Time Resolved Diagnostics of RF Plasmas: a Fluid Model for ion Concentrations in the Sheath

1984 ◽  
Vol 38 ◽  
Author(s):  
Richard A. Gottscho
Keyword(s):  
Impact Ionization ◽  
Fluid Model ◽  
Formation Rate ◽  
Low Frequency ◽  
Quantitative Agreement ◽  
Ion Concentration ◽  
Time Resolved ◽  
Ion Concentrations ◽  
Computational Optimization ◽  
Spectrally Resolved

AbstractA one-dimensional fluid model is presented for time-dependent ion concentrations in chlorine containing discharges. The ion formation rate is determined from experimental plasma-induced emission intensities. The local field is estimated from spectrally resolved laser-induced fluorescence data obtained in similar, BCl3 discharges. Quantitative agreement with experiment is obtained implying that the basic assumptions in the model are valid: (1) ground state ions in the sheath are formed predominantly by electron-impact ionization; (2) Cl2+ ion motion is mobilitylimited by charge exchange collisions with Cl2 neutrals; (3) the degree of Cl2 dissociation is ∼. 65% at a power density of 1.8 W cm−3; (4) the ion concentration near the electrode is spatially uniform throughout most of the rf cycle; and (5) there are two times during a low frequency rf cycle when ions experience a strong extraction force.Semi-empirical models like the one described here should be useful in computational optimization of plasma processes such as etching and deposition, which are in wicre-spread use throughout the microelectronics industry.

Ion Dynamics in Low Frequency RF Plasmas

1983 ◽  
Vol 29 ◽  
Author(s):  
Richard A. Gottscho ◽  
Daniel L. Flamm ◽  
Randolph H. Burton ◽  
Vincent M. Donnelly
Keyword(s):  
Plasma Etching ◽  
Low Frequency ◽  
Ion Concentration ◽  
Ion Dynamics ◽  
Applied Potential ◽  
Time Resolved ◽  
Rf Plasmas ◽  
Use Of Time ◽  
Concentration Time ◽  
State Ionic

ABSTRACTWe describe the use of time-resolved laser-induced fluorescence (TRLIF) and plasma-induced emission (PIE) spectroscopy in studying the dynamics of ion transport, formation, and loss in low frequency RF plasmas, used in plasma etching and deposition. N2+ and Cl2+ ions formed in N2, Cl2, and N2/Cl2 discharges were monitored as a function of both position between the electrodes and magnitude of the applied rf potential. In the discharge center, TRLIF was used to measure ground state ionic lifetimes. In N2/Cl2 mixtures, N2+ was found to charge exchange rapidly with Cl2 and Cl to form Cl2+ and Cl+. In the electrode sheaths, the ion response to the applied potential was evident from periodic depletion of the ion concentration as a result of acceleration by the field. From the spatial variation in the ion concentration time dependence, we deduce that the sheaths expand and contract with the same period as the applied potential.

scholarly journals Broadband dielectric spectroscopy for monitoring temperature-dependent chloride ion motion in BiOCl plates

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Adrian Radoń ◽  
Dariusz Łukowiec ◽  
Patryk Włodarczyk
Keyword(s):  
Electrical Conductivity ◽  
Dielectric Spectroscopy ◽  
Low Frequency ◽  
Chloride Ion ◽  
Ion Source ◽  
Chloride Ions ◽  
Ion Concentration ◽  
Broadband Dielectric Spectroscopy ◽  
Free Chloride ◽  
Structure Rebuilding

AbstractThe dielectric properties and electrical conduction mechanism of bismuth oxychloride (BiOCl) plates synthesized using chloramine-T as the chloride ion source were investigated. Thermally-activated structure rebuilding was monitored using broadband dielectric spectroscopy, which showed that the onset temperature of this process was 283 K. This rebuilding was related to the introduction of free chloride ions into [Bi2O2]2+ layers and their growth, which increased the intensity of the (101) diffraction peak. The electrical conductivity and dielectric permittivity were related to the movement of chloride ions between plates (in the low-frequency region), the interplanar motion of Cl− ions at higher frequencies, vibrations of these ions, and charge carrier hopping at frequencies above 10 kHz. The influence of the free chloride ion concentration on the electrical conductivity was also described. Structure rebuilding was associated with a lower concentration of free chloride ions, which significantly decreased the conductivity. According to the analysis, the BiOCl plate conductivity was related to the movement of Cl− ions, not electrons.

