Membrane filtration and sonication for industrial wastewater reuse

2011 ◽  
Vol 64 (12) ◽  
pp. 2500-2507 ◽  
Author(s):  
C. Caretti ◽  
E. Coppini ◽  
E. Fatarella ◽  
C. Lubello
Keyword(s):  
Textile Industry ◽  
Membrane Filtration ◽  
Formation Rate ◽  
Combined Treatment ◽  
Wastewater Reuse ◽  
Treatment Plant ◽  
Pilot Scale ◽  
Secondary Effluent ◽  
Treated Effluent ◽  
Target Values

This paper presents an experimental study aimed at estimating the efficiency of the innovative process of ultrafiltration (UF) combined with sonication (Son.) for the refinement of treated effluent to be reused in wet textile processes. Such a novel approach, which has not yet been employed on a full industrial scale, has been experienced at pilot scale on the secondary effluent of the Baciacavallo wastewater treatment plant (WWTP), which treats part of the effluent from one of the largest textile industry districts in Italy. The combined treatment efficiency was assessed both on ozonated and non-ozonated Baciacavallo secondary effluent. The membrane filtration process was optimized in terms of running time, backwash, chemical addition and cleaning procedures. The sonication treatment was optimized on laboratory-scale with synthetic solutions (demineralized water added with dyestuffs) in terms of hydroxyl radicals formation rate, frequency, acoustic power, hydrogen peroxide addition, contact time and pH. The optimal conditions have been applied on the pilot-scale sonicator which was used in combination with the UF treatment. According to the experimental results, the best configuration within the Baciacavallo WWTP was the sonication of non-ozonated wastewater followed by the UF. The combined treatment guaranteed the compliance with the target values for wastewater reuse in wet textile industries. This study is part of the Research Project PURIFAST (Purification of industrial and mixed wastewater by combined membrane filtration and sonochemical technologies) LIFE + ENV/IT/000439.

Textile Wastewater Reuse: Ozonation of Membrane Concentrated Secondary Effluent

1999 ◽  
Vol 40 (4-5) ◽  
pp. 99-105 ◽  
Author(s):  
A. Lopez ◽  
G. Ricco ◽  
R. Ciannarella ◽  
A. Rozzi ◽  
A. C. Di Pinto ◽  
...  
Keyword(s):  
Wastewater Treatment ◽  
Acute Toxicity ◽  
Wastewater Treatment Plant ◽  
Textile Industry ◽  
Nonionic Surfactants ◽  
Wastewater Reuse ◽  
Treatment Plant ◽  
Textile Wastewater ◽  
Secondary Effluent ◽  
Complete Disappearance

Among the activities appointed by the EC research-project “Integrated water recycling and emission abatement in the textile industry” (Contract: ENV4-CT95-0064), the effectiveness of ozone for improving the biotreatability of recalcitrant effluents as well as for removing from them toxic and/or inhibitory pollutants has been evaluated at lab-scale. Real membrane concentrates (pH=7.9; TOC=190 ppm; CDO=595 ppm; BOD5=0 ppm; Conductivity=5,000 μS/cm; Microtox-EC20=34%) produced at Bulgarograsso (Italy) Wastewater Treatment Plant by nanofiltering biologically treated secondary textile effluents, have been treated with ozonated air (O3conc.=12 ppm) over 120 min. The results have indicated that during ozonation, BOD5 increases from 0 to 75 ppm, whereas COD and TOC both decrease by about 50% and 30 % respectively. As for potentially toxic and/or inhibitory pollutants such as dyes, nonionic surfactants and halogenated organics, all measured as sum parameters, removals higher than 90% were achieved as confirmed by the complete disappearance of acute toxicity in the treated streams. The only ozonation byproducts searched for and found were aldehydes whose total amount continuously increased in the first hour from 1.2 up to 11.8 ppm. Among them, formaldehyde, acetaldehyde, glyoxal, propionaldehyde, and butyraldehyde were identified by HPLC.

scholarly journals Evaluation of PFCA removal by SAT using a pilot-scale reactor

2017 ◽  
Vol 12 (3) ◽  
pp. 706-716 ◽  
Author(s):  
Yugo Takabe ◽  
Fumitake Nishimura ◽  
Ryosuke Suzuki ◽  
Yasuhiro Asada ◽  
Yumeto Utsunomiya ◽  
...  
Keyword(s):  
Acid Level ◽  
Wastewater Reuse ◽  
Treatment Plant ◽  
Pilot Scale ◽  
Tracer Test ◽  
Soil Aquifer Treatment ◽  
Treated Effluent ◽  
Guideline Values ◽  
Pilot Scale Reactor ◽  
Scale Reactor

