EuTe/PbTe Superlattices: Mbe Growth and Optical Characterization

1993 ◽  
Vol 301 ◽  
Author(s):  
G. Springholz ◽  
Shu Yuan ◽  
G. Bauer ◽  
M. Kriechbaum ◽  
H. Krenn

ABSTRACTThe heteroepitaxial growth of EuTe on PbTe (111) by molecular beam epitaxy (MBE) was investigated using in situ reflection high energy electron diffraction (RHEED). As a function of substrate temperature and Te2 flux rate, the resulting EuTe (111) surfaces exhibit several different surface reconstructions corresponding to Te-stabilized or Eu-stabilized surfaces. The Eustabilized surface shows a (2√3 × 2√3)R30° surface reconstruction. Because of the strain induced tendency for 3D islanding, only in a narrow window of MBE growth parameters perfect 2D layer-by-layer heteroepitaxial growth exists. Using such optimized MBE growth conditions, we have fabricated a series of PbTe/EuTe superlattices. In such superlattices the wide band gap EuTe layers act as barriers and the narrow band gap PbTe as quantum wells. The superlattices were investigated by high resolution x-ray diffraction, showing their high structural perfection. Modulated low temperature Fourier transform infrared reflection measurements were performed in order to determine the confined energy levels in the PbTe quantum wells. The measurements indicate that mini-subbands are formed in the PbTe quantum wells with a mini-band width of 22 meV in agreement with envelope function calculations.

1988 ◽  
Vol 144 ◽  
Author(s):  
F. D. Schowengerdt ◽  
F. J. Grunthaner ◽  
John K. Liu

ABSTRACTWe report on a systematic study of the composition and structure of GaAs/InAs/GaAs quantum wells using Auger Electron Spectroscopy (AES), Extended Energy Loss Fine Structure (EELFS), and Reflection High Energy Electron Diffraction (RHEED) techniques. Double heterostructures with InAs thickness ranging from 2 to 10 monolayers, capped by 2 to 10 monolayers of GaAs, were grown by MBE using a variety of techniques, including those employing sequential, interrupted, and delayed shutter timing sequences. AES peak ratios are compared with model calculations to monitor compositional development of the multilayers. The AES results are correlated with RHEED measurements to determine MBE growth parameters for optimal control of the stoichiometry and surface morphology. EELFS was used to monitor strain in the buried InAs layers. The AES results show departure from smooth laminar growth of layers of stoichiometric InAs on GaAs at temperatures below 420 C and above 470 C. AES results on the quantum well structures suggest floating InAs layers on top of the GaAs and/or facet formation in the GaAs layers. The EELFS results, when compared to bulk InAs, indicate the presence of strain in the buried InAs quantum well.


1992 ◽  
Vol 281 ◽  
Author(s):  
G. Springholz ◽  
G. Bauer

ABSTRACTUsing reflection high energy electron diffraction (RHEED), the heteroepitaxy of EuTe on PbTe (111) by molecular beam epitaxy (MBE) was investigated. The resulting EuTe (111) surfaces exhibit different surface reconstructions corresponding to a Te-stabilized or a Eu-stabilized surface. We have observed perfect 2D layer-by-layer heteroepitaxial growth and RHEED intensity oscillations only for a small range of growth conditions. Using such optimum conditions, we have fabricated strained PbTe/EuTe superlattices with superior structural perfection, as shown by high resolution x-ray diffraction.


1989 ◽  
Vol 145 ◽  
Author(s):  
Francoise S. Turco ◽  
M.C. Tamargo

AbstractReflection high energy electron diffraction (RHEED) intensity oscillations are often used to investigate in situ the growth of III-V materials by molecular beam epitaxy (MBE). In this work, we have used RHEED oscillations to perform a quantitative study of the growth mechanisms of ZnSe, a II-VI semiconductor.Our experiments illustrate that the RHEED pattern of ZnSe is far less intense than that of III-V materials grown by MBE, and no specular spot is observed over a wide range of growth conditions. We have, however, been able to record up to 25 oscillations allowing a quantitative study of the growth of ZnSe by MBE. Thus we have used RHEED oscillations to make an in situ systematic study of the influence of the three main growth parameters (substrate temperature and Zn or Se impinging fluxes) on the ZnSe growth rate. We observed that the variation of the ZnSe growth rate is due to a non unity sticking coefficient of both Zn and Se species at the interface in the standard growth conditions used. Our observations can be described using a thermodynamic model and enable us to control the desired growth conditions. Our work demonstrates the utility of RHEED oscillations to understand the MBE growth mechanisms of II-VI compounds.


