A Novel Method for Low-Resistivity Metal-Interconnection by Using Metallic Functional Liquids and Catalytically Generated Hydrogen Atoms

2012 ◽  
Vol 1401 ◽  
Author(s):  
Nguyen T. T. Kieu ◽  
Keisuke Ohdaira ◽  
Tatsuya Shimoda ◽  
Hideki Matsumura
Keyword(s):  
Photoelectron Spectroscopy ◽  
High Speed ◽  
Uv Light ◽  
Low Cost ◽  
Plastic Substrate ◽  
Hydrogen Atoms ◽  
Ag Nps ◽  
Low Resistivity ◽  
Novel Method ◽  
Semiconductor Chips

ABSTRACTA novel method to make low-resistivity metal lines in assembled silicon (Si) integrated circuit (IC) chips or other semiconductor chips with high-speed and low-cost is demonstrated. In the method, functional silver (Ag)-liquid (Ag-ink) which contains Ag nanoparticles (NPs) in organic solution is used to draw metal-lines in trenches formed on a plastic substrate by imprint technology. Surface energy of trenches is modified by exposing the substrate to ultra-violet (UV) light with the purpose of concentrating the functional Ag-ink into trenches by capillary effect in order to connect with electrodes of Si chips. The resistivity of such metal-lines can be lowered to 4×10-6 Ωcm by exposing the Ag metal-lines to hydrogen (H) atoms generated by catalytic cracking reaction with a heated tungsten catalyzer. X-ray photoelectron spectroscopy (XPS) proves that H atoms can remove organic compounds surrounding Ag NPs, resulting in the low-temperature sintering of NPs as confirmed by scanning electron microscopy (SEM). The method is promising for low-cost fabricating of IC cards or other electronic devices utilizing assemble of many semiconductor chips.

Phase-Change Heat Transfer Measurements Using Temperature-Sensitive Paints

2017 ◽  
Vol 140 (3) ◽  
Author(s):  
Husain Al Hashimi ◽  
Caleb F. Hammer ◽  
Michel T. Lebon ◽  
Dan Zhang ◽  
Jungho Kim
Keyword(s):  
Heat Transfer ◽  
High Speed ◽  
Uv Light ◽  
Flow Boiling ◽  
Low Cost ◽  
Data Interpretation ◽  
Temperature Sensitive ◽  
Time Resolved ◽  
Light Emitting ◽  
Phase Change Heat Transfer

Techniques based on temperature-sensitive paints (TSP) to measure time-resolved temperature and heat transfer distributions at the interface between a wall and fluid during pool and flow boiling are described. The paints are excited using ultraviolet (UV) light emitting diodes (LEDs), and changes in fluorescence intensity are used to infer local temperature differences across a thin insulator from which heat flux distribution is obtained. Advantages over infrared (IR) thermometry include the ability to use substrates that are opaque to IR (e.g., glass, plexiglass and plastic films), use of low-cost optical cameras, no self-emission from substrates to complicate data interpretation, high speed, and high spatial resolution. TSP-based methods to measure wall heat transfer distributions are validated and then demonstrated for pool and flow boiling.

scholarly journals Novel Enzyme-Free Multifunctional Bentonite/Polypyrrole/Silver Nanocomposite Sensor for Hydrogen Peroxide Detection over a Wide pH Range

Sensors ◽  
2019 ◽  
Vol 19 (20) ◽  
pp. 4442 ◽  
Author(s):  
Khouloud Jlassi ◽  
Mostafa H. Sliem ◽  
Kamel Eid ◽  
Igor Krupa ◽  
Mohamed M. Chehimi ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Ag Nanoparticles ◽  
Rational Design ◽  
Uv Light ◽  
Low Cost ◽  
Current Response ◽  
Ag Nps ◽  
Hydrogen Peroxide Detection ◽  
Wide Ph Range ◽  
Ph Range

Precise designs of low-cost and efficient catalysts for the detection of hydrogen peroxide (H2O2) over wide ranges of pH are important in various environmental applications. Herein, a versatile and ecofriendly approach is presented for the rational design of ternary bentonite-silylpropyl-polypyrrole/silver nanoarchitectures (denoted as BP-PS-PPy/Ag) via the in-situ photo polymerization of pyrrole with salinized bentonite (BP-PS) in the presence of silver nitrate. The Pyrrolyl-functionalized silane (PS) is used as a coupling agent for tailoring the formation of highly exfoliated BP-PS-PPy sheet-like nanostructures ornamented with monodispersed Ag nanoparticles (NPs). Taking advantage of the combination between the unique physicochemical properties of BP-PS-PPy and the outstanding catalytic merits of Ag nanoparticles (NPs), the as-synthesized BP-PS-PPy/Ag shows a superior electrocatalytic reduction and high-detection activity towards H2O2 under different pH conditions (from 3 to 10). Intriguingly, the UV-light irradiation significantly enhances the electroreduction activity of H2O2 substantially, compared with the dark conditions, due to the high photoelectric response properties of Ag NPs. Moreover, BP-PS-PPy/Ag achived a quick current response with a detection limit at 1 μM within only 1 s. Our present approach is green, facile, scalable and renewable.