Wastewater reuse using soil aquifer treatment (SAT) is a rational and realistic solution in countries and regions with limited freshwater resources. The behaviour and removal of perfluoroalkyl carboxylic acids (PFCAs) under long hydraulic retention times (HRTs) in SAT may warrant further investigation. In this study, actual treated effluent from a wastewater treatment plant (WWTP) was continuously treated using a pilot-scale SAT reactor with a designed HRT of 30 days, located in the WWTP; PFCA removal characteristics were investigated based on a 14-month monitoring period. Continuous SAT reactor operations were accomplished for 30 months under the designed HRT (28 days, as calculated by a tracer test); stable treatments were achieved during the period, represented by dissolved organic matter removal from 3.94 mgC/L to 0.701 mgC/L. Removal of PFCAs by SAT under an HRT of 28 days was found to be difficult, as indicated by perfluorooctanoic acid level from 18.4 to 19.0 ng/L. In addition, PFCA concentrations may be increased after SAT, probably due to the influences of PFCA precursors; this is indicated by the increase in perfluorononanoic acid from 11.6 to 14.1 ng/L. Based on the guideline values, further removal of PFCAs in SAT-treated effluent may be required.

Comparison between PAA/UV and H2O2/UV disinfection for wastewater reuse

2002 ◽  
Vol 2 (1) ◽  
pp. 205-212 ◽  
Author(s):  
C. Lubello ◽  
C. Caretti ◽  
R. Gori
Keyword(s):  
Municipal Wastewater ◽  
Advanced Oxidation Process ◽  
Combined Treatment ◽  
Wastewater Reuse ◽  
Treatment Plant ◽  
Total Coliform ◽  
Secondary Effluent ◽  
Chemical Products ◽  
High Level ◽  
Very High

The effect of peracetic acid (PAA) on indicator bacteria in secondary sewage effluent has shown PAA to be a viable alternative to other biocides. The synergy between UV/PAA and UV/H2O2 in laboratory experiments and at a pilot plant fed by the secondary effluent of two civil wastewater treatment plant has been investigated. This experiment is part of a larger research project on advanced treatment for municipal wastewater reuse in agriculture. A very high level of disinfection is necessary because of Italy's strict limits on unrestricted wastewater reuse in agriculture (2 CFU Total Coliform/100 ml). We found out that a combined treatment is satisfactory and that it is more efficient when chemical products such as PAA or H2O2 are introduced before UV irradiation, taking advantage of the hydroxyl radicals formation due to photolysis. At a cost parity PAA/UV advanced oxidation process shows the same disinfectant action as H2O2/UV while at a dose (amount) and cost parity, PAA shows a significantly better disinfectant action than H2O2.

Antimicrobial resistance of fecal indicators in disinfected wastewater

2011 ◽  
Vol 64 (12) ◽  
pp. 2352-2361 ◽  
Author(s):  
A. Luczkiewicz ◽  
K. Jankowska ◽  
R. Bray ◽  
E. Kulbat ◽  
B. Quant ◽  
...  
Keyword(s):  
Antimicrobial Agents ◽  
Treatment Plant ◽  
Tetracycline Resistance ◽  
Pilot Scale ◽  
Resistant Bacteria ◽  
Secondary Effluent ◽  
Fecal Indicators ◽  
Extended Spectrum Beta Lactamase ◽  
E Coli ◽  
Operation Conditions

The main objective of the study was to assess the potential of three systems (UV irradiation, ozonation, and micro/ultrafiltration) operated in a pilot scale in removal of antimicrobial-resistant fecal bacteria from secondary effluent of the local wastewater treatment plant (700,000 population equivalent). The effectiveness of the processes was analysed using the removal ratio of fecal indicators (Escherichia coli and Enterococcus spp.). The susceptibility of fecal indicators to antimicrobial agents important in human therapy was examined. Resistance to nitrofurantoin and erythromycin was common among enterococci and followed by resistance to fluoroquinolones and tetracycline. Resistance to high-level aminoglycosides and glycopeptides was also observed. E. coli isolates were most frequently resistant to penicillins and tetracycline. The extended-spectrum beta-lactamase-producing E. coli was detected once, after ozonation. Substantial attention should be paid to the E. coli and enterococci resistant to three or more chemical classes of antimicrobials (MAR), which in general constituted up to 15 and 49% of the tested isolates, respectively. Although the applied methods were effective in elimination of fecal indicators (removal efficiency up to 99.99%), special attention has to be paid to the application of sufficient disinfection and operation conditions to avoid selection of antimicrobial resistant bacteria.

