Inkjet Printing Graphene-Based Transparent Conductive Films

2014 ◽  
Vol 1699 ◽  
Author(s):  
Pei He ◽  
Brian Derby

ABSTRACTGraphene is a strong contender as a material to replace indium tin oxide as the transparent conductor of choice for electronic applications due to its exceptional electrical and optical properties. In this work, we present a study of graphene oxide (GO) films produced by inkjet-printing. The printed GO films are reduced using hydriodic acid (HI) and acetic acid vapour at low temperature. The reduced GO (rGO) films displayed good optical and electrical properties with a sheet resistance 6.8 kΩ/□ at a transmittance of 80%. In addition, we show that the conductivity of rGO films is related to both the size of individual GO sheets in the ink and the thickness of printed films. The rGO films using large size GO sheets displayed a thickness-independent conductivity of ∼ 4 × 104S/m, while the rGO films using small size GO sheets showed a thickness-independent conductivity of ∼ 1.7 × 104S/m. These properties are comparable to graphene films produced by solvent exfoliation. In summary, we demonstrate a scalable and potentially low-cost technique to produce rGO transparent films and a route to improve the conductivity of rGO films by controlling size of GO sheets in the ink.

2016 ◽  
Vol 4 (16) ◽  
pp. 3546-3554 ◽  
Author(s):  
Andreas Albrecht ◽  
Almudena Rivadeneyra ◽  
Alaa Abdellah ◽  
Paolo Lugli ◽  
José F. Salmerón

Printing technologies to produce conductive films and electronic devices are well established and employ only inexpensive materials and devices as well as rapid post-processing methods.


2013 ◽  
Vol 1547 ◽  
pp. 13-20 ◽  
Author(s):  
Mei Fang ◽  
Wolfgang Voit ◽  
Yan Wu ◽  
Lyubov Belova ◽  
K.V. Rao

ABSTRACTDirect printing of functional oxide thin films could provide a new route to low-cost, efficient and scalable fabrications of electronic devices. One challenge that remains open is to design the inks with long term stability for effective deposition of specific oxide materials of industrial importance. In this paper, we introduce a reliable method of producing stable inks for ‘in-situ’ deposition of oxide thin films by inkjet printing. The inks were prepared from metal-acetates solutions and printed on a variety of substrates. The acetate precursors were decomposed into oxide films during the subsequent calcination process to achieve the ‘in-situ’ deposition of the desired oxide films directly on the substrate. By this procedure we have obtained room temperature contamination free ferromagnetic spintronic materials like Fe doped MgO and ZnO films from their acetate(s) solutions. We find that the origin of magnetism in ZnO, MgO and their Fe-doped films to be intrinsic. For a 28 nm thick film of Fe-doped ZnO we observe an enhanced magnetic moment of 16.0 emu/cm3 while it is 5.5 emu/cm3 for the doped MgO film of single pass printed. The origin of magnetism is attributed to cat-ion vacancies. We have also fabricated highly transparent indium tin oxide films with a transparency >95% both in the visible and IR range which is rather unique compared to films grown by any other technique. The films have a nano-porous structure, an added bonus from inkjetting that makes such films advantageous for a broad range of applications.


Micromachines ◽  
2021 ◽  
Vol 12 (8) ◽  
pp. 889
Author(s):  
Yadong Liu ◽  
Juxuan Xie ◽  
Lihui Liu ◽  
Kai Fan ◽  
Zixuan Zhang ◽  
...  

Recently, inkjet printing technology has attracted much attention due to the advantages of drop-on-demand deposition, low-cost and large-area production for organic light-emitting diode (OLED) displays. However, there are still some problems in industrial production and practical application, such as the complexity of ink modulation, high-quality films with homogeneous morphology, and the re-dissolution phenomenon at interfaces. In this work, a printable poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOT:PSS) ink is developed and obtains an adjustable viscosity. Finally, a patterned PEDOT:PSS electrode is fabricated by inkjet printing, and achieves a high conductivity of 1213 S/cm, a transparency of 86.8% and a uniform morphology without coffee-ring effect. Furthermore, the vacuum-evaporated and solution-processed OLEDs are fabricated based on this electrode and demonstrate a current efficiency of 61 cd/A, which is comparable to that of the indium tin oxide counterpart. This work confirms the feasibility of inkjet printing technology to prepare patterned electrodes and expects that it can be used to fabricate highly efficient optoelectronic devices.


