Interfacial Layer Growth Condition Dependent Electrical Conduction in HfO2/SiO2 Heterostructured thin films

2012 ◽  
Vol 1397 ◽  
Author(s):  
Santosh K. Sahoo ◽  
D. Misra

ABSTRACTThe electrical conduction mechanism contributing to the leakage current at different field regions has been studied in this work. The current-voltage (I-V) measurement of TiN/HfO2/SiO2/P-Si nMOS capacitor has been taken for two different interfacial layer (SiO2) growth conditions such as in situ steam grown (ISSG) and chemical processes. It is observed that Poole-Frenkel mechanism is the dominant conduction mechanism in high field region whereas Ohmic conduction is dominant in the low field region. Also it is seen that the gate leakage current is reduced for the devices having chemically grown interfacial layer compared to that of ISSG devices. Both trap energy level (ϕt) and activation energy (Ea) increase in the chemically grown interfacial layer devices for the Poole-Frenkel and Ohmic conduction mechanisms respectively in comparison to ISSG devices. Trap energy level (ϕt) of ~ 0.2 eV, obtained from Poole-Frenkel mechanism indicates that the doubly ionized oxygen vacancies (V2-) are the active defects and are contributing to the leakage current in these devices.

2006 ◽  
Vol 20 (06) ◽  
pp. 315-320
Author(s):  
YONG K. LEE

Leakage current of fluorinated polyimide film was measured as function of time, electric field and sample temperature. Several existing conduction and charge transport mechanism was fit to the experimental results. It was concluded that the bulk limited Pool–Frenkel conduction mechanism was likely to dominate for the leakage current at high electric field (higher than 1 MV/cm) and Ohmic conduction was main conduction mechanism at low electric field (lower than 1 MV/cm).


2013 ◽  
Vol 1547 ◽  
pp. 95-102
Author(s):  
Santosh K. Sahoo ◽  
Rakhi P. Patel ◽  
Colin A. Wolden

ABSTRACTHybrid alumina-silicone nanolaminate films were synthesized by plasma enhanced chemical vapor deposition (PECVD) process. PECVD allows digital control over nanolaminate construction, and may be performed at low temperature for compatibility with flexible substrates. These materials are being considered as dielectrics for application such as capacitors in thin film transistors and memory devices. In this work, we present the temperature dependent current versus voltage (I-V) measurements of the nanolaminate dielectrics in the range of 200- 310 K to better asses their potential in these applications. Various models are used to know the different conduction mechanisms contributing to the leakage current in these nanolaminate films. It is observed that space charge limited current (SCLC) mechanism is the dominant conduction process in the high field region whereas Ohmic conduction process is contributing to the leakage current in the low field region. The shallow electron trap level energy (Et) of 0.16 eV is responsible for SCLC mechanism whereas for Ohmic conduction process the activation energy (Ea) for electrons is about 0.22 eV. An energy band diagram is given to explain the dominance of various conduction mechanisms in different field regions in these nanolaminate films.


2014 ◽  
Vol 31 (10) ◽  
pp. 106103
Author(s):  
Chang Liu ◽  
Wen-Jie Yu ◽  
Bo Zhang ◽  
Zhong-Ying Xue ◽  
Wang-Ran Wu ◽  
...  

2013 ◽  
Vol 1547 ◽  
pp. 53-60
Author(s):  
Santosh K. Sahoo ◽  
H. Bakhru ◽  
Sumit Kumar ◽  
D. Misra ◽  
Colin A. Wolden ◽  
...  

ABSTRACTBa0.8Sr0.2TiO3/ZrO2 heterostructured thin films with different individual layer ZrO2 thicknesses are deposited on Pt/Ti/SiO2/Si substrates by a sol-gel process. The current versus voltage (I-V) measurements of the above multilayered thin films in metal-insulator-metal (MIM) device structures are taken in the temperature range of 310 to 410K. The electrical conduction mechanisms contributing to the leakage current at different field regions have been studied in this work. Various models are used to know the different conduction mechanisms responsible for the leakage current in these devices. It is observed that Poole-Frenkel mechanism is the dominant conduction process in the high field region with deep electron trap energy levels (φt) whereas space charge limited current (SCLC) mechanism is contributing to the leakage current in the medium field region with shallow electron trap levels (Et). Also, it is seen that Ohmic conduction process is the dominant mechanism in the low field region having activation energy (Ea) for the electrons. The estimated trap level energy varies from 0.2 to 1.31 eV for deep level traps and from 0.08 to 0.18 eV for shallow level traps whereas the activation energy for electrons in ohmic conduction process varies from 0.05 to 0.17 eV with the increase of ZrO2 sub layer thickness. An energy band diagram is given to explain the dominance of the various leakage mechanisms in different field regions for these heterostructured thin films.