scholarly journals Microplastics Removal from Treated Wastewater by a Biofilter

Water ◽  
2020 ◽  
Vol 12 (4) ◽  
pp. 1085 ◽  
Author(s):  
Fan Liu ◽  
Nadia Nord ◽  
Kai Bester ◽  
Jes Vollertsen
Keyword(s):  
Particle Number ◽  
Treatment Plant ◽  
Complete Removal ◽  
Pilot Scale ◽  
Particle Mass ◽  
Treated Wastewater ◽  
Secondary Effluent ◽  
Global Environmental Issue ◽  
Wwtp Effluent ◽  
Global Environmental

Microplastic (MP) pollution is a global environmental issue, and traditionally treated wastewater has been identified as a source of land-based microplastics into the aquatic environment. This study evaluated the performance of a pilot-scale biofilter to polish wastewater treatment plant (WWTP) effluent before it enters the environment. The filter was divided into four zones, allowing the concentration of microplastics to be followed through the filter. It was fed with secondary effluent from a conventional WWTP in Denmark. The raw effluent from the WWTP contained 917 items m−3 which corresponded to a mass concentration of 24.8 µg m−3. After the top layer of the biofilter, the concentration had decreased to a median value of 197 item m−3 and 2.8 µg m−3, indicating an overall removal efficiency of 79% in terms of particle number and 89% in terms of particle mass. We also observed a tendency that MP of larger size and higher particle mass were more likely to be retained. After the last filtration zone, all MP larger than 100 µm had been removed. The results of this study demonstrate that biofilters are able to lower the MP abundance in treated wastewater significantly, but a complete removal is not ensured, hence some MP, particularly small-sized ones, can still be discharged into the receiving environment.

Nanofiltration of secondary effluent for wastewater reuse in the textile industry

Desalination ◽  
2008 ◽  
Vol 222 (1-3) ◽  
pp. 272-279 ◽  
Author(s):  
J.M. Gozálvez-Zafrilla ◽  
D. Sanz-Escribano ◽  
J. Lora-García ◽  
M.C. León Hidalgo
Keyword(s):  
Textile Industry ◽  
Wastewater Reuse ◽  
Secondary Effluent

scholarly journals Effect of O3 Dose on the O3/UV Treatment Process for the Removal of Pharmaceuticals and Personal Care Products in Secondary Effluent

2019 ◽  
Vol 3 (2) ◽  
pp. 53 ◽  
Author(s):  
N. Evelin Paucar ◽  
IIho Kim ◽  
Hiroaki Tanaka ◽  
Chikashi Sato
Keyword(s):  
Municipal Wastewater ◽  
Treatment Process ◽  
Limit Of Detection ◽  
Personal Care Products ◽  
Treatment Plant ◽  
Pilot Scale ◽  
Secondary Effluent ◽  
Municipal Wastewater Treatment ◽  
Personal Care ◽  
Uv Treatment

A municipal wastewater treatment plant (WWTP) is a melting pot of numerous pharmaceuticals and personal care products (PPCPs) together with many other substances. The removal of PPCPs using advanced oxidation processes within a WWTP is one way to reduce the amount of PPCPs that potentially enter an aquatic environment. The aim of this study was to examine the effectiveness of the ozone (O3)/UV treatment process, especially, the effects of O3 dose and reaction time, on the removal of PPCPs in the secondary effluent of a WWTP. Experiments were conducted using a pilot-scale treatment process that consisted of two flow-through reactors connected in series. Each reactor was equipped with three 65 W lamps (UV65W). The experimental variables were ozone dosage (1, 2, 3, 4, and 6 mg L−1) and hydraulic retention time (HRT; 5 and 10 min). On the basis of the PPCP concentrations after O3/UV65W treatment and their limit of detection (LOD), 38 PPCPs detected in the secondary effluent were classified into 5 groups ranging from the category of “sensitive” to O3/UV65W or “unstable” in the O3/UV65W process to the category of “insensitive” to O3/UV65W or “very stable” in the O3/UV65W process.

Investigation of potential surrogate organisms and public health risk in UV irradiated secondary effluent

2003 ◽  
Vol 47 (9) ◽  
pp. 37-43 ◽  
Author(s):  
D. Simpson ◽  
J. Jacangelo ◽  
P. Loughran ◽  
C. McIlroy
Keyword(s):  
Public Health ◽  
Health Risk ◽  
Treatment Plant ◽  
Pilot Scale ◽  
Acceptable Level ◽  
Uv Disinfection ◽  
Secondary Effluent ◽  
Indicator Organism ◽  
Indicator Organisms ◽  
Public Health Risk