Development and production experience of the multilayer curtain-coated linerboard of Ji’an PM No. 3,

TAPPI Journal ◽  
2014 ◽  
Vol 13 (2) ◽  
pp. 17-25
Author(s):  
JUNMING SHU ◽  
ARTHAS YANG ◽  
PEKKA SALMINEN ◽  
HENRI VAITTINEN
Keyword(s):  
Titanium Dioxide ◽  
High Speed ◽  
Food Packaging ◽  
Production Efficiency ◽  
Positive Impact ◽  
Low Cost ◽  
Board Structure ◽  
Flexographic Printing ◽  
Curtain Coating ◽  
Coating Formulations

The Ji’an PM No. 3 is the first linerboard machine in China to use multilayer curtain coating technology. Since successful startup at the end of 2011, further development has been carried out to optimize running conditions, coating formulations, and the base paper to provide a product with satisfactory quality and lower cost to manufacture. The key challenges include designing the base board structure for the desired mechanical strength, designing the surface properties for subsequent coating operations, optimizing the high-speed running of the curtain coater to enhance production efficiency, minimizing the amount of titanium dioxide in the coating color, and balancing the coated board properties to make them suitable for both offset and flexographic printing. The pilot and mill scale results show that curtain coating has a major positive impact on brightness, while smoothness is improved mainly by the blade coating and calendering conditions. Optimization of base board properties and the blade + curtain + blade concept has resulted in the successful use of 100% recycled fiber to produce base board. The optical, mechanical, and printability properties of the final coated board meet market requirements for both offset and flexographic printing. Machine runnability is excellent at the current speed of 1000 m/min, and titanium dioxide has been eliminated in the coating formulations without affecting the coating coverage. A significant improvement in the total cost of coated white liner production has been achieved, compared to the conventional concept of using virgin fiber in the top ply. Future development will focus on combining low cost with further quality improvements to make linerboard suitable for a wider range of end-use applications, including frozen-food packaging and folding boxboard.

Low-Cost High-Speed Techniques for Real-Time Simulation of Power Electronic Systems

2007 ◽  
Author(s):  
R. E. Crosbie ◽  
J. J. Zenor ◽  
R. Bednar ◽  
D. Word ◽  
N. G. Hingorani
Keyword(s):  
Real Time ◽  
High Speed ◽  
Low Cost ◽  
Electronic Systems ◽  
Power Electronic ◽  
Real Time Simulation ◽  
Time Simulation

High-speed electro-optic switch using buried electrode structure in polymer Mach–Zehnder waveguide

2016 ◽  
Vol 30 (06) ◽  
pp. 1650063 ◽  
Author(s):  
Jingwen Sun ◽  
Jian Sun ◽  
Yunji Yi ◽  
Lucheng Qv ◽  
Shiqi Sun ◽  
...  
Keyword(s):  
Insertion Loss ◽  
Rise Time ◽  
High Speed ◽  
Low Cost ◽  
Characteristic Parameters ◽  
Electrode Structure ◽  
Processing Cost ◽  
Electro Optic ◽  
Disperse Red 1 ◽  
Excellent Photostability

A low-cost and high-speed electro-optic (EO) switch using the guest–host EO material Disperse Red 1/Polymethyl Methacrylate (DR1/PMMA) was designed and fabricated. The DR1/PMMA material presented a low processing cost, an excellent photostability and a large EO coefficient of 13.1 pm/V. To improve the performance of the switch, the in-plane buried electrode structure was introduced in the polymer Mach–Zehnder waveguide to improve the poling and modulating efficiency. The characteristic parameters of the waveguide and the electrodes were carefully designed and the fabrication process was strictly controlled. Under 1550 nm, the insertion loss of the device was 12.7 dB. The measured switching rise time and fall time of the switch were 50.00 ns and 54.29 ns, respectively.

scholarly journals Photocatalytic reduction of graphene oxide with cuprous oxide film under UV-vis irradiation

