Supramolecular Polymers

MRS Bulletin ◽  
2000 ◽  
Vol 25 (4) ◽  
pp. 49-53 ◽  
Author(s):  
Luc Brunsveld ◽  
Brigitte J. B. Folmer ◽  
E. W. Meijer
Keyword(s):  
20Th Century ◽  
Smart Materials ◽  
Biomedical Applications ◽  
Science And Technology ◽  
Polymeric Materials ◽  
Supramolecular Polymers ◽  
New Materials ◽  
Scientific Challenge

What started as a scientific challenge roughly 10 years ago has become a technological reality today, as materials from supramolecular polymers and their many applications as smart materials have emerged. Synthetic polymeric materials are among the most important classes of new materials introduced in the 20th century. They are primarily used for construction, but electronic and biomedical applications are also at the forefront of science and technology.

Preface

2009 ◽  
Vol 81 (3) ◽  
pp. iv
Author(s):  
Poonam Tandon
Keyword(s):  
Smart Materials ◽  
Materials Science ◽  
Science And Technology ◽  
Uttar Pradesh ◽  
Polymeric Materials ◽  
Scientific Work ◽  
Theoretical Physics ◽  
Structure Property ◽  
Research Award ◽  
Materials Research

The POLYCHAR 16: World Forum on Advanced Materials, organized by the University of Lucknow, was held from 17 to 21 February 2008 in the capital of the state of Uttar Pradesh, India. The annual POLYCHAR conferences have been sponsored by IUPAC for several years and are known for combining the broad field of materials sciences with a clear focus on polymeric materials (the name "POLYCHAR" is derived from the term "polymer characterization"). POLYCHAR 16 was supported by many scientific associations and industries such as IUPAC, Abdus Salam International Center for Theoretical Physics (ICTP) (Trieste, Italy), Indian Space Research Organization (ISRO), Department of Biotechnology (DBT) (India), Council of Scientific and Industrial Research (CSIR) (India), Reliance Industries Ltd. (India), Department of Science and Technology (India), Indian Council for Medical Research (ICMR), Indian National Science Academy (INSA), Uttar Pradesh Council of Science and Technology (UPCST) (India), Lucknow Chapter, Materials Research Society of India (MRSI), and University of Lucknow.As in past years, POLYCHAR puts emphasis on the quality of research presented - in contrast to maximizing the number of participants. The areas covered include nanomaterials and smart materials; natural and biodegradable materials and recycling; materials synthesis; polymers for energy; rheology, solutions, and processing; mechanical properties and performance; characterization and structure-property relationships; biomaterials and tissue engineering; dielectric and electrical properties; surfaces, interfaces, and tribology; and predictive methods. Symptomatically, the number of papers on "green" science was higher than at POLYCHAR 15 last year in Búzios, Rio de Janeiro.There were a total of 292 registered participants from 35 countries (Austria, Bangladesh, Belgium, Brazil, China, Colombia, Croatia, Czech Republic, Egypt, Fiji, UK, France, Germany, India, Iran, Israel, Japan, Korea, Kuwait, Mauritius, Malaysia, Mexico, Nepal, Netherlands, New Zealand, Poland, Portugal, Russia, Sri Lanka, Slovakia, South Africa, Ukraine, USA, Uzbekistan, and Venezuela). This reflects the philosophy of POLYCHAR to provide an international forum to encourage young scientists and advanced students to present their scientific work and give them the opportunity to meet with colleagues and well-known scientists to discuss their results, exchange experiences, and make new contacts, in particular, international ones. Many industrial contacts and much international cooperation with exchange of students and scientists have resulted from this and earlier POLYCHAR meetings.This conference volume represents only a small fraction of the multitude of contributions from different parts of materials science - 48 oral contributions and 170 posters. Many of the contributions have review character, some represent excellent original contributions. Only a small number could be selected for this volume because of the limited space that is available. All this was possible with the sponsorship of IUPAC. Highlights of the conference were the Paul J. Flory Research Award (ex aequo) to Prof. Jiasong He, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China; the International Materials Research Award to Dr. Rameshvar Adhikari, Tribhuvan University, Katmandu, Nepal; and numerous awards for young scientists and students, including the IUPAC Poster Award. Special Prof. Brar's 60th Birthday Celebration Awards were given to IUPAC poster prize winners.The next POLYCHAR will be hosted by Jean-Marc Saiter, University of Rouen, Rouen, France in April 2009.Poonam TandonConference Executive Secretary and Co-editor

scholarly journals Review of Polymeric Materials in 4D Printing Biomedical Applications

