scholarly journals Effect of O3 Dose on the O3/UV Treatment Process for the Removal of Pharmaceuticals and Personal Care Products in Secondary Effluent

2019 ◽  
Vol 3 (2) ◽  
pp. 53 ◽  
Author(s):  
N. Evelin Paucar ◽  
IIho Kim ◽  
Hiroaki Tanaka ◽  
Chikashi Sato

A municipal wastewater treatment plant (WWTP) is a melting pot of numerous pharmaceuticals and personal care products (PPCPs) together with many other substances. The removal of PPCPs using advanced oxidation processes within a WWTP is one way to reduce the amount of PPCPs that potentially enter an aquatic environment. The aim of this study was to examine the effectiveness of the ozone (O3)/UV treatment process, especially, the effects of O3 dose and reaction time, on the removal of PPCPs in the secondary effluent of a WWTP. Experiments were conducted using a pilot-scale treatment process that consisted of two flow-through reactors connected in series. Each reactor was equipped with three 65 W lamps (UV65W). The experimental variables were ozone dosage (1, 2, 3, 4, and 6 mg L−1) and hydraulic retention time (HRT; 5 and 10 min). On the basis of the PPCP concentrations after O3/UV65W treatment and their limit of detection (LOD), 38 PPCPs detected in the secondary effluent were classified into 5 groups ranging from the category of “sensitive” to O3/UV65W or “unstable” in the O3/UV65W process to the category of “insensitive” to O3/UV65W or “very stable” in the O3/UV65W process.

2013 ◽  
Vol 2013 ◽  
pp. 1-10 ◽  
Author(s):  
George Tangyie Chi ◽  
John Churchley ◽  
Katherine D. Huddersman

The pollution of water sources by endocrine disrupting compounds (EDCs) and pharmaceutical and personal care products (PPCPs) is a growing concern, as conventional municipal wastewater treatment systems are not capable of completely removing these contaminants. A continuous stir tank reactor incorporating a modified polyacrylonitrile (PAN) catalyst and dosed with hydrogen peroxide in a heterogeneous Fenton’s process was used at pilot scale to remove these compounds from wastewater that has undergone previous treatment via a conventional wastewater treatment system. The treatment system was effective at ambient temperature and at the natural pH of the wastewater. High levels of both natural and synthetic hormones (EDCs) and PPCPs were found in the effluent after biological treatment of the wastewater. The treatment system incorporating the modified PAN catalyst/H2O2decomposed >90% of the EDCs and >40% of PPCPs using 200 mgL−1H2O2, 3 hr residence time. The estrogenic potency EE2-EQ was removed by 82.77%, 91.36%, and 96.13% from three different wastewater treatment plants. BOD was completely removed (below detection limits); 30%–40% mineralisation was achieved and turbidity reduced by more than 68%. There was a <4% loss in iron content on the catalyst over the study period, suggesting negligible leaching of the catalyst.


1994 ◽  
Vol 30 (4) ◽  
pp. 125-132 ◽  
Author(s):  
D. Carnimeo ◽  
E. Contini ◽  
R. Di Marino ◽  
F. Donadio ◽  
L. Liberti ◽  
...  

The pilot investigation on the use of UV as an alternative disinfectant to NaOCI was started in 1992 at Trani (South Italy) municipal wastewater treatment plant (335 m3/h). The results collected after six months continuous operation enabled us to compare UV and NaOCl disinfection effectiveness on the basis of secondary effluent characteristics, quantify photoreactivation effects, evidence possible DBP formation and assess costs.


2013 ◽  
Vol 838-841 ◽  
pp. 2712-2716
Author(s):  
Yong Tu ◽  
Yong Gang Bai ◽  
Yong Chen ◽  
Wei Jing Liu ◽  
Jun Xu ◽  
...  

The research on ultrafiltration membrane assisted by powdered zeolite for the treatment of secondary effluent from a municipal wastewater treatment plant was studied. The results show that membrane fouling rate is reduced by pre-coating the ultrafiltration membrane with powdered zeolite, and the treatment performance of secondary effluent is enhanced. UV-vis, three-dimensional excitation emission matrix (3D-EEM) fluorescence spectra and scanning electron microscopy (SEM) images for ultrafiltration were also discussed.


2019 ◽  
Vol 252 ◽  
pp. 05010
Author(s):  
Paweł Król ◽  
Alberto Gallina ◽  
Michał Lubieniecki ◽  
Tadeusz Uhl ◽  
Tadeusz Żaba

Waste management is a crucial process to keep the environment in wholesome conditions. The environmental impact of solid waste and wastewater is reduced through construction of appropriate disposal installations. The objective of wastewater treatment in biological reactors is to control the process of biomaterial growth by aerating the sewage content. The process is complex, as depending on a plenty of parameters. In the last decades an effective numerical model, called the Activated Sludge Model (ASM), has been proposed for describing the biological process. The ASM is implemented in the Benchmark Simulation Model (BSM) that simulates the whole wastewater treatment process. The most important parameters in ASM are the kinetic and stoichiometric coefficients. The former describes rate-concentration dependence. The latter characterises the relationship between the components of chemical reactions taking place in the cleaning process. Above parameters are determined by on-site calibration and their importance is relevant during the development of numeric models. This paper aims to examine the influence of kinetic and stoichiometric parameters on the wastewater treatment process of a plant in Płaszów, Kraków. The analysis is carried out by a sample-based numerical procedure. It highlights the ASM parameters playing a major role in the treatment process. Results obtained from the analysis are important for future validation and optimisation processes.