2020 ◽  
Vol 59 (1) ◽  
pp. 207-214 ◽  
Author(s):  
Yao Wang ◽  
Jianqing Feng ◽  
Lihua Jin ◽  
Chengshan Li
Keyword(s):  
Graphene Oxide ◽  
Photoelectron Spectroscopy ◽  
Low Cost ◽  
Photocatalytic Reduction ◽  
Force Microscopy ◽  
Atomic Force ◽  
Reduced Graphene ◽  
Reduction Efficiency ◽  
Metal Organic ◽  
Reduction Effect

AbstractWe have grown Cu2O films by different routes including self-oxidation and metal-organic deposition (MOD). The reduction efficiency of Cu2O films on graphene oxide (GO) synthesized by modified Hummer’s method has been studied. Surface morphology and chemical state of as-prepared Cu2O film and GO sheets reduced at different conditions have also been investigated using atomic force microscopy (AFM) and x-ray photoelectron spectroscopy (XPS). Results show that self-oxidation Cu2O film is more effective on phtocatalytic reduction of GO than MOD-Cu2O film. Moreover, reduction effect of self-oxidation Cu2O film to GO is comparable to that of environmental-friendly reducing agent of vitamin C. The present results offer a potentially eco-friendly and low-cost approach for the manufacture of reduced graphene oxide (RGO) by photocatalytic reduction.

scholarly journals Deposition of Zinc Oxide Coatings on Wood Surfaces Using the Solution Precursor Plasma Spraying Process

Coatings ◽  
2021 ◽  
Vol 11 (2) ◽  
pp. 183
Author(s):  
Ghiath Jnido ◽  
Gisela Ohms ◽  
Wolfgang Viöl
Keyword(s):  
Zinc Oxide ◽  
Ftir Spectroscopy ◽  
Photoelectron Spectroscopy ◽  
Color Change ◽  
Uv Light ◽  
Beech Wood ◽  
Nitrate Solution ◽  
Ftir Spectra ◽  
Solution Precursor ◽  
Wood Surfaces

In the present work, the solution precursor plasma spray (SPPS) process was used to deposit zinc oxide (ZnO) coatings on wood surfaces using zinc nitrate solution as precursor to improve the hydrophobicity and the color stability of European beech wood under exposure to ultraviolet (UV) light. The surface morphology and topography of the wood samples and the coatings were characterized by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The formation of ZnO was detected with the help of X-ray photoelectron spectroscopy (XPS) and by Fourier transform infrared (FTIR) spectroscopy. The FTIR spectra of the coated samples showed the typical Zn–O band at 445 cm−1. According to the XPS analysis, the coatings consist of two different Zn-containing species: ZnO and Zn(OH)2. Variation of the deposition parameters showed that the most significant parameters affecting the microstructure of the coating were the solution concentration, the deposition scan speed, and carrier gas flow rate. The wettability behaviors of the coated wood were evaluated by measuring the water contact angle (WCA). The coatings that completely covered the wood substrates showed hydrophobic behaviors. UV-protection of wood surfaces after an artificial UV light irradiation was evaluated by color measurements and FTIR spectroscopy. The ZnO-coated wood surfaces were more resistant to color change during UV radiation exposure. The total color change decreased up to 60%. Additionally, the FTIR spectra showed that the wood surfaces coated with ZnO had more stability. The carbonyl groups formation and C=C-bonds consumption were significantly lower.

scholarly journals Performance Improvement of ZnSnO Thin-Film Transistors with Low-Temperature Self-Combustion Reaction

Electronics ◽  
2021 ◽  
Vol 10 (9) ◽  
pp. 1099
Author(s):  
Ye-Ji Han ◽  
Se Hyeong Lee ◽  
So-Young Bak ◽  
Tae-Hee Han ◽  
Sangwoo Kim ◽  
...  
Keyword(s):  
Thin Film ◽  
Photoelectron Spectroscopy ◽  
Large Scale ◽  
Low Cost ◽  
Thermal Analyses ◽  
Thin Film Transistor ◽  
Sol Gel ◽  
Annealing Temperatures ◽  
Zinc Tin Oxide ◽  
Thermal Limitation

Conventional sol-gel solutions have received significant attention in thin-film transistor (TFT) manufacturing because of their advantages such as simple processing, large-scale applicability, and low cost. However, conventional sol-gel processed zinc tin oxide (ZTO) TFTs have a thermal limitation in that they require high annealing temperatures of more than 500 °C, which are incompatible with most flexible plastic substrates. In this study, to overcome the thermal limitation of conventional sol-gel processed ZTO TFTs, we demonstrated a ZTO TFT that was fabricated at low annealing temperatures of 350 °C using self-combustion. The optimized device exhibited satisfactory performance, with μsat of 4.72 cm2/V∙s, Vth of −1.28 V, SS of 0.86 V/decade, and ION/OFF of 1.70 × 106 at a low annealing temperature of 350 °C for one hour. To compare a conventional sol-gel processed ZTO TFT with the optimized device, thermogravimetric and differential thermal analyses (TG-DTA) and X-ray photoelectron spectroscopy (XPS) were implemented.

