Bio-Inspired Modulation of Tris(triazolyl)borate's Electronic Properties Resulting in Enhanced Reactivity of Cu(I/II) and Other Transition Metal Complexes

2021 ◽  
Author(s):  
Natalie Anne Dixon
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes

Synthesis and Electronic Properties of Transition Metal Complexes Containing Sulfonamidoquinoline Ligands

Polyhedron ◽  
2021 ◽  
pp. 115269
Author(s):  
Matthew T. Gole ◽  
Patrick Pauls ◽  
Sage F. Hartlaub ◽  
Chip Nataro ◽  
Lauren M. Rossiter ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes

scholarly journals Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes

2021 ◽  
Vol 60 (6) ◽  
pp. 4015-4025
Author(s):  
Alina A. Grineva ◽  
Oleg A. Filippov ◽  
Yves Canac ◽  
Jean-Baptiste Sortais ◽  
Sergei E. Nefedov ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes

Transition Metal Complexes of Diazenes, XVII [1]. Reactions of 1,2-Diazetines and 1,2-Diazetine-N-oxides with Iron Carbonyls

1982 ◽  
Vol 37 (4) ◽  
pp. 463-467 ◽  
Author(s):  
A. Albini ◽  
H. Kisch ◽  
C. Krüger ◽  
An-Pei Chiang
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Lone Pair ◽  
X Ray ◽  
Iron Carbonyls

Enneacarbonyldiiron reacts with 3,3,4,4-tetramethyl-1,2-diazetine (L) or its mono-N-oxide (L′) to form complexes (L)Fe(CO)4 (3), (L)Fe2(CO)7 (4), (L)Fe2(CO)6 (5), or (L′)Fe(CO)4 (6), and small amounts of deoxygenated 4 and 5, respectively. Formation and stability of the complexes is compared with those of ligands with smaller and larger ring sizes and discussed in terms of the electronic properties of the ligand lone-pair Orbitals. The molecular structure of 4 is established by X-ray analysis.

Chemical Trends in Electronic Properties of Gold-3D Transition Metal Impurity Pairs in Silicon

1997 ◽  
Vol 469 ◽  
Author(s):  
J. F. Justo ◽  
L. V. C. Assali
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Metal Impurity ◽  
Trigonal Symmetry ◽  
Transition Metal Impurity ◽  
Theoretical Investigations ◽  
Stable Pairs ◽  
Chemical Trends

ABSTRACTWe report theoretical investigations of the chemical trends in the electronic properties of substitutional gold-interstitial transition-metal complexes in silicon. The results show that the stable pairs in trigonal symmetry are formed by a covalent mechanism which includes, besides Au and TM impurities, also the Si neighbors, rather than being derived from interactions between two electrostatically bound point charges.

scholarly journals Ddpd as Expanded Terpyridine: Dramatic Effects of Symmetry and Electronic Properties in First Row Transition Metal Complexes

Inorganics ◽  
2018 ◽  
Vol 6 (3) ◽  
pp. 86 ◽  
Author(s):  
Christoph Förster ◽  
Matthias Dorn ◽  
Thomas Reuter ◽  
Sven Otto ◽  
Güllü Davarci ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Coordination Chemistry ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Redox Chemistry

The 2,2′:6′:2″-terpyridine ligand has literally shaped the coordination chemistry of transition metal complexes in a plethora of fields. Expansion of the ligand bite by amine functionalities between the pyridine units in the tridentate N,N’-dimethyl-N,N’-dipyridine-2-yl-pyridine-2,6-diamine ligand (ddpd) modifies the properties of corresponding transition metal complexes, comprising redox chemistry, molecular dynamics, magnetism and luminescence. The origins of these differences between ddpd and tpy complexes will be elucidated and comprehensively summarized with respect to first row transition metal complexes with d2–d10 electron configurations. Emerging applications of these ddpd complexes complementary to those of the well-known terpyridine ligand will be highlighted.

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