Characterization of Pmma Gel Spheres and Shear Induced Microstructure

1991 ◽  
Vol 248 ◽  
Author(s):  
S. E. Paulin ◽  
Bruce J. Ackersons ◽  
M. S. Wolfe
Keyword(s):  
Phase Diagram ◽  
Intrinsic Viscosity ◽  
Volume Fraction ◽  
Particle Properties ◽  
Effective Volume Fraction ◽  
Sphere Suspensions ◽  
Work Done ◽  
Pmma Particles ◽  
Nonequilibrium Phase Diagram

AbstractPolymethylmethacrylate (PMMA) particles are suspended without additional free polymer in benzyl alcohol, where they swell to nearly three times their dry radius. The single particle properties are examined by static and dynamic light scattering measurements, as well as by intrinsic viscosity measurements. A colloidal liquid/crystal phase diagram is determined as a function of effective volume fraction determined from the intrinsic viscosity. The samples are subjected to oscillatory shear flows to determine the influence of flow on the particle microstructure. A nonequilibrium phase diagram is constructed indicating a correlation between spontaneous ordering at equilibrium and shear induced ordering. These results are compared with previous work done for hard PMMA sphere suspensions.

Rheological characterization of tack and viscoelasticity of compositions of crepe coating used in the Yankee dryer

TAPPI Journal ◽  
2019 ◽  
Vol 18 (11) ◽  
pp. 641-649
Author(s):  
JOSHUA OMAMBALA ◽  
CARL MCINTYRE
Keyword(s):  
Normal Force ◽  
Weight Ratio ◽  
Good Combination ◽  
Rheological Characterization ◽  
Nonlinear Viscoelastic ◽  
Coating Composition ◽  
Linear And Nonlinear ◽  
Work Done ◽  
Tissue Production

The vast majority of tissue production uses creping to achieve the required set of properties on the base sheet. The Yankee coating helps to develop the desired crepe that in turn determines properties such as bulk and softness. The adhesion of the sheet to the Yankee surface is a very important characteristic to consider in achieving the desired crepe. The coating mix usually consists of the adhesive, modifier, and release. A good combination of these components is essential to achieving the desired properties of the tissue or towel, which often are determined by trials on the machine that can be time consuming and lead to costly rejects. In this paper, five compositions of an industrial Yankee coating adhesive, modifier, and release were examined rheologically. The weight ratio of the adhesive was kept constant at 30% in all five compositions and the modifier and release ratios were varied. The normal force and work done by the different compositions have been shown at various temperatures simulating that of the Yankee surface, and the oscillatory test was carried out to explain the linear and nonlinear viscoelastic characteristic of the optimal coating composition.

TEM Characterization of Pseudotetragonal Mullite

2001 ◽  
Vol 7 (S2) ◽  
pp. 426-427
Author(s):  
Bradley R. Johnson ◽  
Waltraud M. Kriven
Keyword(s):  
Phase Diagram ◽  
Spatial Relationship ◽  
Equilibrium Structure ◽  
Lattice Parameters ◽  
Orthorhombic Structure ◽  
Containerless Processing ◽  
Rich Phase ◽  
Tem Characterization ◽  
Solution Field

Mullite (3Al2O3•2SiO2) exists in a solid solution field (∼57-63 mol% Al2O3) as the only stable compound in the Al2O3•SiO2 phase diagram at ambient pressures. Equilibrium 3:2 mullite has an orthorhombic structure with b>a (o-mullite). However, when initially crystallized from molecularly mixed, 3:2 precursors at temperatures < 1200°C, the first phase that forms has lattice parameters with a ≈b. This structure is often termed pseudotetragonal mullite (pt-mullite), since even when the ‘a’ and ‘b’ lattice parameters are identical, they are symmetrically independent. Pseudotetragonal mullite has been shown to contain approx. 70 mol% Al2O3. with increasing time and temperature, the structure gradually assimilates the residual SiO2, and the lattice parameters change, such that by 1400°C, the material has attained its equilibrium structure and composition.TEM was used to determine the spatial relationship between the crystalline phase and the residual, amorphous, SiO2-rich phase in pt-mullite. The starting materials were quenched, 3:2 mullite beads and fibers (made by containerless processing).

