An Examination of Mass Transport Paths in Conventional and Highly Textured AL-CU Interconnect Lines

1997 ◽  
Vol 472 ◽  
Author(s):  
R. J. Gleixner ◽  
H. Kanekof ◽  
M. Matsuot ◽  
H. Toyodat ◽  
W. D. Nix

ABSTRACTThe electromigration lifetime of aluminum interconnect lines shows a strong dependence on the quality of the texture in the metal. This observation has been explained in terms of a decreased diffusivity along the grain boundaries, generally the dominant path for diffusion and void growth. As the texture in the metal is strengthened, atomic order along the grain boundaries is increased, and diffusion is suppressed.In this paper, we examine passivated A1–0.5wt%Cu interconnect lines having either TaAl underlayers or conventional Ti/TiN underlayers. Rocking curve measurements confirm that Al deposited on TaAl has a very strong (111) texture (FWHM ∼ 0.6°) compared to Al on Ti/TiN (FWHM ∼ 6°). Interconnect lines of both types were electrically stressed at 225°C and 250°C for 20 hours at a current density of 3 MA/cm2. The lines were then stripped of passivation, and the void numbers, sizes, and morphologies were determined.Analysis of the void data gave a surprising result: the void volume in the highly-textured Al was greater than in the conventional Al. However, voids in the conventional Al were observed to follow grain boundaries across the width and sever the line, while such destructive void growth was not observed in the highly-textured Al. Instead, voids grew either with a faceted shape or along the line edge, never extending across the line width. Modeling electromigration in the surrounding microstructures shows that void locations in the highly-textured lines are often independent of the surrounding grain boundaries. In this case, the line sidewalls appear to be significant mass transport paths. Since these paths do not cross the line width, voids growth across the line is difficult. This resistance to fatal damage makes highly textured aluminum a promising interconnect material.

1997 ◽  
Vol 473 ◽  
Author(s):  
R. J. Gleixner ◽  
H. Kanekot ◽  
M. Matsuo ◽  
H. Toyoda ◽  
W. D. Nix

ABSTRACTThe electromigration lifetime of aluminum interconnect lines shows a strong dependence on the quality of the texture in the metal. This observation has been explained in terms of a decreased diffusivity along the grain boundaries, generally the dominant path for diffusion and void growth. As the texture in the metal is strengthened, atomic order along the grain boundaries is increased, and diffusion is suppressed.In this paper, we examine passivated Al-0.5wt%Cu interconnect lines having either Ta Al underlayers or conventional Ti/TiN underlayers. Rocking curve measurements confirm that Al deposited on TaAl has a very strong (111) texture (FWHM ∼ 0.6°) compared to Al on Ti/TiN (FWHM ∼ 6°). Interconnect lines of both types were electrically stressed at 225°C and 250°C for 20 hours at a current density of 3 MA/cm2. The lines were then stripped of passivation, and the void numbers, sizes, and morphologies were determined.Analysis of the void data gave a surprising result: the void volume in the highly-textured Al was greater than in the conventional Al. However, voids in the conventional Al were observed to follow grain boundaries across the width and sever the line, while such destructive void growth was not observed in the highly-textured Al. Instead, voids grew either with a faceted shape or along the line edge, never extending across the line width. Modeling electromigration in the surrounding microstructures shows that void locations in the highly-textured lines are often independent of the surrounding grain boundaries. In this case, the line sidewalls appear to be significant mass transport paths. Since these paths do not cross the line width, voids growth across the line is difficult. This resistance to fatal damage makes highly textured aluminum a promising interconnect material.


2015 ◽  
Vol 137 (3) ◽  
Author(s):  
Naokazu Murata ◽  
Naoki Saito ◽  
Kinji Tamakawa ◽  
Ken Suzuki ◽  
Hideo Miura

Effects of crystallographic quality of grain boundaries on mechanical and electrical properties were investigated experimentally. A novel method using two parameters of image quality (IQ) and confidence index (CI) values based on electron back-scattering diffraction (EBSD) analysis was proposed in order to evaluate crystallographic quality of grain boundaries. IQ value was defined as an index to evaluate crystallinity in region irradiated with electron beam. CI value determined existence of grain boundaries in the region. It was found that brittle intergranular fatigue fracture occurred in the film without annealing and the film annealed at 200 °C because network of grain boundaries with low crystallinity remained in these films. On the other hand, the film annealed at 400 °C caused only ductile transgranular fatigue fracture because grain boundaries with low crystallinity almost disappeared. From results of measurement of electrical properties, electrical resistivity of copper interconnection annealed at 400 °C with high crystallinity (2.09 × 10−8 Ωm) was low and electron migration (EM) resistance was high compared with an copper interconnection without annealing with low crystallinity (3.33 × 10−8 Ωm). It was clarified that the interconnection with high crystallinity had superior electrical properties. Thus, it was clarified that the crystallographic quality of grain boundaries has a strong correlation of mechanical and electrical reliability.


2004 ◽  
Vol 812 ◽  
Author(s):  
Ehrenfried Zschech ◽  
Moritz A. Meyer ◽  
Eckhard Langer

AbstractIn-situ SEM electromigration studies were performed at fully embedded via/line interconnect structures to visualize the time-dependent void evolution in inlaid copper interconnects. Void formation, growth and movement, and consequently interconnect degradation, depend on both interface bonding and copper microstructure. Two phases are distinguished for the electromigration-induced interconnect degradation process: In the first phase, agglomerations of vacancies and voids are formed at interfaces and grain boundaries, and voids move along weak interfaces. In the second phase of the degradation process, they merge into a larger void which subsequently grows into the via and eventually causes the interconnect failure. Void movement along the copper line and void growth in the via are discontinuous processes, whereas their step-like behavior is caused by the copper microstructure. Directed mass transport along inner surfaces depends strongly on the crystallographic orientation of the copper grains. Electromigration lifetime can be drastically increased by changing the copper/capping layer interface. Both an additional CoWP coating and a local copper alloying with aluminum increase the bonding strength of the top interface of the copper interconnect line, and consequently, electromigration-induced mass transport and degradation processes are reduced significantly.