scholarly journals Synthesis of Exosome-Based Fluorescent Gold Nanoclusters for Cellular Imaging Applications

2021 ◽  
Vol 22 (9) ◽  
pp. 4433
Author(s):  
Eun Sung Lee ◽  
Byung Seok Cha ◽  
Seokjoon Kim ◽  
Ki Soo Park
Keyword(s):  
Photoelectron Spectroscopy ◽  
Low Cost ◽  
Stokes Shift ◽  
Gold Nanoclusters ◽  
Human Colon ◽  
Cellular Imaging ◽  
Metal Nanoclusters ◽  
Human Colon Cancer ◽  
X Ray ◽  
High Concentrations

In recent years, fluorescent metal nanoclusters have been used to develop bioimaging and sensing technology. Notably, protein-templated fluorescent gold nanoclusters (AuNCs) are attracting interest due to their excellent fluorescence properties and biocompatibility. Herein, we used an exosome template to synthesize AuNCs in an eco-friendly manner that required neither harsh conditions nor toxic chemicals. Specifically, we used a neutral (pH 7) and alkaline (pH 11.5) pH to synthesize two different exosome-based AuNCs (exo-AuNCs) with independent blue and red emission. Using field-emission scanning electron microscopy, energy dispersive X-ray microanalysis, nanoparticle tracking analysis, and X-ray photoelectron spectroscopy, we demonstrated that AuNCs were successfully formed in the exosomes. Red-emitting exo-AuNCs were found to have a larger Stokes shift and a stronger fluorescence intensity than the blue-emitting exo-AuNCs. Both exo-AuNCs were compatible with MCF-7 (human breast cancer), HeLa (human cervical cancer), and HT29 (human colon cancer) cells, although blue-emitting exo-AuNCs were cytotoxic at high concentrations (≥5 mg/mL). Red-emitting exo-AuNCs successfully stained the nucleus and were compatible with membrane-staining dyes. This is the first study to use exosomes to synthesize fluorescent nanomaterials for cellular imaging applications. As exosomes are naturally produced via secretion from almost all types of cell, the proposed method could serve as a strategy for low-cost production of versatile nanomaterials.

scholarly journals A Facile and Green Synthesis of a MoO2-Reduced Graphene Oxide Aerogel for Energy Storage Devices

Materials ◽  
2020 ◽  
Vol 13 (3) ◽  
pp. 594 ◽  
Author(s):  
Mara Serrapede ◽  
Marco Fontana ◽  
Arnaud Gigot ◽  
Marco Armandi ◽  
Glenda Biasotto ◽  
...  
Keyword(s):  
Graphene Oxide ◽  
Reduced Graphene Oxide ◽  
Photoelectron Spectroscopy ◽  
Electrochemical Impedance ◽  
Chemical Reduction ◽  
Low Cost ◽  
Xps Analysis ◽  
3D Scaffold ◽  
Energy Storage Devices ◽  
Reduced Graphene

A simple, low cost, and “green” method of hydrothermal synthesis, based on the addition of l-ascorbic acid (l-AA) as a reducing agent, is presented in order to obtain reduced graphene oxide (rGO) and hybrid rGO-MoO2 aerogels for the fabrication of supercapacitors. The resulting high degree of chemical reduction of graphene oxide (GO), confirmed by X-Ray Photoelectron Spectroscopy (XPS) analysis, is shown to produce a better electrical double layer (EDL) capacitance, as shown by cyclic voltammetric (CV) measurements. Moreover, a good reduction yield of the carbonaceous 3D-scaffold seems to be achievable even when the precursor of molybdenum oxide is added to the pristine slurry in order to get the hybrid rGO-MoO2 compound. The pseudocapacitance contribution from the resulting embedded MoO2 microstructures, was then studied by means of CV and electrochemical impedance spectroscopy (EIS). The oxidation state of the molybdenum in the MoO2 particles embedded in the rGO aerogel was deeply studied by means of XPS analysis and valuable information on the electrochemical behavior, according to the involved redox reactions, was obtained. Finally, the increased stability of the aerogels prepared with l-AA, after charge-discharge cycling, was demonstrated and confirmed by means of Field Emission Scanning Electron Microscopy (FESEM) characterization.

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