Magnetic Characterization of SUS316L Deformed by High Pressure Torsion

2011 ◽  
Vol 239-242 ◽  
pp. 1300-1303
Author(s):  
Hong Cai Wang ◽  
Minoru Umemoto ◽  
Innocent Shuro ◽  
Yoshikazu Todaka ◽  
Ho Hung Kuo
Keyword(s):  
Plastic Deformation ◽  
High Pressure ◽  
Stainless Steel ◽  
Phase Transformation ◽  
Austenitic Stainless Steel ◽  
Volume Fraction ◽  
High Pressure Torsion ◽  
Austenitic Matrix ◽  
Magnetic Characterization

SUS316L austenitic stainless steel was subjected to severe plastic deformation (SPD) by the method of high pressure torsion (HPT). From a fully austenitic matrix (γ), HPT resulted in phase transformation from g®a¢. The largest volume fraction of 70% a¢ was obtained at 0.2 revolutions per minute (rpm) while was limited to 3% at 5rpm. Pre-straining of g by HPT at 5rpm decreases the volume fraction of a¢ obtained by HPT at 0.2rpm. By HPT at 5rpm, a¢®g reverse transformation was observed for a¢ produced by HPT at 0.2rpm.

A Novel Processing Route for the Fabrication of Monolithic and Composite Silicon Nitride

1992 ◽  
Vol 287 ◽  
Author(s):  
R. V. Raman ◽  
S. V. Rele
Keyword(s):  
Volume Fraction ◽  
Hot Isostatic Pressing ◽  
Thermal Exposure ◽  
Processing Route ◽  
Promising Alternative ◽  
Α Phase ◽  
Key Issues ◽  
Novel Processing ◽  
Composite Silicon

ABSTRACTCurrent hot isostatic consolidation methodology used for the fabrication of complex-shaped Si3N4-based components requires the use of an expensive glass encapsulation technique and extended thermal exposure (in hours) of the specimen. An alternative consolidation approach involving the use of solid pressure transmitting media under high pressure, has enabled the consolidation of Si3N4 alloys without the need for glass encapsulation.Characterization of microstructures and mechanical properties of this (MOR, fracture toughness) material has been carried out and will be presented. It has been noted that in Si 3N4/8%Y2O3-4%Al2O3 composition, consolidated using this approach, a significantly larger volume fraction of α phase has been retained compared with typically observed conversion in α⇒ β in hot isostatically pressed material or sintered material.Key issues for addressing densification and microstructure control using this process are presented. This rapid consolidation approach appears to be a promising alternative to hot isostatic pressing for the fabrication of complex-shaped Si3N4 components.

Estimation of Interlayer Thickness in Inorganic Particulate-Filled Polymer Composites

2011 ◽  
Vol 24 (6) ◽  
pp. 777-788 ◽  
Author(s):  
J.Z. Liang
Keyword(s):  
Polymer Composites ◽  
Volume Fraction ◽  
Particle Diameter ◽  
Interfacial Structure ◽  
Interlayer Thickness ◽  
Filled Polymer ◽  
Mechanical And Physical Properties ◽  
The Relationship ◽  
Good Agreement

The structure of the interlayer between matrix and inclusions affect directly the mechanical and physical properties of inorganic particulate-filled polymer composites. The interlayer thickness is an important parameter for characterization of the interfacial structure. The effects of the interlayer between the filler particles and matrix on the mechanical properties of polymer composites were analyzed in this article. On the basis of a simplified model of interlayer, an expression for estimating the interlayer thickness ([Formula: see text]) was proposed. In addition, the relationship between the [Formula: see text] and the particle size and its concentration was discussed. The results showed that the calculations of the [Formula: see text] and thickness/particle diameter ratio ([Formula: see text]) increased nonlinearly with an increase of the volume fraction of the inclusions. Moreover, the predictions of [Formula: see text] and the relevant data reported in literature were compared, and good agreement was found between them.

