Enhancing oxidation of TNT and RDX in wastewater: pre-treatment with elemental iron

2003 ◽  
Vol 47 (10) ◽  
pp. 93-99 ◽  
Author(s):  
S.-Y. Oh ◽  
D.K. Cha ◽  
P.C. Chiu ◽  
B.J. Kim
Keyword(s):  
Treatment Process ◽  
Complete Removal ◽  
Column Length ◽  
Energetic Compounds ◽  
One Dimensional ◽  
Elemental Iron ◽  
Advection Dispersion ◽  
Fenton’S Oxidation ◽  
Pre Treatment ◽  
Fenton's Oxidation

Munitions manufacturing wastewater is commonly treated by adsorption to activated carbon. We are proposing a new munitions manufacturing wastewater treatment system consisting of a reductive pre-treatment process and subsequent Fenton's oxidation to mineralize energetic compounds such as TNT and RDX. The pre-treatment involves reduction of electron-withdrawing nitro groups of TNT and RDX with elemental iron. The iron-treated explosives are then oxidized by Fenton's reagent through the addition of H2O2. The objective of this work is to investigate the feasibility of using elemental iron to convert TNT and RDX to reduction products which may be more oxidizable in subsequent Fenton's oxidation. Results of batch reduction experiments with elemental iron showed complete removal of TNT and RDX and formation of the reduction products within 60 minutes. Results of column experiments showed a rapid and complete removal of TNT and RDX within 9.7 minutes retention time. Fitting observed effluent concentrations to a one-dimensional advection-dispersion equation, we were able to predict the concentration profiles of TNT and RDX in the iron column and calculate the iron column length required for the desired removal. The results of Fenton's oxidation experiments showed that iron pre-treatment enhanced both the rate and extent of TNT and RDX mineralization by Fenton's oxidation.

scholarly journals Pre-treatment of industrial landfill leachate by Fenton’s oxidation

2013 ◽  
Vol 9 (1) ◽  
pp. 51-56
Keyword(s):  
Reaction Time ◽  
Landfill Leachate ◽  
Oxidation Reaction ◽  
Organic Load ◽  
Solution Ph ◽  
Reaction Solution ◽  
Fenton’S Oxidation ◽  
Initial Ph ◽  
Pre Treatment ◽  
Fenton's Oxidation

Biological treatment (aerobic and anaerobic) of industrial landfill leachate is limited by the presence of toxic contaminants (e.g., heavy metals) and recalcitrant (biopersistent) organics (e.g., polyphenols, pharmaceuticals, cosmetics, etc.,), hindering viable conditions for biomass proliferation in biological reactors, with difficulties in meeting concentration limits imposed by applied regulations. Fenton’s oxidation by the use of Fe2+-H2O2-H+ mixture may be used as a pre-treatment of industrial landfill leachate for preliminary abatement of the organic load and to improve biodegradability (BOD/COD>0.4) to favour biological oxidation in conventional wastewater treatment plants. Leachate from Grottaglie (S.E. Italy) non-hazardous landfill (pH 8.6; COD=11.000 mg l-1; BOD5=2.400 mg l-1; NH4-N=2.900 mg l-1; conductivity=60.000 μS cm-1) was laboratory tested in different operative conditions, i.e., initial pH, Fe2+/H2O2 ratio, concentrations and reaction time. The oxidation reaction was monitored by equilibrium pH and residual COD and BOD5 concentrations. Best operative conditions were obtained at pH 3, Fe2+=700 mg l-1, H2O2=9,900 mg l-1 (H2O2/Fe2+ratio~13w/w), reaction time=2h. Following the oxidation reaction, solution pH was neutralized by the addition of Ca(OH)2 or NaOH (120 meq l-1) for further abatement of target parameters by precipitation/sorption. Preliminary technical/economical evaluation of possible process schemes is also given in the paper.

Comparison of Fenton's oxidation and ozonation for removal of estrogens

2011 ◽  
Vol 63 (10) ◽  
pp. 2131-2137 ◽  
Author(s):  
Jana Nakrst ◽  
Mirjana Bistan ◽  
Tatjana Tišler ◽  
Jana Zagorc-Končan ◽  
Jan Derco ◽  
...  
Keyword(s):  
Estrogenic Activity ◽  
Complete Removal ◽  
Molar Ratio ◽  
Chemical Analyses ◽  
Screening Assay ◽  
Molar Ratios ◽  
Fenton’S Oxidation ◽  
17Β Estradiol ◽  
Fenton's Oxidation ◽  
By Products

This study compares efficiency of Fenton's oxidation and ozonation of 17β-estradiol (E2) and 17α-ethinylestradiol (EE2) as two possible processes for removal of estrogens from aqueous solutions. The effectiveness of Fenton's oxidative removal was studied at different ratios of reagents Fe2+:H2O2 (1:0.5; 1:10; 1:20; 1:33), where with some molar ratios up to 100% removal of E2 and EE2 was achieved in the first few minutes of reaction. The best molar ratio for E2 (17β-estradiol) removal was 1:33, while in the case of EE2 the most efficient one was 1:20 ratio. Ozonation was much faster, because complete removal of estrogens was achieved in 30 seconds (pH≈6), but the time of ozonation was extended up to 60 minutes trying to decompose formed by-products, expressing estrogenic activity, detected by YES (Yeast Estrogen Screening) assay. The obtained results showed that the removal efficiency of estrogens from waters should be assessed by a combination of chemical analyses and bioassay.