scholarly journals Numerical and Experimental Investigation of Longitudinal Oscillations in Hall Thrusters

Aerospace ◽  
2021 ◽  
Vol 8 (6) ◽  
pp. 148
Author(s):  
Vittorio Giannetti ◽  
Manuel Martín Saravia ◽  
Luca Leporini ◽  
Simone Camarri ◽  
Tommaso Andreussi
Keyword(s):  
Discharge Current ◽  
Fluid Model ◽  
Low Frequency ◽  
Hall Thruster ◽  
Hall Thrusters ◽  
Current Signal ◽  
Plasma Parameters ◽  
Plasma Properties ◽  
Breathing Mode ◽  
Spatio Temporal

One of the main oscillatory modes found ubiquitously in Hall thrusters is the so-called breathing mode. This is recognized as a relatively low-frequency (10–30 kHz), longitudinal oscillation of the discharge current and plasma parameters. In this paper, we present a synergic experimental and numerical investigation of the breathing mode in a 5 kW-class Hall thruster. To this aim, we propose the use of an informed 1D fully-fluid model to provide augmented data with respect to available experimental measurements. The experimental data consists of two datasets, i.e., the discharge current signal and the local near-plume plasma properties measured at high-frequency with a fast-diving triple Langmuir probe. The model is calibrated on the discharge current signal and its accuracy is assessed by comparing predictions against the available measurements of the near-plume plasma properties. It is shown that the model can be calibrated using the discharge current signal, which is easy to measure, and that, once calibrated, it can predict with reasonable accuracy the spatio-temporal distributions of the plasma properties, which would be difficult to measure or estimate otherwise. Finally, we describe how the augmented data obtained through the combination of experiments and calibrated model can provide insight into the breathing mode oscillations and the evolution of plasma properties.

Thermal stability of ribosomes from a thermophilic and a mesophilic fungus

1973 ◽  
Vol 19 (6) ◽  
pp. 761-763 ◽  
Author(s):  
H. M. Miller ◽  
M. G. Shepherd
Keyword(s):  
Thermal Stability ◽  
Ion Concentration ◽  
Magnesium Ion ◽  
Penicillium Notatum ◽  
Ribosomal Subunits ◽  
Ion Concentrations ◽  
Thermal Stability Of

Ribosomes and ribosomal subunits from the thermophile Penicillium duponti were found to be more thermostable than the corresponding particles from the mesophile Penicillium notatum. The thermostability of the ribosomes from both organisms was dependent on magnesium ion concentration. The dissociation of the 80-S ribosomes into 60-S and 40-S subunits occurred at higher magnesium ion concentrations for the mesophile than the thermophile.

scholarly journals A numerical model of the ionosphere, including the E-region above EISCAT

1996 ◽  
Vol 14 (2) ◽  
pp. 191-200 ◽  
Author(s):  
P.-Y. Diloy ◽  
A. Robineau ◽  
J. Lilensten ◽  
P.-L. Blelly ◽  
J. Fontanari
Keyword(s):  
Electric Field ◽  
Fluid Model ◽  
Molecular Ions ◽  
Ion Concentration ◽  
Topside Ionosphere ◽  
Ion Chemistry ◽  
Vhf Radar ◽  
Theoretical Predictions ◽  
Consistent Manner ◽  
E Region

Abstract. It has been previously demonstrated that a two-ion (O+ and H+) 8-moment time-dependent fluid model was able to reproduce correctly the ionospheric structure in the altitude range probed by the EISCAT-VHF radar. In the present study, the model is extended down to the E-region where molecular ion chemistry (NO+ and O+2, essentially) prevails over transport; EISCAT-UHF observations confirmed previous theoretical predictions that during events of intense E×B induced convection drifts, molecular ions (mainly NO+) predominate over O+ ions up to altitudes of 300 km. In addition to this extension of the model down to the E-region, the ionization and heating resulting from both solar insolation and particle precipitation is now taken into account in a consistent manner through a complete kinetic transport code. The effects of E×B induced convection drifts on the E- and F-region are presented: the balance between O+ and NO+ ions is drastically affected; the electric field acts to deplete the O+ ion concentration. The [NO+]/[O+] transition altitude varies from 190 km to 320 km as the perpendicular electric field increases from 0 to 100 mV m-1. An interesting additional by-product of the model is that it also predicts the presence of a noticeable fraction of N+ ions in the topside ionosphere in good agreement with Retarding Ion Mass Spectrometer measurements onboard Dynamic Explorer.

