A Two-Step, Lightly Nitrided Gate Oxidation Process For Sub-0.5 μm Cmos Technology

1996 ◽  
Vol 428 ◽  
Author(s):  
P. K. Roy ◽  
Y. Ma ◽  
M. T. Flemming
Keyword(s):  
Oxidation Process ◽  
Defect Density ◽  
Charge Trapping ◽  
Cmos Technology ◽  
Simple Extension ◽  
Gate Oxides ◽  
Nitrogen Incorporation ◽  
Oxide Characteristics

AbstractThis work describes a two-step, lightly nitrided gate oxidation process for sub-0.5 jtm CMOS technology. This process is a simple extension of conventional oxidation using an in-situ N2O post oxidation anneal for nitrogen incorporation. Light nitrogen incorporation (∼3%) near the Si/SiO2 interface has improved oxide characteristics such as defect density (Do.), wear-out (Nbd), breakdown (Vbd) and tunneling (VFN) without altering its charge trapping behavior. Impacts of nitridation are more significant for thinner (<65Å) gate oxides (GOX).

High Quality Ultrathin Gate Dielectrics Prepared by In-Situ RTP

1995 ◽  
Vol 387 ◽  
Author(s):  
L. K. Han ◽  
M. Bhat ◽  
J. Yan ◽  
D. Wristers ◽  
D. L. Kwong
Keyword(s):  
Gate Dielectric ◽  
Defect Density ◽  
Gate Dielectrics ◽  
Charge Trapping ◽  
Interface State ◽  
High Quality ◽  
Hot Carrier ◽  
Thermal Oxide ◽  
State Generation

AbstractThis paper reports on the formation of high quality ultrathin oxynitride gate dielectric by in-situ rapid thermal multiprocessing. Four such gate dielectrics are discussed here; (i) in-situ NO-annealed SiO2, (ii) N2O- or NO- or O2-grown bottom oxide/RTCVD SiO2/thermal oxide, (iii) N2O-grown bottom oxide/Si3N4/N2O-oxide (ONO) and (iv) N2O-grown bottom oxide/RTCVD SiO2/N2O-oxide. Results show that capacitors with NO-based oxynitride gate dielectrics, stacked oxynitride gate dielectrics with varying quality of bottom oxide (O2/N2O/NO), and the ONO structures show high endurance to interface degradation, low defect-density and high charge-to-breakdown compared to thermal oxide. The N2O-last reoxidation step used in the stacked dielectrics and ONO structures is seen to suppress charge trapping and interface state generation under Fowler-Nordheim injection. The stacked oxynitride gate dielectrics also show excellent MOSFET performance in terms of transconductance and mobility. While the current drivability and mobilities are found to be comparable to thermal oxide for N-channel MOSFET's, the hot-carrier immunity of N-channel MOSFET's with the N2O-oxide/CVD-SiO2/N2O-oxide gate dielectrics is found to be significantly enhanced over that of conventional thermal oxide.

Study of Nitrogen Incorporation in Gate Oxides Using the Resistance to Oxidation Method

1996 ◽  
Vol 429 ◽  
Author(s):  
I. Sagnes ◽  
D. Laviale ◽  
M. Regache ◽  
F. Glowacki ◽  
L. Deutschmann ◽  
...  
Keyword(s):  
Nitrogen Concentration ◽  
Gate Oxide ◽  
Cmos Technology ◽  
Gate Oxides ◽  
Thermal Budget ◽  
Nitrogen Incorporation ◽  
Resistance To Oxidation ◽  
Low Thermal Budget ◽  
Direct Use ◽  
Low Nitrogen

Numerous nitridation processes have been studied to obtain very thin (≤ 6 nm), reproducible and reliable gate oxides. Recent results (1,2,3) have confirmed that i) the NO molecule is the species responsible for the nitrogen incorporation at the SiO2/Si interface and that ii) the direct use of NO gas allows the gate oxide to be nitrided at low thermal budget whilst maintaining the same advantages as those of N2O nitridation. NO nitridation of very thin oxides has so far been inadequately documented in terms of incorporated nitrogen concentration at the SiO2/Si interface. It is of prime importance to control the incorporation of a few nitrogen monolayers at the SiO2/Si interface, particularly for device performances in the 0. 18μm CMOS technology. In the following we present results on the control of low nitrogen concentration in pure NO atmosphere, with particular emphasis on a method based on the re-oxidation of nitrided oxides. This method can be used in a production line thus avoiding the high costs and long characterization times associated with SIMS measurements.

Cathodoluminescence of Catalyst Crystallites

1982 ◽  
Vol 40 ◽  
pp. 664-665
Author(s):  
E.D. Boyes ◽  
P.L. Gai ◽  
D.B. Darby ◽  
C. Warwick
Keyword(s):  
Defect Density ◽  
Chemical Properties ◽  
Operating Conditions ◽  
Semiconductor Materials ◽  
Environmental Cell ◽  
High Resolution Structure ◽  
Commercially Important ◽  
Crystallographic Defects ◽  
Resolution Structure

The extended crystallographic defects introduced into some oxide catalysts under operating conditions may be a consequence and accommodation of the changes produced by the catalytic activity, rather than always being the origin of the reactivity. Operation without such defects has been established for the commercially important tellurium molybdate system. in addition it is clear that the point defect density and the electronic structure can both have a significant influence on the chemical properties and hence on the effectiveness (activity and selectivity) of the material as a catalyst. SEM/probe techniques more commonly applied to semiconductor materials, have been investigated to supplement the information obtained from in-situ environmental cell HVEM, ultra-high resolution structure imaging and more conventional AEM and EPMA chemical microanalysis.