2000 ◽  
Vol 41 (4-5) ◽  
pp. 361-368 ◽  
Author(s):  
L. Bonomo ◽  
G. Pastorelli ◽  
E. Quinto ◽  
G. Rinaldi

Two bench-scale reactors, fed with the secondary effluent of a municipal wastewater treatment plant (WWTP), were used in order to study tertiary nitrification in pure oxygen moving bed biofilm reactors (PO-MBBRs) with patented KMT® media as biofilm carriers. The process allowed to measure very high nitrification rates, both in ammonia limiting conditions (up to 7 gN m−2 d−1; oxygen-to-ammonia nitrogen ratio higher than 3–4 mgO2 (mgN)−1) and in oxygen limiting conditions (up to 8 gN m−2 d−1; oxygen-to-ammonia nitrogen ratio lower than 1–2 mgO2 (mgN)−1). Since the process proved flexible and reliable, it is suitable for full-scale application to municipal WWTPs. Typical application could regard, but is not limited to, tertiary nitrification of secondary effluent from existing high-purity oxygen activated sludge systems designed to achieve only organic carbon removal.


2014 ◽  
Vol 21 (2) ◽  
pp. 245-254
Author(s):  
Wioleta Stelmach ◽  
Paweł Szarlip ◽  
Andrzej Trembaczowski

Abstract Investigations of processes occurring during wastewater treatment have progressed beyond the stage of technology. Currently, great numbers of representatives of diverse specialist research apply increasingly sophisticated measurement methods that have not been employed in this field of science. One of the methods is IRMS (Isotope Ratio Mass Spectrometry). Tracking changes in the ratios of biogenic element isotopes is useful in eg identification and monitoring of investigated processes. Since the IRMS technique has hardly been used for investigations of the wastewater treatment process, pilot research should be instigated to determine the isotope ratios occurring naturally in the process. The aim of the study was to determine changes in carbon and nitrogen isotope ratios at the successive stages of the technological line in wastewater treatment plants. The study material comprised: i) suspensions of raw sewage and mixtures of wastewater and activated sludge; ii) gases sampled from the volume of the suspensions; iii) gases sampled from the air above the suspension surface. The research material originated from the facilities of “Hajdow” municipal wastewater treatment plant in Lublin (SE Poland). The samples were analysed for the carbon and nitrogen isotope ratios, and the concentrations of the gases as well as total organic carbon (TOC), inorganic carbon (IC), Kjeldahl nitrogen (KN), dry weight, pH, and Eh were determined. The results obtained suggest that: i) the IRMS technique can be successfully applied in investigations of processes occurring during wastewater treatment; ii) isotope ratios in the carbon and nitrogen compounds (CO2 and N2) both in the suspensions and gases contained therein and in the air above them differ from each other and change at the different stages of the treatment process; iii) further research is indispensable in order to identify processes responsible for fractionation of carbon and nitrogen isotopes.


2018 ◽  
Vol 77 (11) ◽  
pp. 2723-2732 ◽  
Author(s):  
Xiaowei Zheng ◽  
Shenyao Zhang ◽  
Jibiao Zhang ◽  
Deying Huang ◽  
Zheng Zheng

Abstract With the improvement of wastewater discharge standards, wastewater treatment plants (WWTPs) are continually undergoing technological improvements to meet the evolving standards. In this study, a quartz sand deep bed denitrification filter (DBDF) was used to purify WWTP secondary effluent, utilizing high nitrate nitrogen concentrations and a low C/N ratio. Results show that more than 90% of nitrate nitrogen (NO3-N) and 75% of chemical oxygen demand (COD) could be removed by the 20th day of filtration. When the filter layer depth was set to 1,600 mm and the additional carbon source CH3OH was maintained at 30 mg L−1 COD (20 mg L−1 methanol), the total nitrogen (TN) and COD concentrations of DBDF effluent were stabilized below 5 and 30 mg L−1, respectively. Analysis of fluorescence revealed that DBDF had a stronger effect on the removal of dissolved organic matter (DOM), especially of aromatic protein-like substances. High throughput sequencing and qPCR results indicate a distinctly stratified microbial distribution for the main functional species in DBDF, with quartz sand providing a good environment for microbes. The phyla Proteobacteria, Bacteroidetes, and Chloroflexi were found to be the dominant species in DBDF.


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