Effect of Green Microstructure and Processing Variables on the Microwave Sintering of Alumina

1990 ◽  
Vol 189 ◽  
Author(s):  
Arindam Dé ◽  
Iftikhar Ahmad ◽  
E. Dow Whitney ◽  
David E. Clark
Keyword(s):  
Particle Size ◽  
Microwave Sintering ◽  
Heating Rates ◽  
Hybrid Heating ◽  
Processing Variables ◽  
Conventional Sintering ◽  
Rapid Sintering ◽  
Temperature Time ◽  
Fast Firing

ABSTRACTThe concept of 'hybrid heating with microwave (MW) energy at 2.45 GHZ.'for ultra rapid sintering of alumina is being introduced. This technique is a combination of MW - materual interaction as well as conventional radiant/conduction mechanisms, and facilitates the attainment of perhaps, the highest possible heating rates in a multimode MW cavity at 2.45 GJZz. (1500ºC in 120 sees.). Rapid sintering of pure.undoped alumina with this novel techniQue culminates in uniform, homogeneous microstructures and mechanical property enhancements vis-a-vis conventional fast firing.The role of green microstructure (particle size) on MW(hybrid) heating and processing variables (temperature, time) on the MW (hybrid) heating phenomena vs. conventional fast firing were investigated. Hybrid heated samples showed accelerated densification with comparable grain sizes when compared with the conventionally fast fired samples. The effectof particle size on the microwave (hybrid) heating phenomena was found to be analogous to conventional sintering.

The Effect of Microwave Sintering Time to PM Aluminum Alloys

2015 ◽  
Vol 754-755 ◽  
pp. 240-244
Author(s):  
M.N. Derman ◽  
Syaza Nabilla Mohd Suhaimi ◽  
Zuraidawani Che Daud
Keyword(s):  
Microwave Sintering ◽  
Microwave Oven ◽  
Solid Particles ◽  
Binding Reaction ◽  
Aluminium Powder ◽  
Sintering Time ◽  
Conventional Sintering ◽  
Rapid Sintering ◽  
Powder Particles ◽  
Solid Liquid

Microwave sintering is new sintering technology method to produce Al alloys. The advantages of this method because of very short sintering time and less production cost compare to conventional sintering. However, the main problems in microwave sintering are required to be controlled sintering time due to rapid sintering mechanism. Therefore the effect of microwave sintering time to PM Aluminium will be studied. The compacted and sintered aluminium powder is placed in a microwave oven at a different period of 5 minutes, 10 minutes, 15 minutes and 20 minutes. Compression of 150 MPa is applied on aluminium powder to form pellets. Palette is shaped to 1cm in diameter and weighs 1g. SiC is placed together with aluminium samples in the microwave for the purpose of absorbing electromagnetic energy and is converted to heat. Results of different period sintering of aluminium pallet production altered physical properties of each sample. For a rapid sintering time, aluminium pallet does not show any binding reaction between powder particles. Whereas, for long microwave sintering period, solid particles phase change into solid-liquid phase caused by the movement and the formation of bonds between particles. Hence, this will be affecting the mechanical properties of the sample material.

Nanostructure Evolution of ZnO in Ultra-fast Microwave Sintering

2011 ◽  
Vol 691 ◽  
pp. 65-71 ◽  
Author(s):  
Rodolfo F. K. Gunnewiek ◽  
Ruth Herta Goldsmith Aliaga Kiminami
Keyword(s):  
Grain Size ◽  
Zinc Oxide ◽  
Grain Growth ◽  
Microwave Sintering ◽  
High Heating Rate ◽  
Heating Rates ◽  
Grain Sizes ◽  
Average Grain Size ◽  
Conventional Sintering ◽  
Holding Temperature

Grain growth is inevitable in the sintering of pure nanopowder zinc oxide. Sintering depend on diffusion kinetics, thus this growth could be controlled by ultra-fast sintering techniques, as microwave sintering. The purpose of this work was to investigate the nanostructural evolution of zinc oxide nanopowder compacts (average grain size of 80 nm) subjected to ultra-rapid microwave sintering at a constant holding temperature of 900°C, applying different heating rates and temperature holding times. Fine dense microstructures were obtained, with controlled grain growth (grain size from 200 to 450nm at high heating rate) when compared to those obtained by conventional sintering (grain size around 1.13µm), which leads to excessively large average final grain sizes.

