Laboratory Studies For Design of a Foam Pilot For Reducing Gas Channeling From Gas Cap in Production Well in Messoyakhskoye Field

2021 ◽  
Author(s):  
Emil Rinatovich Saifullin ◽  
Chengdong Yuan ◽  
Maiia Vladimirovna Zvada ◽  
Mikhail Alekseevich Varfolomeev ◽  
Shinar Kayratovna Shanbosinova ◽  
...  

Abstract Messoyakhskoye field, operated by Gazprom Neft, is currently experiencing gas channeling from gas cap in production wells because of strong heterogeneity. Foam for a long has been considered as a good candidate for gas blocking, (Svorstol I. et al., 1996), (Hanssen, J. E., & Dalland, M. 1994), (Aarra, M. G. et al., 1996). However, foam injection for gas blocking in injection well is different from that in production well, where it is necessary to selectively and long-term impact on gas-saturated highly permeable areas without affecting the phase permeability of oil in the reservoir. This paper provides detailed laboratory studies that show how to determine suitable foam systems for gas blocking in production well. For gas blocking in production well, a long half-life time is required to sustain stable foam because a continuous shear of surfactant solution/gas can't be achieved like in injection well. Therefore, reinforced foam by polymer is chosen. Four polymer stabilizers and five foam agents were evaluated using bulk test to determine foaming ability, foam stability, and effect of oil by comparing foam rate and half-life time to determine the suitable foam system. Furthermore, filtration experiments were conducted at reservoir conditions to determine the optimal injection mode by evaluating apparent viscosity, breakthrough pressure gradient, resistance factor, and residual resistance factor. Polymer can significantly improve half-life time (increase foam stability), and the higher the polymer concentration, the longer the half-life time. But simultaneously, a high polymer concentration will increase the initial viscosity of solution, which not only decreases the foam rate, but also increases difficulties in injection. Therefore, an optimal polymer concentration of about 0.15-0.2 wt% is determined considering all these influences. Filtration experiments showed that the apparent viscosity in core first increased and then deceased with foam quality (the ratio of gas volume to foam volume (gas + liquid). The optimal injection mode is co-injection of surfactant/polymer solution and gas to in-situ generate foam at the optimal foam quality of about 0.65. Filtration experiments on the different permeability cores showed that gas-blocking ability of polymer reinforced foam is better in high-permeability cores, which is beneficial for blocking high permeability zone. It should be also noted that under a certain ratio of oil to foam solution (about lower than 1 to 1), the presence of oil slowly decreased foam rate with increasing oil volume, but significantly increased half -life time, which is favorable for foam treatment in production well. This work highlights the difference between foam injection for gas blocking in production well and injection well, and emphasizes the use of polymer reinforced foam. Moreover, this work shows systematic experimental methods for choosing suitable foam systems for gas blocking in production well considering different factors, which provides a guide regarding what kinds of foaming agents and polymer stabilizers should be used and how to evaluate them for designing a pilot application.

2021 ◽  
Vol 34 (3) ◽  
pp. 128-134
Author(s):  
Taoping Bai ◽  
Wentao Jiang ◽  
Lin Liang ◽  
Yalan Li ◽  
Yubo Fan

<b><i>Objectives:</i></b> The objective of our study was to develop an optical method that instantly evaluates the stability of sclerosing foam, which would enable early predictions of the clinical performance of the foam and reduce the occurrence of clinical side effects. <b><i>Methods:</i></b> Based on the principle of light scattering, we developed a method to optically test foam stability and verified it experimentally using sodium morrhuate (2 mL; 0.05 g/mL) and carbon dioxide. A self-made foam preparation instrument was used to achieve a preparation speed of 275 mm/s. The liquid-gas ratios were considered as 1:3, 1:4, and 1:5. Curves of illuminance with respect to the drainage rate and decay time were obtained. By fitting the curve, the relationship between foam half-life time (FHT) and foam decay was obtained. Thus, foam stability was evaluated using the initial illuminance value; the foam transfer time was approximately 3 s. <b><i>Results:</i></b> The experimental FHT varies between 205 and 232 s. Illuminance is exponentially related to drainage rate and linearly related with time. FHT can be expressed by the initial illuminance and illuminance curve fitting coefficients. The half-life of the foam decreases as the initial illuminance value increases, for the same sclerosing drug. The suitability of foam stability is determined by the position of the initial value in the chart. <b><i>Conclusion:</i></b> Optical methods are feasible for evaluating foam stability over a short period of time. Clinically predicting the stability of freshly prepared foam can reduce number of incidences of further complications. This will promote the development of foam sclerotherapy and provide a basic understanding of the internal mechanical properties of foam.