2020 ◽  
Vol 64 (5) ◽  
pp. 50405-1-50405-5
Author(s):  
Young-Woo Park ◽  
Myounggyu Noh

Abstract Recently, the three-dimensional (3D) printing technique has attracted much attention for creating objects of arbitrary shape and manufacturing. For the first time, in this work, we present the fabrication of an inkjet printed low-cost 3D temperature sensor on a 3D-shaped thermoplastic substrate suitable for packaging, flexible electronics, and other printed applications. The design, fabrication, and testing of a 3D printed temperature sensor are presented. The sensor pattern is designed using a computer-aided design program and fabricated by drop-on-demand inkjet printing using a magnetostrictive inkjet printhead at room temperature. The sensor pattern is printed using commercially available conductive silver nanoparticle ink. A moving speed of 90 mm/min is chosen to print the sensor pattern. The inkjet printed temperature sensor is demonstrated, and it is characterized by good electrical properties, exhibiting good sensitivity and linearity. The results indicate that 3D inkjet printing technology may have great potential for applications in sensor fabrication.


Electronics ◽  
2021 ◽  
Vol 10 (2) ◽  
pp. 140
Author(s):  
Lichen Liu ◽  
Ziping Cao ◽  
Min Chen ◽  
Jun Jiang

This paper reports the fabrication and characterization of (Bi0.48Sb1.52)Te3 thick films using a tape casting process on glass substrates. A slurry of thermoelectric (Bi0.48Sb1.52)Te3 was developed and cured thick films were annealed in a vacuum chamber at 500–600 °C. The microstructure of these films was analyzed, and the Seebeck coefficient and electric conductivity were tested. It was found that the subsequent annealing process must be carefully designed to achieve good thermoelectric properties of these samples. Conductive films were obtained after annealing and led to acceptable thermoelectric performance. While the properties of these initial materials are not at the level of bulk materials, this work demonstrates that the low-cost tape casting technology is promising for fabricating thermoelectric modules for energy conversion.


Nanomaterials ◽  
2021 ◽  
Vol 11 (6) ◽  
pp. 1489
Author(s):  
Bhaskar Parida ◽  
Saemon Yoon ◽  
Dong-Won Kang

Materials and processing of transparent electrodes (TEs) are key factors to creating high-performance translucent perovskite solar cells. To date, sputtered indium tin oxide (ITO) has been a general option for a rear TE of translucent solar cells. However, it requires a rather high cost due to vacuum process and also typically causes plasma damage to the underlying layer. Therefore, we introduced TE based on ITO nanoparticles (ITO-NPs) by solution processing in ambient air without any heat treatment. As it reveals insufficient conductivity, Ag nanowires (Ag-NWs) are additionally coated. The ITO-NPs/Ag-NW (0D/1D) bilayer TE exhibits a better figure of merit than sputtered ITO. After constructing CsPbBr3 perovskite solar cells, the device with 0D/1D TE offers similar average visible transmission with the cells with sputtered ITO. More interestingly, the power conversion efficiency of 0D/1D TE device was 5.64%, which outperforms the cell (4.14%) made with sputtered-ITO. These impressive findings could open up a new pathway for the development of low-cost, translucent solar cells with quick processing under ambient air at room temperature.


2021 ◽  
Author(s):  
Yuxin Tang ◽  
Wanying Yin ◽  
Yue Huang ◽  
Ganghua Zhang ◽  
Qingbiao Zhao ◽  
...  

Silver nanowires (AgNWs) network has shown great promise as transparent conductive films (TCFs) due to its excellent optoelectronic performance. In order to replace indium tin oxide (ITO), considerable intricate methods...


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Jose Recatala-Gomez ◽  
Pawan Kumar ◽  
Ady Suwardi ◽  
Anas Abutaha ◽  
Iris Nandhakumar ◽  
...  

Abstract The best known thermoelectric material for near room temperature heat-to-electricity conversion is bismuth telluride. Amongst the possible fabrication techniques, electrodeposition has attracted attention due to its simplicity and low cost. However, the measurement of the thermoelectric properties of electrodeposited films is challenging because of the conducting seed layer underneath the film. Here, we develop a method to directly measure the thermoelectric properties of electrodeposited bismuth telluride thin films, grown on indium tin oxide. Using this technique, the temperature dependent thermoelectric properties (Seebeck coefficient and electrical conductivity) of electrodeposited thin films have been measured down to 100 K. A parallel resistor model is employed to discern the signal of the film from the signal of the seed layer and the data are carefully analysed and contextualized with literature. Our analysis demonstrates that the thermoelectric properties of electrodeposited films can be accurately evaluated without inflicting any damage to the films.


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