scholarly journals From ionising radiation to air ion formation in the lower atmosphere

2016 ◽  
Author(s):  
Xuemeng Chen ◽  
Veli-Matti Kerminen ◽  
Jussi Paatero ◽  
Pauli Paasonen ◽  
Hanna E. Manninen ◽  
...  
Keyword(s):  
Gamma Radiation ◽  
Ionising Radiation ◽  
Ion Concentration ◽  
Lower Atmosphere ◽  
Forest Site ◽  
Long Distance ◽  
Ion Concentrations ◽  
Ion Formation ◽  
Depth Analysis ◽  
Ion Production

Abstract. Most of the ion production in the atmosphere is attributed to ionising radiation. In the lower atmosphere, ionising radiation consists mainly of the decay emissions of radon and its progeny, gamma radiation of the terrestrial origin as well as photons and elementary particles of cosmic radiation. These types of radiation produce ion pairs via the ionisation of nitrogen and oxygen as well as trace species in the atmosphere, the rate of which is defined as the ionising capacity. Larger air ions are produced out of the initial charge carriers by processes, such as clustering or attachment to pre-existing aerosol particles. This study aimed 1) to identify the key factors responsible for the variability in ionising radiation and in the observed air ion concentrations, 2) to reveal the linkage between them, and 3) to provide an in-depth analysis into the effects of ionising radiation on air ion formation, based on measurement data collected during 2003–2006 from a boreal forest site in southern Finland. In general, gamma radiation dominated the ion production in the lower atmosphere. Variations in the ionising capacity came from mixing layer dynamics, soil type and moisture content, meteorological conditions, long-distance transportation, snow cover attenuation and precipitation. Similar diurnal patterns to variations in the ionising capacity were observed in air ion concentrations of the cluster size (0.8–1.7 nm in mobility diameters). Clear promotion effects of the ionising radiation on air ion production were demonstrated. Typically, features observed in the 0.8–1 nm ion concentration were in connection to variations of the ionising capacity. Further by carefully constraining perturbing variables, a clear relationship was also identifiable between the cluster ion concentration and the ionising capacity, proving the functionality of ionising radiation in air ion production in the lower atmosphere.

scholarly journals Theta activity paradoxically boosts gamma and ripple frequency sensitivity in prefrontal interneurons

2021 ◽  
Vol 118 (51) ◽  
pp. e2114549118
Author(s):  
Ricardo Martins Merino ◽  
Carolina Leon-Pinzon ◽  
Walter Stühmer ◽  
Martin Möck ◽  
Jochen F. Staiger ◽  
...  
Keyword(s):  
Low Frequency ◽  
Gamma Oscillations ◽  
Brain State ◽  
Gabaergic Interneurons ◽  
Time Resolved ◽  
Cortical Rhythms ◽  
Brain States ◽  
Fast Spiking ◽  
Fast Oscillations ◽  
Cross Frequency Coupling

Fast oscillations in cortical circuits critically depend on GABAergic interneurons. Which interneuron types and populations can drive different cortical rhythms, however, remains unresolved and may depend on brain state. Here, we measured the sensitivity of different GABAergic interneurons in prefrontal cortex under conditions mimicking distinct brain states. While fast-spiking neurons always exhibited a wide bandwidth of around 400 Hz, the response properties of spike-frequency adapting interneurons switched with the background input’s statistics. Slowly fluctuating background activity, as typical for sleep or quiet wakefulness, dramatically boosted the neurons’ sensitivity to gamma and ripple frequencies. We developed a time-resolved dynamic gain analysis and revealed rapid sensitivity modulations that enable neurons to periodically boost gamma oscillations and ripples during specific phases of ongoing low-frequency oscillations. This mechanism predicts these prefrontal interneurons to be exquisitely sensitive to high-frequency ripples, especially during brain states characterized by slow rhythms, and to contribute substantially to theta-gamma cross-frequency coupling.

