances ◽  
2019 ◽  
Vol 9 (6) ◽  
pp. 065214 ◽  
Author(s):  
Kaimin Guo ◽  
Anmin Chen ◽  
Wanpeng Xu ◽  
Dan Zhang ◽  
Mingxing Jin

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