scholarly journals Comparing Markets Rents from a User Cost and Reaction Model

2010 ◽  
Author(s):  
Marc Francke
Keyword(s):  
Reaction Model ◽  
User Cost

Intensification of cooling in a batch reactor with an exothermic reaction by nonisothermal control in stable pseudostationary states

1984 ◽  
Vol 49 (11) ◽  
pp. 2566-2578 ◽  
Author(s):  
Josef Horák ◽  
Petr Beránek ◽  
Dagmar Maršálková
Keyword(s):  
Batch Reactor ◽  
Exothermic Reaction ◽  
Reaction Model ◽  
Order Reaction ◽  
Zero Order ◽  
Coolant Temperature ◽  
Inlet Temperature ◽  
Adaptive Parameter ◽  
Zero Order Reaction ◽  
Set Up

An algorithm is set up and tested for the temperature control of a batch reactor consisting in jump changes in the inlet temperature of entering coolant. This temperature is so chosen that its difference from the temperature of the reaction mixture is near the highest difference at which the stable pseudostationary state of the system still exists. For the prediction of the new coolant inlet temperature, a zero-order reaction model is used with an adaptive parameter estimated from the experimentally established value of the maximum of the reaction mixture overheating at the previous coolant temperature.

Numerical Approximations to Solution of Biochemical Reaction Model

2011 ◽  
Vol 9 (1) ◽  
Author(s):  
Ahmet Yildirim ◽  
Ahmet Gökdogan ◽  
Mehmet Merdan
Keyword(s):  
Analytical Solution ◽  
Approximate Analytical Solution ◽  
Transformation Method ◽  
Reaction Model ◽  
Biochemical Reaction ◽  
Graphical Form ◽  
Kutta Method ◽  
Transform Method ◽  
Runge Kutta Method ◽  
Differential Transform

In this paper, approximate analytical solution of biochemical reaction model is used by the multi-step differential transform method (MsDTM) based on classical differential transformation method (DTM). Numerical results are compared to those obtained by the fourth-order Runge-Kutta method to illustrate the preciseness and effectiveness of the proposed method. Results are given explicit and graphical form.

Gas Cell Infrared and Attenuated Total Reflection Infrared Spectroscopic Studies for Organic–Inorganic Interactions in Adsorption of Fulvic Acid on the Goethite Surface Generating Carbon Dioxide

2021 ◽  
pp. 000370282199121
Author(s):  
Yuki Nakaya ◽  
Satoru Nakashima ◽  
Takahiro Otsuka
Keyword(s):  
Carbon Dioxide ◽  
Activation Energy ◽  
Fulvic Acid ◽  
Spectroscopic Studies ◽  
Reaction Model ◽  
Total Reflection ◽  
Attenuated Total Reflection ◽  
Gas Cell ◽  
Rate Determining Step ◽  
Ir Spectroscopic

The generation of carbon dioxide (CO2) from Nordic fulvic acid (FA) solution in the presence of goethite (α-FeOOH) was observed in FA–goethite interaction experiments at 25–80 ℃. CO2 generation processes observed by gas cell infrared (IR) spectroscopy indicated two steps: the zeroth order slower CO2 generation from FA solution commonly occurring in the heating experiments of the FA in the presence and absence of goethite (activation energy: 16–19 kJ mol–1), and the first order faster CO2 generation from FA solution with goethite (activation energy: 14 kJ mol–1). This CO2 generation from FA is possibly related to redox reactions between FA and goethite. In situ attenuated total reflection infrared (ATR-IR) spectroscopic measurements indicated rapid increases with time in IR bands due to COOH and COO– of FA on the goethite surface. These are considered to be due to adsorption of FA on the goethite surface possibly driven by electrostatic attraction between the positively charged goethite surface and negatively charged deprotonated carboxylates (COO–) in FA. Changes in concentration of the FA adsorbed on the goethite surface were well reproduced by the second order reaction model giving an activation energy around 13 kJ mol–1. This process was faster than the CO2 generation and was not its rate-determining step. The CO2 generation from FA solution with goethite is faster than the experimental thermal decoloration of stable structures of Nordic FA in our previous report possibly due to partial degradations of redox-sensitive labile structures in FA.

scholarly journals A Comprehensive Life-Cycle Cost Analysis Approach Developed for Steel Bridge Deck Pavement Schemes

Coatings ◽  
2021 ◽  
Vol 11 (5) ◽  
pp. 565
Author(s):  
Changbo Liu ◽  
Zhendong Qian ◽  
Yang Liao ◽  
Haisheng Ren
Keyword(s):  
Life Cycle ◽  
Life Cycle Cost ◽  
Bridge Deck ◽  
Analysis Approach ◽  
Steel Bridge ◽  
User Cost ◽  
Construction Quality ◽  
Concrete System ◽  
Traffic Conditions ◽  
Bridge Deck Pavement