Jeans-Alfvén instability in quantum dusty magnetoplasmas

2017 ◽  
Vol 83 (1) ◽  
Author(s):  
M. Jamil ◽  
A. Rasheed ◽  
M. Amir ◽  
G. Abbas ◽  
Young-Dae Jung
Keyword(s):  
Significant Contribution ◽  
Electron Number Density ◽  
Fluid Model ◽  
Low Frequency ◽  
Momentum Balance ◽  
Number Density ◽  
Electron Number ◽  
Momentum Balance Equation ◽  
Quantum Plasmas ◽  
Jeans Instability

The Jeans instability is examined in quantum dusty magnetoplasmas due to low-frequency magnetosonic perturbations. The fluid model consisting of the momentum balance equation for quantum plasmas, Poisson’s equation for the gravitational potential and Maxwell’s equations for electromagnetic magnetosonic perturbations is solved. The numerical analysis elaborates the significant contribution of magnetic field, electron number density and variable dust mass to the Jeans instability.

Local mechanisms of phase-dependent postsynaptic modifications of NMDA-induced oscillations in the abducens motoneurons: a simulation study

1996 ◽  
Vol 76 (2) ◽  
pp. 1015-1024 ◽  
Author(s):  
I. L. Kopysova ◽  
S. M. Korogod ◽  
J. Durand ◽  
S. Tyc-Dumont
Keyword(s):  
Synaptic Input ◽  
Pattern Generation ◽  
Ion Concentration ◽  
Extracellular Potassium ◽  
Pump System ◽  
Voltage Gated ◽  
Ion Concentrations ◽  
Concentration Changes ◽  
Transmembrane Currents

1. In vivo experiments have shown that extracellular microelectrophoretic application of N-methyl-D-aspartate (NMDA) induced oscillatory plateau potentials with bursts of action potentials in rat abducens motoneurons. The period of these slow NMDA oscillations could be altered by single trigeminal non-NMDA excitatory input delivered at low frequency during the NMDA oscillations. 2. A resetting of the oscillations was observed depending on the phase of slow oscillatory cycle during which the trigeminal excitation occurred. 3. We investigated local mechanisms responsible for the phase-dependent modifications of NMDA oscillations, including contributions of voltage and concentration transients, in the mathematical model of the isopotential membrane compartment equipped with voltage-gated Na+, K+, and Ca2+ channels, with Ca2+-dependent K+ channels, and with ligand-gated NMDA and alpha-amino-3-hydroxy-5-methyl-4-isoxazolepropionic acid (AMPA) receptor channels. The faithful model was constructed with the use of models described earlier, which were modified by increasing time constants of kinetic variables of all voltage-gated conductances and by including coupled dynamics of voltages and ion concentrations. The changes in ion concentrations were produced near the membrane by transmembrane currents and removal mechanisms (pumps, diffusion). 4. This work focuses on local arrangement of voltage- and ligand-gated conductances and on local ion concentration changes in two separate pools: the postsynaptic pool of AMPA receptors and the extrasynaptic pool. In terms of the electrotonic and diffusional length constants, these pools were electrotonically close but diffusionally remote. 5. It was found that the effect of resetting can be produced by a local interaction between plateau and spike-generating conductances and glutamate receptors. 6. In vivo phase-dependent interactions between NMDA oscillations and AMPA synaptic input were reproduced by the local model only when changes in intracellular sodium and extracellular potassium concentrations were taken into account and the mechanisms of ion removal from postsynaptic pools had slower kinetics than the fast pump system operating in the extracellular pool. 7. Postsynaptic changes in ion concentrations of Na+ and K+ in intra- and extracellular layers near the membrane shift of Nernst equilibrium potentials for these ions depending on the phase of activation of synaptic input. Thus Na+ and k+ components of all transmembrane currents involved in the pattern generation are differently affected by synaptic action during the oscillations. We conclude that slow postsynaptic changes in ion concentrations near the membrane play a key role in the resetting of the NMDA oscillations.

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