Effect of Powder Particle Size of Tin Based Alloy Sintered via Hybrid Microwave and Conventional Furnace

2014 ◽  
Vol 575 ◽  
pp. 160-164
Author(s):  
Arshad Azrina ◽  
Shaiful Anuar Ismail ◽  
A. Nurulhuda ◽  
Yacob Suhaila ◽  
Ali Rafidah
Keyword(s):  
Particle Size ◽  
Powder Particle ◽  
Processing Time ◽  
Microwave Sintering ◽  
Powder Particle Size ◽  
Material Synthesis ◽  
Considerable Potential ◽  
Conventional Furnace ◽  
Conventional Sintering ◽  
Lower Porosity

Microwave processing of metal alloy powders have gained considerable potential in the field of material synthesis. This paper aims to present the effect of powder particle size of Tin Based Alloy sintered using different type of heat source. Tin (Sn) based alloy containing two different sizes, 10 μm and 150 μm of Sn powder were successfully sintered using hybrid microwave and conventional sintering. The overall processing time was reduced by about 93% through microwave sintering. The comparative analysis is based on densification parameter, microhardness, microstructures and XRD detected phases of the specimens. All specimen with 10 μm sintered in microwave exhibited 90% of theoretical density while exhibited 86% lower porosity and possessed 30% higher in microhardness value.

Microwave Processing and Sintering of PZT and PLZT Ceramics

1988 ◽  
Vol 124 ◽  
Author(s):  
W. B. Harrison ◽  
M. R. B. Hanson ◽  
B. G. Koepke
Keyword(s):  
Lead Titanate ◽  
Microwave Sintering ◽  
Ferroelectric Properties ◽  
Lead Zirconate ◽  
Microwave Processing ◽  
High Density ◽  
Pzt Ceramics ◽  
Conventional Sintering ◽  
Processing Techniques ◽  
Fast Firing

ABSTRACTMicrowave processing techniques were established for all of the thermal treatment steps necessary to prepare high density PZT and PLZT. The microstructure and ferroelectric properties of the microwave processed materials were compared to conventionally sintered and fast fired PZT. Unique high density, small grain size, PZT and PLZT were obtained by microwave sintering either conventionally or fully microwave processed powders. It was estimated that microwave sintering would use only five percent of the energy used by conventional sintering.The suitability of microwave processing for the production of two modifications (Sr and La) of lead zirconate - lead titanate (PZT) ceramics was investigated in this program. A commercial microwave oven was used to evaluate drying, calcining, binder burnoff, and sintering. These materials were then compared to those produced by fast-firing and conventional sintering methods.

scholarly journals Particle Characteristics’ Influence on FLASH Sintering of Potassium Sodium Niobate: A Relationship with Conduction Mechanisms

Materials ◽  
2021 ◽  
Vol 14 (5) ◽  
pp. 1321
Author(s):  
Ricardo Serrazina ◽  
Camila Ribeiro ◽  
Maria Elisabete Costa ◽  
Luis Pereira ◽  
Paula M. Vilarinho ◽  
...  
Keyword(s):  
Particle Size ◽  
Impurity Content ◽  
Lead Free ◽  
Sintering Process ◽  
Potassium Sodium Niobate ◽  
Volatile Elements ◽  
Flash Sintering ◽  
Conventional Sintering ◽  
Surface Conduction

The considerable decrease in temperature and time makes FLASH sintering a more sustainable alternative for materials processing. FLASH also becomes relevant if volatile elements are part of the material to be processed, as in alkali-based piezoelectrics like the promising lead-free K0.5Na0.5NbO3 (KNN). Due to the volatile nature of K and Na, KNN is difficult to process by conventional sintering. Although some studies have been undertaken, much remains to be understood to properly engineer the FLASH sintering process of KNN. In this work, the effect of FLASH temperature, TF, is studied as a function of the particle size and impurity content of KNN powders. Differences are demonstrated: while the particle size and impurity degree markedly influence TF, they do not significantly affect the densification and grain growth processes. The conductivity of KNN FLASH-sintered ceramics and KNN single crystals (SCs) is compared to elucidate the role of particles’ surface conduction. When particles’ surfaces are not present, as in the case of SCs, the FLASH process requires higher temperatures and conductivity values. These results have implications in understanding FLASH sintering towards a more sustainable processing of lead-free piezoelectrics.