This study aims to evaluate the economy of a steel bridge deck pavement scheme (SBDPS) using a comprehensive life-cycle cost (LCC) analysis approach. The SBDPS are divided into the “epoxy asphalt concrete system”(EA system) and“ Gussasphalt concrete system”(GA system) according to the difference in the material in the lower layer of the SBDPS. A targeted LCC checklist, including manager cost and user cost was proposed, and a Markov-based approach was applied to establish a life-cycle performance model with clear probability characteristics for SBDPS. Representative traffic conditions were designed using a uniform design method, and the LCC of SBDPS under representative traffic conditions and different credibility (construction quality as a random factor) was compared. The reliability of the LCC analysis approach was verified based on the uncertainty analysis method. Based on an expert-scoring approach, a user cost weight was obtained to ensure it is considered reasonably in the LCC analysis. Compared with the cumulative traffic volume, the cumulative equivalent single axle loads (CESAL) have a closer relationship with the LCC. The GA system has better LCC when the CESAL is less, while the EA system is just the opposite. The breaking point of CESAL for the LCC of the EA system and the GA system is 15 million times. The LCC analysis of SBDPS should consider the influence of random factors such as construction quality. The comprehensive LCC analysis approach in this paper can provide suggestions for bridge-management departments to make a reasonable selection on SBDPS.

scholarly journals Langmuir Adsorption Kinetics in Liquid Media: Interface Reaction Model

ACS Omega ◽  
2021 ◽  
Author(s):  
Md Akhtarul Islam ◽  
Myisha Ahmed Chowdhury ◽  
Md. Salatul Islam Mozumder ◽  
Md. Tamez Uddin
Keyword(s):  
Adsorption Kinetics ◽  
Interface Reaction ◽  
Reaction Model ◽  
Liquid Media ◽  
Langmuir Adsorption

scholarly journals A Multiobjective Decision-Making Model for Risk-Based Maintenance Scheduling of Railway Earthworks

2021 ◽  
Vol 11 (3) ◽  
pp. 965
Author(s):  
Irina Stipanovic ◽  
Zaharah Allah Bukhsh ◽  
Cormac Reale ◽  
Kenneth Gavin
Keyword(s):  
Utility Theory ◽  
Structural Reliability ◽  
Structural Performance ◽  
Maintenance Planning ◽  
Relative Importance ◽  
User Cost ◽  
Multi Attribute Utility Theory ◽  
Network Maintenance ◽  
Decision Making Model ◽  
Do So

Aged earthworks constitute a major proportion of European rail infrastructures, the replacement and remediation of which poses a serious problem. Considering the scale of the networks involved, it is infeasible both in terms of track downtime and money to replace all of these assets. It is, therefore, imperative to develop a rational means of managing slope infrastructure to determine the best use of available resources and plan maintenance in order of criticality. To do so, it is necessary to not just consider the structural performance of the asset but also to consider the safety and security of its users, the socioeconomic impact of remediation/failure and the relative importance of the asset to the network. This paper addresses this by looking at maintenance planning on a network level using multi-attribute utility theory (MAUT). MAUT is a methodology that allows one to balance the priorities of different objectives in a harmonious fashion allowing for a holistic means of ranking assets and, subsequently, a rational means of investing in maintenance. In this situation, three different attributes are considered when examining the utility of different maintenance options, namely availability (the user cost), economy (the financial implications) and structural reliability (the structural performance and subsequent safety of the structure). The main impact of this paper is to showcase that network maintenance planning can be carried out proactively in a manner that is balanced against the needs of the organization.

scholarly journals Isothermal Kinetic Analysis of the Thermal Decomposition of Wood Chips from an Apple Tree

Processes ◽  
2021 ◽  
Vol 9 (2) ◽  
pp. 195
Author(s):  
Ivan Vitázek ◽  
Martin Šotnar ◽  
Stella Hrehová ◽  
Kristína Darnadyová ◽  
Jan Mareček
Keyword(s):  
Thermal Decomposition ◽  
Apple Tree ◽  
Combustion Process ◽  
Reaction Model ◽  
Wood Chips ◽  
Small Scale ◽  
Exponential Factor ◽  
Air Atmosphere ◽  
First Order Chemical Reaction ◽  
Isothermal Kinetic

The thermal decomposition of wood chips from an apple tree is studied in a static air atmosphere under isothermal conditions. Based on the thermogravimetric analysis, the values of the apparent activation energy and pre-exponential factor are 34 ± 3 kJ mol−1 and 391 ± 2 min−1, respectively. These results have also shown that this process can be described by the rate of the first-order chemical reaction. This reaction model is valid only for a temperature range of 250–290 °C, mainly due to the lignin decomposition. The obtained results are used for kinetic prediction, which is compared with the measurement. The results show that the reaction is slower at higher values of degree of conversion, which is caused by the influence of the experimental condition. Nevertheless, the obtained kinetic parameters could be used for the optimization of the combustion process of wood chips in small-scale biomass boilers.

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