Fenton’s Oxidation of Phenalkamine Condensate Using Aluminium Dross and Laterite Iron Nanoparticle as a Catalyst

2019 ◽  
Author(s):  
Dhitosh Kumar Sahoo ◽  
Varsha M ◽  
Dr. B. Manu
Author(s):  
Rui C. Martins ◽  
Fernando J.R. Abegão ◽  
Adrián M.T. Silva ◽  
Rosa M. Quinta-Ferreira

AbstractThe present research is based on a case-study involving the development of an adequate treatment for agro-effluents originating from wineries. Flocculation, Fenton’s oxidation and ozonation processes were investigated in order to define the best integration strategy that may conduce to optimal efficiency of degradation and operational cost. Chemical oxygen demand (COD), total suspended solids (TSS), and total organic carbon (TOC) were some of the parameters used to analyze the performance of these technologies. The higher COD and TSS removals (73% and 94% respectively) were achieved combining the ozonation treatment with the Fenton process. In addition, the respective cost of COD reduction is lower in this case, when compared with other alternatives. Flocculation revealed not to be needed since in the ozonation process the suspended solids are able to be degraded.


2015 ◽  
Vol 41 (4) ◽  
pp. 33-39 ◽  
Author(s):  
Haiming Zou ◽  
Wanzheng Ma ◽  
Yan Wang

Abstract Dye wastewater is one of typically non-biodegradable industrial effluents. A new process linking Fenton’s oxidation with biological oxidation proposed in this study was investigated to degrade the organic substances from real dye wastewater. During the combination process, the Fenton’s oxidation process can reduce the organic load and enhance biodegradability of dye wastewater, which is followed by biological aerated filter (BAF) system to further remove organic substances in terms of discharge requirement. The results showed that 97.6% of chemical oxygen demand (COD) removal by the combination process was achieved at the optimum process parameters: pH of 3.5, H2O2 of 2.0 mL/L, Fe(II) of 500 mg/L, 2.0 h treatment time in the Fenton’s oxidation process and hydraulic retention time (HRT) of 5 h in the BAF system. Under these conditions, COD concentration of effluent was 72.6 mg/L whereas 3020 mg/L in the influent, thus meeting the requirement of treated dye wastewater discharge performed by Chinese government (less than 100 mg/L). These results obtained here suggest that the new process combining Fenton’s oxidation with biological oxidation may provide an economical and effective alternative for treatment of non-biodegradable industrial wastewater.


2014 ◽  
Vol 1044-1045 ◽  
pp. 215-218
Author(s):  
Xian Huan Qiu ◽  
Hai Yu ◽  
Peng Fei Deng

In the presence of acetic acid, the effects of pH, processing time, addition of Fe2+ and H2O2 on dye wastewater treatment were studied. Experimental results showed that in the presence of acetic acid, when the pH value was 4, the processing time was 30.0min, addition of ferrous sulfate was 4.8g/L, and addition of hydrogen peroxide was 56mL/L, the treatment effect was the best, COD removal rate reached 51.0%. Further studied of the effect of the presence of acetic acid on Fenton’s oxidation of dye wastewater, the results showed that without of acetic acid, the COD removal rate was higher than that with acetic acid. And the effect of Fenton's reagent on oxidation of dye substances was interfered by the presence of acetic acid.


2002 ◽  
Vol 45 (12) ◽  
pp. 189-196 ◽  
Author(s):  
M. Altinbas ◽  
I. Ozturk ◽  
A.F. Aydin

The aim of the study was to investigate ammonia recovery from high strength agro industry effluents involving significant amounts of ammonia, by applying magnesium ammonium phosphate (MAP) precipitation technology. Two types of industrial effluents have been tested in the study. The first plant was an opium alkaloid processing industry and the second one was a baker`s yeast industry. High chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN) and unacceptable dark brown color characterized effluents from both industries. Effluents from the biologically treated opium alkaloid and baker's yeast industries were both applied at the stoichiometric ratio (Mg:NH4:PO4 =1:1:1) and above the stoichiometric ratio (Mg:NH4:PO4 =1.1:1:1.1) to MAP precipitation. NH4 removals of 61-80% were achieved at the pH of 9.2 at the stoichiometric ratio, whereas 83% NH4 removal was obtained at the pH of 9.2 above the stoichiometric ratio. Experimental studies performed on both anaerobically and/or aerobically treated baker`s yeast and opium alkaloid industry effluents have clearly indicated that MAP precipitation was an appropriate treatment option for NH4 removal or struvite recovery from high ammonia content agro industry effluents. Additional ammonia recovery studies were conducted on ozonated and Fenton's oxidation applied effluents and these have also indicated that the amounts of struvite and the quality of MAP precipitate was increased significantly. In this framework, MAP sludge recovered from combined biological and Fenton's oxidation treatment effluents were considered as a more valuable slow release fertilizer for agricultural use.


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