Fibrin Formation: The Role of the Fibrinogen-Fibrin Monomer Complex

1976 ◽  
Vol 36 (01) ◽  
pp. 037-048 ◽  
Author(s):  
Eric P. Brass ◽  
Walter B. Forman ◽  
Robert V. Edwards ◽  
Olgierd Lindan
Keyword(s):  
Particle Size ◽  
Induction Period ◽  
Fibrin Clot ◽  
Clot Formation ◽  
Appreciable Amount ◽  
Buffer System ◽  
Homeostatic Mechanism ◽  
Fibrin Formation ◽  
Fibrin Monomer

SummaryThe process of fibrin formation using highly purified fibrinogen and thrombin was studied using laser fluctuation spectroscopy, a method that rapidly determines particle size in a solution. Two periods in fibrin clot formation were noted: an induction period during which no fibrin polymerization occurred and a period of rapid increase in particle size. Direct measurement of fibrin monomer polymerization and fibrinopeptide release showed no evidence of an induction period. These observations were best explained by a kinetic model for fibrin clot formation incorporating a reversible fibrinogen-fibrin monomer complex. In this model, the complex serves as a buffer system during the earliest phase of fibrin formation. This prevents the accumulation of free polymerizable fibrin monomer until an appreciable amount of fibrinogen has reacted with thrombin, at which point the fibrin monomer level rises rapidly and polymerization proceeds. Clinically, the complex may be a homeostatic mechanism preventing pathological clotting during periods of elevated fibrinogen.

Positive Role of Synthesis Method and Hard Template on the Catalytic Performance of SAPO-34 in Methanol to Olefin Reaction.

2020 ◽  
Vol 23 ◽  
Author(s):  
Sajjad Rimaz ◽  
Reza Katal
Keyword(s):  
Particle Size ◽  
Synthesis Method ◽  
Catalytic Performance ◽  
Hard Template ◽  
Structure Directing Agent ◽  
Positive Role ◽  
Methanol To Olefin ◽  
Dg Method ◽  
Synthesis Procedure

: In the present study, SAPO-34 particles were synthesized using hydrothermal (HT) and dry gel (DG) conversion methods in the presence of diethyl amine (DEA) as an organic structure directing agent (SDA). Carbon nanotubes (CNT) were used as hard template in the synthesis procedure to introduce transport pores into the structures of the synthesized samples. The synthesized samples were characterized with different methods to reveal effects of synthesis method and using hard template on their structure and catalytic performance in methanol to olefin reaction (MTO). DG conversion method results in smaller particle size in comparison with hydrothermal method, resulting in enhancing catalytic performance. On the other side, using CNT in the synthesis procedure with DG method results in more reduction in particle size and formation of hierarchical structure which drastically improves catalytic performance.

Effect of grain size on the vapour phase hydration of monoclinic and triclinic modifications of tricalcium silicate; role of high temperature activation

1991 ◽  
Vol 56 (10) ◽  
pp. 1993-2008
Author(s):  
S. Hanafi ◽  
G. M. S. El-Shafei ◽  
B. Abd El-Hamid
Keyword(s):  
Particle Size ◽  
Vapour Phase ◽  
Tricalcium Silicate ◽  
Active Centers ◽  
Thermally Activated ◽  
Grain Sizes ◽  
Intermediate Size ◽  
Surface Active ◽  
Temperature Activation

The hydration of tricalcium silicate (C3S) with three grain sizes of monoclinic (M) and triclinic (T) modifications and on their thermally activated samples were investigated by exposure to water vapour at 80°C for 60 days. The products were investigated by XRD, TG and N2 adsorption. The smaller the particle size the greater was the hydration for both dried and activated samples from (M). In the activated samples a hydrate with 2θ values of 38.4°, 44.6° and 48.6° could be identified. Hydration increased with particle size for the unactivated (T) samples but after activation the intermediate size exhibited enhanced hydration. Thermal treatment at 950°C of (T) samples increased the surface active centers on the expense of those in the bulk. Changes produced in surface texture upon activation and/or hydration are discussed.

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