2021 ◽  
Author(s):  
Abeer Alarawi ◽  
Abdullah Al Moajil ◽  
Abdullah Alrustum ◽  
Waddah AlMahri

Abstract Foamed fluids are commonly used in acidizing and fracturing applications to minimize formation damage, improve fluid recovery, and as diverting-agents. However, significant concerns with foamed fluids are poor stability and low viscosity. The study objectives include evaluating the commercially available surfactants’ foamability and stability when mixed with and without nanoparticles. The prepared foamed fluid characteristics such as rheology, morphology, stability, and proppant suspension were evaluated. Foam loop rheometer experiments were conducted at 1500 psi and 70% N2 quality to assess foam-stability and rheological properties. Foam decaying time was detected by half-life-time measurements (measuring foam-height as a function of time). Turbiscan was used to study the proppant settling using backscattering light. A high-resolution optical microscope was used to observe foam morphology and stability. The surfactant C-nanoparticles-based foamed fluid demonstrated stable foam with a high viscosity value that reached &gt;110 cP at 100 S-1 77 °F and 70% N2 quality. Compared to the surfactant-based foamed fluid, combining the surfactant with nanoparticles as a foam-stabilizer increased the foam-half-life-time by nearly 35-75%. Foam bubbles size of surfactants A and B (with/without NPs) were large with an irregular shape and tended to rupture intermittently within 50 and 8 minutes, respectively. Bubbles average size of surfactant C (with/without NPs) based foams was small, and the count was higher than the foams of surfactants A and B. surfactant C (with/without NPs) based foams demonstrated bubbles with a spherical shape. Turbiscan stability index values of several surfactants-nanoparticles-based foamed fluids were almost comparable at 77 and 122 °F. Lastly, the foam fluids’ proppant settling velocity prepared with nanoparticles was lower than pure surfactant-based foams.


1983 ◽  
Vol 49 (02) ◽  
pp. 109-115 ◽  
Author(s):  
M Hoylaerts ◽  
E Holmer ◽  
M de Mol ◽  
D Collen

SummaryTwo high affinity heparin fragments (A/r 4,300 and M, 3,200) were covalently coupled to antithrombin III (J. Biol. Chem. 1982; 257: 3401-3408) with an apparent 1:1 stoichiometry and a 30-35% yield.The purified covalent complexes inhibited factor Xa with second order rate constants very similar to those obtained for antithrombin III saturated with these heparin fragments and to that obtained for the covalent complex between antithrombin III and native high affinity heparin.The disappearance rates from plasma in rabbits of both low molecular weight heparin fragments and their complexes could adequately be represented by two-compartment mammillary models. The plasma half-life (t'/j) of both low Afr-heparin fragments was approximately 2.4 hr. Covalent coupling of the fragments to antithrombin III increased this half-life about 3.5 fold (t1/2 ≃ 7.7 hr), approaching that of free antithrombin III (t1/2 ≃ 11 ± 0.4 hr) and resulting in a 30fold longer life time of factor Xa inhibitory activity in plasma as compared to that of free intact heparin (t1/2 ≃ 0.25 ± 0.04 hr).


2011 ◽  
Vol 2 (1) ◽  
pp. 13-17
Author(s):  
I. David ◽  
M. Visescu

Abstract Geothermal energy source is the heat from the Earth, which ranges from the shallow ground (the upper 100 m of the Earth) to the hot water and hot rock which is a few thousand meters beneath the Earth's surface. In both cases the so-called open systems for geothermal energy resource exploitation consist of a groundwater production well to supply heat energy and an injection well to return the cooled water, from the heat pump after the thermal energy transfer, in the underground. In the paper an analytical method for a rapid estimation of the ground water flow direction effect on the coupled production well and injection well system will be proposed. The method will be illustrated with solutions and images for representative flow directions respect to the axis of the production/injection well system.


2017 ◽  
pp. 63-67
Author(s):  
L. A. Vaganov ◽  
A. Yu. Sencov ◽  
A. A. Ankudinov ◽  
N. S. Polyakova

The article presents a description of the settlement method of necessary injection rates calculation, which is depended on the injected water migration into the surrounding wells and their mutual location. On the basis of the settlement method the targeted program of geological and technical measures for regulating the work of the injection well stock was created and implemented by the example of the BV7 formation of the Uzhno-Vyintoiskoe oil field.