An in situ and ex situ TEM study of the formation of thin cobalt silicide films by molecular beam epitaxy on the silicon (100) surface

1988 ◽  
Vol 46 ◽  
pp. 884-885
Author(s):  
D. Loretto ◽  
J. M. Gibson ◽  
S. M. Yalisove ◽  
R. T. Tung
Keyword(s):  
Molecular Beam Epitaxy ◽  
Molecular Beam ◽  
Defect Density ◽  
High Vacuum ◽  
Ultra High Vacuum ◽  
Ex Situ ◽  
Metal Base ◽  
In Situ Experiments ◽  
Potential Applications

The cobalt disilicide/silicon system has potential applications as a metal-base and as a permeable-base transistor. Although thin, low defect density, films of CoSi2 on Si(111) have been successfully grown, there are reasons to believe that Si(100)/CoSi2 may be better suited to the transmission of electrons at the silicon/silicide interface than Si(111)/CoSi2. A TEM study of the formation of CoSi2 on Si(100) is therefore being conducted. We have previously reported TEM observations on Si(111)/CoSi2 grown both in situ, in an ultra high vacuum (UHV) TEM and ex situ, in a conventional Molecular Beam Epitaxy system.The procedures used for the MBE growth have been described elsewhere. In situ experiments were performed in a JEOL 200CX electron microscope, extensively modified to give a vacuum of better than 10-9 T in the specimen region and the capacity to do in situ sample heating and deposition. Cobalt was deposited onto clean Si(100) samples by thermal evaporation from cobalt-coated Ta filaments.

Ultrathin Gate Dielectric Growth at Reduced Pressure

1994 ◽  
Vol 342 ◽  
Author(s):  
Robert McIntosh ◽  
Carl Galewski ◽  
John Grant
Keyword(s):  
Gate Dielectric ◽  
Charge Trapping ◽  
Cmos Technology ◽  
Interface State ◽  
Constant Current ◽  
Reduced Pressure ◽  
Current Stress ◽  
Ultrathin Oxides ◽  
State Generation ◽  
Improved Characteristics

The Growth of ultrathin oxides in N2O ambient has been a subject of extensive research for submicron CMOS technology. Oxides grown in N2O tend to have a higher charge-to-breakdown, less charge trapping under constant current stress, and less interface state generation under current stress and radiation than conventional oxides grown in oxygen [1,2]. In addition the penetration of boron through N2O oxides is significantly less than through conventional thermal oxides [3]. The improved characteristics of N2O are due to an interfacial pileup of nitrogen atoms [1-3]. Thus the growth of thermal oxides in N2O provides a method for obtaining many of the more favorable aspects of reoxidized-nitrided silicon dioxides, with a much simpler process.

Humic acid removal by gas–liquid interface discharge plasma: performance, mechanism and comparison to ozonation

2019 ◽  
Vol 5 (1) ◽  
pp. 152-160 ◽  
Author(s):  
Yanyan Cui ◽  
Jianwei Yu ◽  
Ming Su ◽  
Zeyu Jia ◽  
Tingting Liu ◽  
...  
Keyword(s):  
Humic Acid ◽  
Advanced Oxidation Process ◽  
Discharge Plasma ◽  
Oxidation Process ◽  
Advanced Oxidation ◽  
Liquid Interface ◽  
Oh Radicals ◽  
Discharge Process

A novel advanced oxidation process (AOP) based on plasma in gas–liquid interface discharge was evaluated for humic acid removal. Much better performance was obtained compared to ozonation. The OH˙ radicals generated by reaction of in situ produced ozone and H2O2 during discharge process were mainly responsible for the removal.

Gate-Prior-To-Isolation Cmos-Technology with Through-The-Gate-Implanted Ultra-Thin Gate Oxides

1999 ◽  
Vol 567 ◽  
Author(s):  
Udo Schwalke ◽  
Christian Gruensfelder ◽  
Alexander Gschwandtner ◽  
Gudrun Innertsberger ◽  
Martin Kerber
Keyword(s):  
Gate Oxide ◽  
Cmos Technology ◽  
Wafer Surface ◽  
Shallow Trench Isolation ◽  
Trench Isolation ◽  
Process Architecture ◽  
Process Complexity ◽  
Mos Gate ◽  
Cluster Tool

ABSTRACTWe have realized direct-tunneling gate oxide (1.6nm) NMOS and PMOS transistors by means of through-the-gate-implantation in a comer parasitics-free shallow-trench-isolation CMOS technology. In order to take full advantage of in-situ cluster-tool processing and to preserve initial wafer-surface quality, the essential part of the MOS gate is fabricated prior to device isolation and through-the-gate-implantation is utilized for well- and channel doping. In addition, a fully-reinforced-gate-oxide-perimeter is provided and trench comer parasitics are eliminated by the advanced process architecture EXTIGATE without increasing process complexity.

Sign in / Sign up

Export Citation Format

Share Document