Reuse of Wastewaters in Agriculture by Means of Sprinkler Irrigation on a Farmland Area of 3000 ha – Large Scale Experience in Germany

1986 ◽  
Vol 18 (9) ◽  
pp. 163-173
Author(s):  
R. Boll ◽  
R. Kayser
Keyword(s):  
Large Scale ◽  
Treatment Process ◽  
Treatment Plant ◽  
Sprinkler Irrigation ◽  
Paper Briefly ◽  
Treatment Results ◽  
Sewage Farm ◽  
Western Germany ◽  
Pre Treatment ◽  
Main Components

The Braunschweig wastewater land treatment system as the largest in Western Germany serves a population of about 270.000 and has an annual flow of around 22 Mio m3. The whole treatment process consists of three main components : a pre-treatment plant as an activated sludge process, a sprinkler irrigation area of 3.000 ha of farmland and an old sewage farm of 200 ha with surface flooding. This paper briefly summarizes the experiences with management and operation of the system, the treatment results with reference to environmental impact, development of agriculture and some financial aspects.

Vivianite Occurrence and Remediation Techniques in Biosolids Pre-treatment Process

2018 ◽  
Vol 2018 (4) ◽  
pp. 103-117
Author(s):  
Bipin Pathak ◽  
Ahmed Al-Omari ◽  
Scott Smith ◽  
Nicholas Passarelli ◽  
Ryu Suzuki ◽  
...  
Keyword(s):  
Treatment Process ◽  
Pre Treatment

Initial-boundary value problems for the one-dimensional linear advection–dispersion equation with decay

2020 ◽  
Vol 75 (8) ◽  
pp. 713-725 ◽  
Author(s):  
Guenbo Hwang
Keyword(s):  
Boundary Conditions ◽  
Dirichlet Boundary ◽  
Boundary Value ◽  
Initial Boundary ◽  
Initial Boundary Value Problems ◽  
One Dimensional ◽  
Advection Dispersion ◽  
Asymptotically Periodic ◽  
The One ◽  
Initial Boundary Value

AbstractInitial-boundary value problems for the one-dimensional linear advection–dispersion equation with decay (LAD) are studied by utilizing a unified method, known as the Fokas method. The method takes advantage of the spectral analysis of both parts of Lax pair and the global algebraic relation coupling all initial and boundary values. We present the explicit analytical solution of the LAD equation posed on the half line and a finite interval with general initial and boundary conditions. In addition, for the case of periodic boundary conditions, we show that the solution of the LAD equation is asymptotically t-periodic for large t if the Dirichlet boundary datum is periodic in t. Furthermore, it can be shown that if the Dirichlet boundary value is asymptotically periodic for large t, then so is the unknown Neumann boundary value, which is uniquely characterized in terms of the given asymptotically periodic Dirichlet boundary datum. The analytical predictions for large t are compared with numerical results showing the excellent agreement.

scholarly journals Bioethanolic yeasts from dung beetles: tapping the potential of extremophilic yeasts for improvement of lignocellulolytic feedstock fermentation

2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Anita Ejiro Nwaefuna ◽  
Karl Rumbold ◽  
Teun Boekhout ◽  
Nerve Zhou
Keyword(s):  
Treatment Process ◽  
Dung Beetles ◽  
Production Costs ◽  
Industrial Wastes ◽  
Major Drawback ◽  
Renewable Fuel ◽  
Extreme Stress ◽  
Pre Treatment ◽  
The Cost ◽  
Simultaneous Saccharification

AbstractBioethanol from abundant and inexpensive agricultural and industrial wastes possesses the potential to reduce greenhouse gas emissions. Bioethanol as renewable fuel addresses elevated production costs, as well as food security concerns. Although technical advancements in simultaneous saccharification and fermentation have reduced the cost of production, one major drawback of this technology is that the pre-treatment process creates environmental stressors inhibitory to fermentative yeasts subsequently reducing bioethanol productivity. Robust fermentative yeasts with extreme stress tolerance remain limited. This review presents the potential of dung beetles from pristine and unexplored environments as an attractive source of extremophilic bioethanolic yeasts. Dung beetles survive on a recalcitrant lignocellulose-rich diet suggesting the presence of symbiotic yeasts with a cellulolytic potential. Dung beetles inhabiting extreme stress environments have the potential to harbour yeasts with the ability to withstand inhibitory environmental stresses typically associated with bioethanol production. The review further discusses established methods used to isolate bioethanolic yeasts, from dung beetles.

Temperature dependence of germinability of wheat (Triticum aestivum L.) grain in relation to pre-harvest sprouting

1984 ◽  
Vol 35 (2) ◽  
pp. 115 ◽  
Author(s):  
DJ Mares
Keyword(s):  
Dry Weight ◽  
Complete Removal ◽  
Triticum Aestivum L ◽  
Treatment Temperature ◽  
Preharvest Sprouting ◽  
Optimum Temperature ◽  
Grain Dormancy ◽  
Lag Period ◽  
Pre Treatment ◽  
Damage Tolerant

Germinability in harvest-mature wheat grain showed a marked dependence on temperature. The optimum temperature for the complete germination of all grains ranged from 20�C for the non-dormant variety, Timgalen, to 10�C for the strongly dormant red wheat RL 4137, whereas the optimum in terms of the shortest lag period ranged from 25� to 15�C for the same varieties. Germinability gradually increased during post-harvest storage and, for after-ripened grain, the optimum temperature for both complete germination and shortest lag period were greater than 30�C. Germinability could also be increased by pre-treating imbibing grains at temperatures of 5�, 10� or in some cases 15�C. This treatment was only effective for grain at moisture contents >25% (dry weight) and the effect was not reversed by redesiccation. The pre-treatment temperature required for maximum germinability decreased with increasing levels of grain dormancy. Complete removal of dormancy required a pre-treatment period of c. 48 h; however, lesser periods gave the shortest lag period in the case of the dormant varieties. The implications of these results for the utilization of dormancy in the development of preharvest sprouting damage tolerant varieties and their subsequent use in practice are discussed.

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