2020 ◽  
Vol 27 ◽  
Author(s):  
Shwethashree Malla ◽  
Sathyanarayana N. Gummadi

Background: Physical parameters like pH and temperature play a major role in the design of an industrial enzymatic process. Enzyme stability and activity are greatly influenced by these parameters; hence optimization and control of these parameters becomes a key point in determining the economic feasibility of the process. Objective: This study was taken up with the objective to optimize physical parameters for maximum stability and activity of xylose reductase from D. nepalensis NCYC 3413 through separate and simultaneous optimization studies and comparison thereof. Method: Effects of pH and temperature on the activity and stability of xylose reductase from Debaryomyces nepalensis NCYC 3413 were investigated by enzyme assays and independent variables were optimised using surface response methodology. Enzyme activity and stability were optimised separately and concurrently to decipher the appropriate conditions. Results: Optimized conditions of pH and temperature for xylose reductase activity were determined to be 7.1 and 27 ℃ respectively, with predicted responses of specific activity (72.3 U/mg) and half-life time (566 min). The experimental values (specific activity 50.2 U/mg, half-life time 818 min) were on par with predicted values indicating the significance of the model. Conclusion: Simultaneous optimization of xylose reductase activity and stability using statistical methods is effective as compared to optimisation of the parameters separately.


1997 ◽  
Vol 62 (6) ◽  
pp. 855-865 ◽  
Author(s):  
Katarína Erentová ◽  
Vladimír Adamčík ◽  
Andrej Staško ◽  
Oskar Nuyken ◽  
Arming Lang ◽  
...  

The cathodically and photochemically induced decomposition of thioazo compounds XC6H4-N2-S-C6H4CH3 and their polymers with X = NO2, COOH, and SO3H were investigated. The formation of carbon-centered XC6H4. and sulfur-centered .S-C6H4Y radicals was confirmed using spin-trap technique. These reactive radicals either abstract hydrogen from CH3CN solvent molecule forming .CH2CN radical or they recombine to cage products XC6H4-S-C6H4CH3 eliminating N2. The decomposition rate of the investigated thioazo compounds is characterized by a formal half-life time of 5 to 10 s.


2014 ◽  
Vol 44 (4) ◽  
pp. 411-418 ◽  
Author(s):  
Renato Alves Teixeira ◽  
Tatiana Gazel Soares ◽  
Antonio Rodrigues Fernandes ◽  
Anderson Martins de Souza Braz

Studies to select one or more species of coverage plants adapted to Amazonian soil and climate conditions of the Amazon are a promising strategy for the improvement of environmental quality, establishing no-till agricultural systems, and thereby reducing the impacts of monoculture farming. The aim of this study was to assess the persistence time, half-life time, macronutrient content and accumulation, and C:N ratio of straw coverage in a Ultisol in northeastern Pará. Experimental design was randomized blocks with five treatments and five replicates. Plants were harvested after 105 days, growth and biomass production was quantified. After 84 days, soil coverage was 97, 85, 52, 50, and 15% for signalgrass (Brachiaria brizantha) (syn. Urochloa), dense crowngrass (Panicum purpurascens), jack bean (Canavalia ensiformes), pearl millet (Pennisetum americanum) and sunn hemp (Crotalaria juncea,), respectively. Signalgrass yielded the greatest dry matter production (9,696 kg ha-1). It also had high C:N ratio (38.4), long half-life (86.5 days) and a high persistence in the field. Jack bean also showed high dry matter production (8,950 kg ha-1), but it had low C:N ratio (17.4) and lower half-life time (39 days) than the grasses. These attributes indicate that signalgrass and jack bean have a high potential for use as cover plants in no-till agricultural systems in the State of Pará.


2020 ◽  
Vol 42 (4) ◽  
pp. 495-495
Author(s):  
Weimin Xie Weimin Xie ◽  
Dongsheng He Dongsheng He ◽  
Shuang Liu Shuang Liu ◽  
Fei Chen Fei Chen ◽  
Hongqiang Li Hongqiang Li

Over-stabilized foam has always been a problem that plagues the dodecylamine (DDA) flotation system. In this study, a new device, “automatic foam analyzer”, was successfully used to characterize the behavior of foam in DDA solution. The effects of pH and DDA dosage on the foam properties were investigated from four aspects: bubble diffusion capacity, Bikerman coefficient, half-life period and solution conductivity, and the mechanism of pH and DDA concentration on foam properties was analyzed by solution chemistry and surface tension of DDA, then the change process of foam structure was deduced. The results showed that the foaming property and stability of DDA bubbles were the best at pH=8. Simultaneously, with the increase of DDA dosage, the foaming property of bubbles was enhanced, the half-life was prolonged, and the foam stability was also improved.


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