Selective Growth of GaAs on GaAs-Coated Si Substrate by Liquid Phase Electro-Epitaxy

1991 ◽  
Vol 237 ◽  
Author(s):  
Shiro Sakai ◽  
Yasuno Ohashi

ABSTRACTThe selective LPEE (liquid phase electro-epitaxy) growth of GaAs on GaAs-coated Si substrate prepared by MOCVD has been performed. Several attempts, the use of the insulator melt cap, lowering of the melt height and optimization of the stripe direction, have been tried to increase the lateral growth rate. Very wide (60 μm) lateral overgrowth on the SiO2 mask is obtained by making the stripe window in <010> and equivalent directions and by increasing the lateral current component in the LPEE. The GaAs layer laterally grown on the SiO2 has much less EPD (etch pit density) showing that the defect in the MOCVD-GaAs is blocked by the SiO2. The growth mechanism and the method of increasing the lateral growth rate are discussed.

2003 ◽  
Vol 216 (1-4) ◽  
pp. 78-82 ◽  
Author(s):  
Toshio Kochiya ◽  
Yutaka Oyama ◽  
Ken Suto ◽  
Jun-Ichi Nishizawa

2003 ◽  
Vol 258 (1-2) ◽  
pp. 41-48
Author(s):  
Yutaka Oyama ◽  
Toshio Kochiya ◽  
Ken Suto ◽  
Jun-Ichi Nishizawa

2002 ◽  
Vol 243 (2) ◽  
pp. 267-274 ◽  
Author(s):  
Yutaka Oyama ◽  
Toshio Kochiya ◽  
Ken Suto ◽  
Jun-ichi Nishizawa

Polymer ◽  
2006 ◽  
Vol 47 (21) ◽  
pp. 7601-7606 ◽  
Author(s):  
Koji Yamada ◽  
Kaori Watanabe ◽  
Kiyoka Okada ◽  
Akihiko Toda ◽  
Masamichi Hikosaka

2009 ◽  
Vol 257 (10) ◽  
pp. 2175-2181 ◽  
Author(s):  
Miho Kojima ◽  
Fabio Minoru Yamaji ◽  
Hiroyuki Yamamoto ◽  
Masato Yoshida ◽  
Takahisa Nakai

2000 ◽  
Vol 639 ◽  
Author(s):  
H. Shin ◽  
D. B. Thomson ◽  
P. Q. Miraglia ◽  
S. D. Wolter ◽  
R. Schlesser ◽  
...  

ABSTRACTFree-standing single crystals of bulk GaN were grown via unseeded vapor phase transport at 1130°C on hexagonal BN surfaces via direct reaction of Ga with ammonia. The number of nucleation events was reduced and the crystal size increased by introducing the ammonia at high temperatures. The resulting crystals were either needles or platelets depending on the process variables employed. Low V/III ratios achieved via ammonia flow rates ≤ 75sccm and/or ammonia total pressures ≤ 430Torr favored lateral growth. The average lateral growth rate for the platelets was ∼50μm/hr; the average vertical growth rate for the needles was ∼500μm/hr. Growth rates in all other directions for each of these two morphologies were very low. Seeded growth of both needle and platelet crystals was also achieved; however, the growth rate decreased at longer times and higher pressures due to reaction with H2 from the increased decomposition of ammonia. Nitrogen dilution suppressed this decomposition. A 2mm × 1.5mm GaN crystal was grown with minimal decomposition in a 66.7%NH3 and 33.3%N2 gas mixture.


2012 ◽  
Vol 19 (4) ◽  
pp. 28-33 ◽  
Author(s):  
Guo-wei Chang ◽  
Shu-ying Chen ◽  
Qing-chun Li ◽  
Xu-dong Yue ◽  
Guang-can Jin

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