2008 ◽  
Vol 600-603 ◽  
pp. 759-762
Author(s):  
Rajat Mahapatra ◽  
Alton B. Horsfall ◽  
Nicolas G. Wright

In this study we report interface and carrier transport behaviour in Al/HfO2/SiO2/SiC MIS structure. The density of the interface states (Dit) and the oxide trapped charges (Not) are found to be ~7 x 1011 eV-1cm-2 @ Ec-Et = 0.2 eV, and ~ 4.8 x 1011 cm-2. The temperature dependencies on gate current density are explored to study the different charge transport mechanisms through the HfO2-based dielectric stack on 4H-SiC. In the low voltage region, the conduction mechanism is controlled by a space charge limited or electronic hopping conduction process. Beyond this region (1.25 MV/cm <E <2.45MV/cm), leakage current consists of combination of Pool-Frenkel (PF) and Schottky emission The trap energy level is found to be ~0.6 eV. In the higher field region (> 2.5 MV/cm), and at higher temperatures Schottky emission (SE) fits the data very well. The barrier height is found to be ~1.5 eV, which is higher than the value for just HfO2 on SiC


2008 ◽  
Vol 388 ◽  
pp. 201-204 ◽  
Author(s):  
Makito Nakano ◽  
Akira Saito ◽  
Nobuyuki Wada

The electrical degradation mechanisms of BaTiO3-based ceramics were investigated by measuring the dependence of leakage current on high electric fields. Before the degradation, the leakage current predominately obeyed Ohm’s law and Poole-Frenkel relation. As the degradation progressed, the Poole-Frenkel emission current increased. Moreover, the total current at the high electric fields also comprised Schottky emissions between cathodes and dielectric layers.


2017 ◽  
Vol 56 (10) ◽  
pp. 102201 ◽  
Author(s):  
Shigekazu Okumura ◽  
Keizo Kinoshita ◽  
Junichi Fujikata ◽  
Takasi Simoyama ◽  
Hideki Ono ◽  
...  

1994 ◽  
Vol 08 (25) ◽  
pp. 1591-1595
Author(s):  
M.H. CHOHAN ◽  
H. MAHMOOD ◽  
FARHANA SHAH

A study of the electrical conduction mechanism in polyimide (Kapton) films has been made. The measurements were carried out on films of 12.5 and 25 µm thick in the voltage range of 100 to 3000 V and in the temperature range of 300 to 373 K. The conduction mechanism in the low field region is a hopping type process while the high field phenomenon is a Poole-Frenkel behavior. The activation energy is about 1.1 eV at 100 V and 0.8 eV at 3000 V.


1999 ◽  
Vol 567 ◽  
Author(s):  
Renee Nieh ◽  
Wen-Jie Qi ◽  
Yongjoo Jeon ◽  
Byoung Hun Lee ◽  
Aaron Lucas ◽  
...  

ABSTRACTBa0.5Sr0.5TiO3 (BST) is one of the high-k candidates for replacing SiO2 as the gate dielectric in future generation devices. The biggest obstacle to scaling the equivalent oxide thickness (EOT) of BST is an interfacial layer, SixOy, which forms between BST and Si. Nitrogen (N2) implantation into the Si substrate has been proposed to reduce the growth of this interfacial layer. In this study, capacitors (Pt/BST/Si) were fabricated by depositing thin BST films (50Å) onto N2 implanted Si in order to evaluate the effects of implant dose and annealing conditions on EOT. It was found that N2 implantation reduced the EOT of RF magnetron sputtered and Metal Oxide Chemical Vapor Deposition (MOCVD) BST films by ∼20% and ∼33%, respectively. For sputtered BST, an implant dose of 1×1014cm−;2 provided sufficient nitrogen concentration without residual implant damage after annealing. X-ray photoelectron spectroscopy data confirmed that the reduction in EOT is due to a reduction in the interfacial layer growth. X-ray diffraction spectra revealed typical polycrystalline structure with (111) and (200) preferential orientations for both films. Leakage for these 50Å BST films is on the order of 10−8 to 10−5 A/cm2—lower than oxynitrides with comparable EOTs.


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