Front-End Integration Effects on Gate Oxide Quality

1996 ◽  
Vol 428 ◽  
Author(s):  
F. Lin ◽  
S. A. Ajuria ◽  
V. Ilderem ◽  
M. P. Masquelier

AbstractIn this paper, the impact of several front-end processing steps (up to gate oxidation) on gate oxide integrity (GOI) is evaluated. In PBL isolation processing, the use of as-deposited amorphous silicon (a-Si), subsequently annealed during nitride deposition, results in better structural and electrical properties compared to as-deposited polysilicon or as-deposited a-Si with an extra anneal step prior to nitride deposition. Thicker or dual sacrificial schemes exhibit improved gate oxide low voltage breakdown and charge-to-breakdown. Dilute RCA chemistries during pre-gate cleaning produce equal or better surfaces for gate oxidation than the conventional non-dilute RCA with less chemical usage. As gate oxides are scaled below 100Å, lowering gate oxidation temperature is proven to result in far better gate oxide quality than maintaining process temperatures at or above 900°C and diluting oxygen in either argon or nitrogen.

1999 ◽  
Vol 5 (S2) ◽  
pp. 120-121
Author(s):  
D. A. Muller ◽  
T. Sorsch ◽  
S. Moccio ◽  
F. H. Baumann ◽  
K. Evans-Lutterodt ◽  
...  

The transistors planned for commercial use ten years from now in many electronic devices will have gate lengths shorter than 130 atoms, gate oxides thinner than 1.2 nm of SiO2 and clock speeds in excess of 10 GHz. It is now technologically possible to produce such transistors with gate oxides only 5 silicon atoms thick[l]. Since at least two of those 5 atoms are not in a local environment similar to either bulk Si or bulk SiO2, the properties of the interface are responsible for a significant fraction of the “bulk” properties of the gate oxide. However the physical (and especially their electrical) properties of the interfacial atoms are very different from .bulk Si or bulk SiO2. Further, roughness on an atomic scale can alter the leakage current by orders of magnitude.In our studies of such devices, we found that thermal oxidation tends to produce Si/SiO2 interfaces with 0.1-0.2 nm rms roughness.


2000 ◽  
Vol 654 ◽  
Author(s):  
X. Duan ◽  
K. Kisslinger ◽  
L. Mayes ◽  
S. Ruby ◽  
J. Barrett

AbstractThe Si/SiO2 interface is attracting new interest as gate dielectrics in MOS devices become ultra thin. In this paper, the impact of pre-gate cleaning on the morphology of the Si/SiO2 interface and the electrical performance of CMOS gate oxides has been systematically investigated. Using the High-Resolution Transmission Electron Microscopy (HRTEM) technique, we observed the Si/SiO2 interface at an atomic level. We have found a direct experimental relationship between the pre-gate cleaning scheme, Si/SiO2 interface morphology, and the electrical properties of CMOS gate oxides. When the ratio of H2O2:NH4OH ≥ 1.45, the roughness of the Si/SiO2 interface was dramatically improved, which, in turn, increased the Charge-to-Breakdown to an ideal value.


2015 ◽  
Vol 821-823 ◽  
pp. 480-483 ◽  
Author(s):  
A.I. Mikhaylov ◽  
Alexey V. Afanasyev ◽  
V.V. Luchinin ◽  
S.A. Reshanov ◽  
Adolf Schöner ◽  
...  

Electrical properties of the gate oxides thermally grown in N2O on n-type and p-type 4H-SiC have been compared using conventional MOS structure and inversion-channel MOS structure, respectively. Sufficient difference in the electrical properties of the gate oxides grown on n-type and p-type 4H-SiC was revealed. We conclude that the gate oxide process optimisation using inversion-channel MOS devices is superior as compared to the conventional MOS structure.


2018 ◽  
Vol 924 ◽  
pp. 461-464 ◽  
Author(s):  
Hidenori Tsuji ◽  
Takuji Hosoi ◽  
Yutaka Terao ◽  
Takayoshi Shimura ◽  
Heiji Watanabe

We investigated the impact of high-temperature H2/Ar mixture gas treatment of 4H-SiC(0001) surfaces before SiO2 deposition on the electrical properties of SiO2/SiC interfaces. Physical characterizations revealed that the SiC surface treated by the H2/Ar mixture gas exhibited a (√3×√3)R30° structure composed of Si-O bonds, indicating that a well-ordered and stable silicate adlayer was formed by the treatment to passivate SiC(0001) surface. Electrical defects at the CVD-grown SiO2/SiC interface was significantly reduced by the treatment. Consequently, a peak electron mobility in SiC-MOSFETs with the deposited gate oxides was enhanced to 24.9 cm2/Vs.


1998 ◽  
Vol 525 ◽  
Author(s):  
J. Kuehne ◽  
S. Hattangady ◽  
J. Piccirillo ◽  
G. C. Xing ◽  
G. Miner ◽  
...  

ABSTRACTIn order to prevent boron penetration in PMOS transistors without degrading channel mobility, it is necessary to engineer the distribution of nitrogen introduced into the gate oxide. We have investigated methods of engineering this distribution using nitric oxide (NO) gas in an RTP system to thermally nitride ultra-thin gate oxides. In one approach, the gate oxide is simultaneously grown and nitrided in a mixture of nitric oxide and oxygen. For a 40 Å film, SIMS depth profiling shows that this process moves the nitrogen peak into the bulk of the oxide away from the oxide silicon interface. In another approach, an 11 Å chemical oxide produced by a standard pre-furnace wet clean is nitrided in NO at 800 deg. C. This film is subsequently reoxidized in either oxygen or steam. For an 1100 deg. C., 120 sec RTP reoxidation in oxygen, the final film thickness is 41 Å. The nitrogen has a peak concentration of 5 at. % and the peak is located in the oxide 25 Åfrom the oxide/silicon interface. Ramped voltage breakdown testing was carried out on MOS capacitors built using reoxidized NO nitrided films. They have breakdown characteristics that are equivalent to conventional furnace grown oxides. These films show considerable promise as gate dielectrics for CMOS technologies at geometries of 0.25um and below.


1990 ◽  
Vol 137 (1) ◽  
pp. 57 ◽  
Author(s):  
M. Steyaert ◽  
Z. Chang
Keyword(s):  

2011 ◽  
Vol 3 (10) ◽  
pp. 1-4 ◽  
Author(s):  
Bushra A Hasan ◽  
◽  
Ghuson H Mohamed ◽  
Amer A Ramadhan

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