Watercare's Mangere Wastewater Treatment Plant in Auckland, New Zealand treats sewage from a population equivalent of approximately 1,000,000. The treatment plant is currently undergoing a major upgrade, and as a part of this upgrade the largest UV disinfection plant in the world (at the time of award of the contract) is being constructed. Pilot scale investigations were undertaken at a purpose built facility. The pilot plant employed secondary treatment, sand filtration, UV disinfection and a number of low pressure membrane systems. Investigations at the facility focussed on attempting to identify relationships between potential surrogate indicator organisms (including enterococci, faecal coliforms, Clostridium perfringens spores and F-specific bacteriophage) and pathogenic organisms (including culturable human enteric viruses, bacterial pathogens and parasites). The aim of the study was to identify a suitable indicator organism and an associated effluent concentration that would ensure that an acceptable level of public health risk was maintained in the environment. The results showed that no suitable surrogate indicator organism could be found. However the results did indicate that a two tiered operating strategy, based on the concentration of enteroviruses present in raw sewage and an appropriate UV dose, would ensure that an acceptable level of public health risk was maintained in the environment.

An integrated wastewater reuse concept combining natural reclamation techniques, membrane filtration and metal oxide adsorption

2008 ◽  
Vol 57 (6) ◽  
pp. 909-914 ◽  
Author(s):  
A. Sperlich ◽  
X. Zheng ◽  
M. Jekel ◽  
M. Ernst
Keyword(s):  
Membrane Fouling ◽  
Water Reuse ◽  
Membrane Filtration ◽  
Sodium Hydroxide Solution ◽  
Wastewater Reuse ◽  
Ferric Hydroxide ◽  
Operation Time ◽  
Pilot Scale ◽  
Phosphorus Concentration ◽  
Total Phosphorus Concentration

In a Sino-German research project, a sustainable water reclamation concept was developed for different applications of municipal water reuse at the Olympic Green 2008 in Beijing, China. Results from pilot-scale experiments in Beijing and Berlin show that selective nutrient removal by adsorption onto granular ferric hydroxide (GFH) after a membrane bioreactor (MBR) can maintain a total phosphorus concentration of <0.03 μg L−1 P, thus preventing eutrophication of artificial lakes. Operation time of GFH adsorption columns can be extended by regeneration using sodium hydroxide solution. A subsequent ultrafiltration (UF) membrane after bank filtration creates an additional barrier for pathogens and allows for further urban reuse applications such as toilet flushing. Short term bank / bio-filtration prior to UF is shown to effectively remove biopolymers and reduce membrane fouling.

The fouling characterization and control in the high concentration PAC membrane bioreactor HCPAC-MBR

2005 ◽  
Vol 51 (6-7) ◽  
pp. 77-84 ◽  
Author(s):  
G.T. Seo ◽  
S.W. Jang ◽  
S.H. Lee ◽  
C.H. Yoon
Keyword(s):  
Membrane Fouling ◽  
Membrane Filtration ◽  
Treatment Plant ◽  
Water Treatment Plant ◽  
Pilot Scale ◽  
High Concentration ◽  
Nakdong River Basin ◽  
Cake Layer ◽  
Experimental Apparatus ◽  
Operation Period

This study focuses on the experimental investigation to identify the effect of PAC at high concentrations on the fouling of membranes. A pilot-scale experimental apparatus was installed at a water treatment plant located downstream of Nakdong river basin, Korea. Effluent of rapid sand filter was used as influent of the system, which consists of PAC bio-reactor, submerged membrane module (hollow fiber with pore size 0.1 μm) and air supply facility. PAC was dosed at 40 g/L initially and it was not replaced during the operation period. Suction type filtration was carried out at intervals of 12 min. suction and 3 min. idling. At the initial flux 0.36 m/d, the system could be operated stably for around 90 days at target trans-membrane pressure (TMP) of 40 kPa. Among total resistance of membrane filtration, cake and gel layer resistance, Rc+Rg, was the dominant fraction (more than 90% of the total) to increase the filtration pressure, which means that the filtration resistance could be controlled by the PAC cake layer and then irreversible membrane fouling could be prevented. Three minutes air backwashing every 3 days could extend the operation period to 127 days. Organics were analyzed in terms of molecular weight structure. The influent of the system consists of 15.0% and 74.4% of hydrophobic and hydrophilic natural organic matter (NOM), respectively. Hydrophobic and hydrophilic (electrostatic) interaction was the main factor on fouling of the membrane in the reactor. Hydrophobic fraction decreased slightly in the effluent, which means hydrophobic NOM removal in the reactor by adsorption. Organics accumulated in the membrane were extracted for analysis after a certain period of operation. The fraction of hydrophobic and hydrophilic organics was 41.4% and 38.9%, respectively. On the basis of the experimental results, the hydrophobic organics were the major materials causing the fouling of the membrane, which should be changed to other types of material.

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