1993 ◽  
Vol 317 ◽  
Author(s):  
N. Frank ◽  
G. Springholz ◽  
G. Bauer

ABSTRACTMBE growth of 2% lattice-Mismatched EuTe on PbTe (111) is studied combining in-situ reflection high-energy electron diffraction (RHEED) with UHV scanning tunneling Microscopy (STM) to investigate the evolution of the EuTe surface Morphology. Using RHEED we have found that 2D nucleation and layer-by-layer growth occurs only in a very narrow range of growth conditions as a result of a strain induced coherent islanding of the surface[l], which leads to a roughening transition at the critical layer thickness hc of 45 Monolayers (ML). Starting with a very smooth initial (111) PbTe surface with terrace widths of 50 to 200 nm, islands of monolayer height are formed due to 2D nucleation of EuTe. For EuTe layer thicknesses below hc, the root mean square roughness (RMS) is essentially constant and equal to about one ML. Beyond hc, the surface roughness increases strongly and islands of about 20 ML height are observed for an EuTe layer thickness of 66 ML.


1993 ◽  
Vol 312 ◽  
Author(s):  
Richard Mirin ◽  
Mohan Krishnamurthy ◽  
James Ibbetson ◽  
Arthur Gossard ◽  
John English ◽  
...  

AbstractHigh temperature (≥ 650°C) MBE growth of AlAs and AlAs/GaAs superlattices on (100) GaAs is shown to lead to quasi-periodic facetting. We demonstrate that the facetting is only due to the AlAs layers, and growth of GaAs on top of the facets replanarizes the surface. We show that the roughness between the AlAs and GaAs layers increases with increasing number of periods in the superlattice. The roughness increases to form distinct facets, which rapidly grow at the expense of the (100) surface. Within a few periods of the initial facet formation, the (100) surface has disappeared and only the facet planes are visible in cross-sectional transmission electron micrographs. At this point, the reflection high-energy electron diffraction pattern is spotty, and the specular spot is a distinct chevron. We also show that the facetting becomes more pronounced as the substrate temperature is increased from 620°C to 710°C. Atomic force micrographs show that the valleys enclosed by the facets can be several microns long, but they may also be only several nanometers long, depending on the growth conditions.


2016 ◽  
Vol 83 (11) ◽  
Author(s):  
Qianli Chen ◽  
Ahmed Elbanna

A wide range of engineered and natural composites exhibit a layered architecture whereby individual building blocks are assembled layer by layer using cohesive interfaces. We present a novel mechanism for evolving acoustic band gap structure in a model system of these composites through patterning the microstructure in a way that triggers nonplanar interfacial deformations between the layers as they are stretched. Through the controlled deformation and growth of interlayer channels under macroscopic tension, we observe the emergence of multiple wide band gaps due to Bragg diffraction and local resonance. We describe these phenomena in details for three example microstructures and discuss the implications of our approach for harnessing controlled deformation in modulating band gap properties of composite materials.


1986 ◽  
Vol 67 ◽  
Author(s):  
H. Ishiwara ◽  
T. Asano ◽  
H. C. Lee ◽  
Y. Kuriyama ◽  
K. Seki ◽  
...  

ABSTRACTRecent progress in the research of heteroepitaxial growth of Si, Ge, and GaAs films on CaF2/Si structures is reviewed. Growth conditions and material properties of the Si/CaF2/Si structures are first discussed. It is shown that such growth techniques as the predeposition technique and the recrystallization method are useful to improve the crystalline quality of Si films on the CaF2/Si structures. Then, device application of the Si/CaF2/Si structure to field effect transistors with epitaxial MIS (metal-insulatorsemiconductor) gate electrodes is described. Finally, epitaxial growth of Ge and GaAs films on the CaF2/Si structure are discussed, in which such growth parameters as the substrate temperature and growth rate are optimized to obtain high-quality films with excellent crystallinity and smooth surface.


2007 ◽  
Vol 244 (5) ◽  
pp. 1727-1734 ◽  
Author(s):  
H. Haratizadeh ◽  
B. Monemar ◽  
Plamen P. Paskov ◽  
Per Olof Holtz ◽  
E. Valcheva ◽  
...  

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