Electronic properties of transition-metal complexes determined from electroabsorption (Stark) spectroscopy. 2. Mononuclear complexes of ruthenium(II)

1991 ◽  
Vol 95 (24) ◽  
pp. 9773-9781 ◽  
Author(s):  
J. R. Reimers ◽  
N. S. Hush
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Stark Spectroscopy ◽  
Mononuclear Complexes

Synthesis and Electronic Properties of Transition Metal Complexes Containing Sulfonamidoquinoline Ligands

Polyhedron ◽  
2021 ◽  
pp. 115269
Author(s):  
Matthew T. Gole ◽  
Patrick Pauls ◽  
Sage F. Hartlaub ◽  
Chip Nataro ◽  
Lauren M. Rossiter ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes

scholarly journals Experimental and Theoretical Insights into the Electronic Properties of Anionic N-Heterocyclic Dicarbenes through the Rational Synthesis of Their Transition Metal Complexes

2021 ◽  
Vol 60 (6) ◽  
pp. 4015-4025
Author(s):  
Alina A. Grineva ◽  
Oleg A. Filippov ◽  
Yves Canac ◽  
Jean-Baptiste Sortais ◽  
Sergei E. Nefedov ◽  
...  
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes

Transition Metal Complexes of Diazenes, XVII [1]. Reactions of 1,2-Diazetines and 1,2-Diazetine-N-oxides with Iron Carbonyls

1982 ◽  
Vol 37 (4) ◽  
pp. 463-467 ◽  
Author(s):  
A. Albini ◽  
H. Kisch ◽  
C. Krüger ◽  
An-Pei Chiang
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Lone Pair ◽  
X Ray ◽  
Iron Carbonyls

Enneacarbonyldiiron reacts with 3,3,4,4-tetramethyl-1,2-diazetine (L) or its mono-N-oxide (L′) to form complexes (L)Fe(CO)4 (3), (L)Fe2(CO)7 (4), (L)Fe2(CO)6 (5), or (L′)Fe(CO)4 (6), and small amounts of deoxygenated 4 and 5, respectively. Formation and stability of the complexes is compared with those of ligands with smaller and larger ring sizes and discussed in terms of the electronic properties of the ligand lone-pair Orbitals. The molecular structure of 4 is established by X-ray analysis.

Structural analysis of the coordination of dinitrogen to transition metal complexes

2015 ◽  
Vol 71 (3) ◽  
pp. 369-386 ◽  
Author(s):  
Benjamin Peigné ◽  
Gabriel Aullón
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Electronic Configuration ◽  
Nitrogen Molecule ◽  
Geometrical Parameters ◽  
Binuclear Complexes ◽  
Mononuclear Complexes ◽  
Structural Database ◽  
Metal Properties

Transition-metal complexes show a wide variety of coordination modes for the nitrogen molecule. A structural database study has been undertaken for dinitrogen complexes, and geometrical parameters around theLnM—N2unit are retrieved from the Cambridge Structural Database. These data were classified in families of compounds, according to metal properties, to determine the degree of lengthening for the dinitrogen bonding. The importance of the nature of the metal center, such as coordination number and electronic configuration, is reported. Our study reveals poor activation by coordination of dinitrogen in mononuclear complexes, always havingend-oncoordination. However, partial weakening of nitrogen–nitrogen bonding is found forend-onbinuclear complexes, whereasside-oncomplexes can be completely activated.

Chemical Trends in Electronic Properties of Gold-3D Transition Metal Impurity Pairs in Silicon

1997 ◽  
Vol 469 ◽  
Author(s):  
J. F. Justo ◽  
L. V. C. Assali
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Electronic Properties ◽  
Transition Metal Complexes ◽  
Metal Impurity ◽  
Trigonal Symmetry ◽  
Transition Metal Impurity ◽  
Theoretical Investigations ◽  
Stable Pairs ◽  
Chemical Trends

ABSTRACTWe report theoretical investigations of the chemical trends in the electronic properties of substitutional gold-interstitial transition-metal complexes in silicon. The results show that the stable pairs in trigonal symmetry are formed by a covalent mechanism which includes, besides Au and TM impurities, also the Si neighbors, rather than being derived from interactions between two electrostatically bound point charges.

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