La structure de classes québécoise au 19e siècle et le problème de l'articulation des modes de production

1981 ◽  
Vol 14 (3) ◽  
pp. 487-518
Author(s):  
Gérald Bernier
Keyword(s):  
Census Data ◽  
New France ◽  
Class Structure ◽  
Capitalist Development ◽  
Single Class ◽  
The Moment ◽  
Empirical Demonstration ◽  
Work Done ◽  
The Impact

The study of social classes in the nineteenth century requires the development of conceptual tools able to explain the impact of the Conquest on the pre-existant social structures in determining transformations of the class structure during the subsequent decades.This article examines the work done on this question by Marxist writers. The author criticizes certain conclusions which have been drawn and which suggest deficiencies at a theoretical level. The objections relate to the marked tendency of these conclusions to perceive the structural effects of the Conquest in terms of the formation of a double-class structure characterized by “ethnic origins.” Specifically, the author challenges the notion of the division itself, as well as the criterion on which the division is based.The author proposes that an analysis centred upon the concepts relating to a problem of the transition and linkage of different modes of production permits a more satisfying interpretation, if accompanied by a certain number of considerations of the “upside” and “downside” of the Conquest. To this end, the argument is based on a characterization of New France in terms of the domination of the relations of production of the feudal type and on an analysis of metropolitan centres with intent to evaluate their level of capitalist development at the moment of their respective colonial penetration in Canada. The results of this approach permit one to posit the existence of a single-class structure, characterized principally by the existence of elements connecting diverse modes and forms of production, whose origin reflects the unequal state of economic development in the two metropolitan centres.The empirical demonstration rests on the census data of 1851–1852 and on the complementary information drawn from the works of historians.

METALLURGICAL AND CORROSION CHARACTERIZATION OF POST WELD HEAT TREATED DUPLEX STAINLESS STEEL (UNS S31803) JOINTS BY FRICTION WELDING PROCESS

2016 ◽  
Vol 23 (03) ◽  
pp. 1650013 ◽  
Author(s):  
MOHAMMED ASIF M. ◽  
KULKARNI ANUP SHRIKRISHNA ◽  
P. SATHIYA
Keyword(s):  
Stainless Steel ◽  
Duplex Stainless Steel ◽  
Friction Welding ◽  
Volume Fraction ◽  
Welding Process ◽  
Equilibrium Temperature ◽  
Weld Interface ◽  
Heat Treated ◽  
Weld Heat

The present study focuses on the metallurgical and corrosion characterization of post weld heat treated duplex stainless steel joints. After friction welding, it was confirmed that there is an increase in ferrite content at weld interface due to dynamic recrystallization. This caused the weldments prone to pitting corrosion attack. Hence the post weld heat treatments were performed at three temperatures 1080[Formula: see text]C, 1150[Formula: see text]C and 1200[Formula: see text]C with 15[Formula: see text]min of aging time. This was followed by water and oil quenching. The volume fraction of ferrite to austenite ratio was balanced and highest pit nucleation resistance were achieved after PWHT at 1080[Formula: see text]C followed by water quench and at 1150[Formula: see text]C followed by oil quench. This had happened exactly at parameter set containing heating pressure (HP):40 heating time (HT):4 upsetting pressure (UP):80 upsetting time (UP):2 (experiment no. 5). Dual phase presence and absence of precipitates were conformed through TEM which follow Kurdjumov–Sachs relationship. PREN of ferrite was decreasing with increase in temperature and that of austenite increased. The equilibrium temperature for water quenching was around 1100[Formula: see text]C and that for oil quenching was around 1140[Formula: see text]C. The pit depths were found to be in the range of 100[Formula: see text]nm and width of 1.5–2[Formula: see text][Formula: see text]m.

Phase diagram, crystal growth and characterization of Mn-substituted ZnGeAs2 system

2008 ◽  
Vol 69 (2-3) ◽  
pp. 408-410 ◽  
Author(s):  
Hiroaki Matsushita ◽  
Masaki Watanabe ◽  
Akinori Katsui
Keyword(s):  
Phase Diagram ◽  
Crystal Growth
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