1999 ◽  
Vol 5 (S2) ◽  
pp. 98-99
Author(s):  
C. Barry Carter ◽  
N. Ravishankar ◽  
Carsten Korte ◽  
M.P. Mallamaci

The interaction of a liquid with a solid substrate has been the subject of intense research since the early 1800s. The subject is relevant and very important even today from a basic science as well as technological standpoint. Liquid-phase-sintered oxide ceramics often contain a siliceous glassy layer in the grain boundaries which affect the properties of the ceramic. The wetting of the grain boundaries by the liquid has a strong dependence on the crystallography. While some boundaries are preferably wet, other special boundaries appear to be completely ‘dry’. The presence of the liquid film also affects the faceting behavior of the boundary plane. While several studies have been carried out on these intergranular glass films, many of the basic issues still remain unclear. The development of modern microscopy techniques facilitate the characterization of structure and chemistry at a high spatial resolution. This paper deals with the microstructural examination of two of the important issues involved with these intergranular films, i.e., faceting of grain boundaries in the presence of a glassy phase and the behavior of interfaces between two glassy phases of different compositions.


2000 ◽  
Vol 6 (S2) ◽  
pp. 386-387
Author(s):  
N. Ravishankar ◽  
M.T. Johnson ◽  
C. Barry Carter

The migration of grain boundaries in polycrystalline materials can occur under a variety of driving forces. Grain growth in a single-phase material and Ostwald ripening of a second phase are two common processes involving boundary migration. The mass transport in each of these cases can be related to a chemical potential difference across the grains; due to curvature in the former case and due to a difference in the chemistry in the latter case. The mass transport across grains controls the densification process during sintering. In the case of liquid-phase sintering (LPS), a liquid film may be present at the grain boundaries which results in an enhanced mass transport between grains leading to faster densification. Hence, in LPS, it is important to understand mass transport across and along a boundary containing a liquid film. The use of bicrystals and tricrystals with glass layers in the boundary can provide a controlled geometry by which to study this phenomenon.


2018 ◽  
Vol 245 ◽  
pp. 06014 ◽  
Author(s):  
Sergey Andreev ◽  
Vladimir Zaginaylov ◽  
Andris Matveev

A significant part of the water resources used in agricultural production comes for irrigation. Due to the strong dependence of soil moisture on weather factors, the irrigation process must be carefully managed. To date, irrigation management is mainly carried out either as a function of soil moisture or according to a predetermined program. The article shows that both methods of management are imperfect since they can lead to a violation of agrotechnical requirements and waste of water. In order to improve the quality of irrigation and eliminate overspending of water resources, it was proposed to manage the water in a combined way. In this case, the formation of the control action occurs according to the results of the comparison of the controlled variable and disturbing influences with the reference values. The controlled value is the soil moisture, and as disturbing influences are considered the temperature and humidity of the air, atmospheric pressure, wind speed, precipitation. In addition, the proposed irrigation management method takes into account the forecast of the synoptic services on precipitation, their intensity and duration. To obtain information on the controlled value, as well as on disturbing influences, appropriate measuring devices are used, and information on the prediction of precipitation is delivered from a specialized server via the Internet. Before starting to use the control method, the agrotechnical requirements, the type, age and vegetation period of the plants are determined and set. The inclusion of irrigation equipment is carried out in accordance with the program and shut down - depending on the magnitude of the control signal.


Author(s):  
Naokazu Murata ◽  
Naoki Saito ◽  
Kinji Tamakawa ◽  
Ken Suzuki ◽  
Hideo Miura

Both mechanical and electronic properties of electroplated copper films used for interconnections were investigated experimentally considering the change of their micro texture caused by heat treatment. The fracture strain of the film annealed at 400°C increased from about 3% to 15% and their yield stress decreased from about 270 MPa to 90 MPa. In addition, it was found that two different fatigue fracture modes appeared in the film. One was a typical ductile fracture mode and the other was brittle one. When the brittle fracture occurred, a crack propagated along weak or porous grain boundaries which were formed during electroplating. The brittle fracture mode disappeared after the annealing at 300°C. These results clearly indicated that the mechanical properties of electroplated copper thin films vary drastically depending on their micro texture. The electrical reliability of the electroplated copper yjin film interconnections was also investigated. The interconnections used for electromigration tests were made using by a damascene process. An abrupt fracture mode due to local fusion appeared in the as-electroplated interconnections. Since the fracture rate increased almost linearly with the square of the applied current density, this fracture mode was dominated by local Joule heating. It seemed that the local current concentration occurred around the porous grain boundaries. The life of the interconnections was improved drastically after the annealing at 400°C. This was because of the increase of the average grain size and the improvement of the quality of grain boundaries in the annealed interconnections. However, the stress-induced migration occurred in the interconnections annealed at 400°C. This was because of the high tensile residual stress caused by the constraint of the densification of the films during annealing by the surrounding oxide film. Therefore, it is very important to control the crystallographic quality of electroplated copper films for improving the reliability of thin film interconnections. The quality of the grain boundaries can be evaluated by applying an EBSD (Electron Back Scatter Diffraction) analysis. New two experimentally determined parameters are proposed for evaluating the quality of grain boundaries quantitatively. It was confirmed that the crystallographic quality of grain boundaries can be evaluated quantitatively by using the two parameters, and it is possible to estimate both the strength and reliability of the interconnections.


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