Polymers ◽  
2019 ◽  
Vol 11 (11) ◽  
pp. 1864 ◽  
Author(s):  
Ming-You Shie ◽  
Yu-Fang Shen ◽  
Suryani Dyah Astuti ◽  
Alvin Kai-Xing Lee ◽  
Shu-Hsien Lin ◽  
...  
Keyword(s):  
3D Printing ◽  
Smart Materials ◽  
Biomedical Applications ◽  
Polymeric Materials ◽  
3D Printer ◽  
Future Prospects ◽  
4D Printing ◽  
Current Application ◽  
3D Printed ◽  
Over Time

The purpose of 4D printing is to embed a product design into a deformable smart material using a traditional 3D printer. The 3D printed object can be assembled or transformed into intended designs by applying certain conditions or forms of stimulation such as temperature, pressure, humidity, pH, wind, or light. Simply put, 4D printing is a continuum of 3D printing technology that is now able to print objects which change over time. In previous studies, many smart materials were shown to have 4D printing characteristics. In this paper, we specifically review the current application, respective activation methods, characteristics, and future prospects of various polymeric materials in 4D printing, which are expected to contribute to the development of 4D printing polymeric materials and technology.

scholarly journals CeO2 Nanoparticle-Containing Polymers for Biomedical Applications: A Review

Polymers ◽  
2021 ◽  
Vol 13 (6) ◽  
pp. 924
Author(s):  
Alexander B. Shcherbakov ◽  
Vladimir V. Reukov ◽  
Alexander V. Yakimansky ◽  
Elena L. Krasnopeeva ◽  
Olga S. Ivanova ◽  
...  
Keyword(s):  
Biomedical Applications ◽  
Metal Oxide Nanoparticles ◽  
Polymeric Materials ◽  
Negative Effects ◽  
New Horizons ◽  
Beneficial Effects ◽  
Advanced Composite ◽  
Unique Material ◽  
Biomedical Polymers ◽  
Biomedical Potential

The development of advanced composite biomaterials combining the versatility and biodegradability of polymers and the unique characteristics of metal oxide nanoparticles unveils new horizons in emerging biomedical applications, including tissue regeneration, drug delivery and gene therapy, theranostics and medical imaging. Nanocrystalline cerium(IV) oxide, or nanoceria, stands out from a crowd of other metal oxides as being a truly unique material, showing great potential in biomedicine due to its low systemic toxicity and numerous beneficial effects on living systems. The combination of nanoceria with new generations of biomedical polymers, such as PolyHEMA (poly(2-hydroxyethyl methacrylate)-based hydrogels, electrospun nanofibrous polycaprolactone or natural-based chitosan or cellulose, helps to expand the prospective area of applications by facilitating their bioavailability and averting potential negative effects. This review describes recent advances in biomedical polymeric material practices, highlights up-to-the-minute cerium oxide nanoparticle applications, as well as polymer-nanoceria composites, and aims to address the question: how can nanoceria enhance the biomedical potential of modern polymeric materials?

Computational Exploration of Functional Nanoscale Carbonaceous Materials

2021 ◽  
Vol 17 ◽  
Author(s):  
Grigoriy Sereda ◽  
Md Tusar Uddin ◽  
Jacob Wente
Keyword(s):  
Biomedical Applications ◽  
Chemical Processes ◽  
Computational Power ◽  
Carbonaceous Materials ◽  
New Materials ◽  
New Era ◽  
Physico Chemical ◽  
Computational Exploration ◽  
Properties Of Materials ◽  
Computational Research

Background: The unique ability of carbon to form a wide variety of allotrope modifications has ushered a new era in the material science. Tuning the properties of these materials by functionalization is a must-have tool for their design customized for a specific practical use. The exponentially growing computational power available to researchers allows for the prediction and thorough understanding of the underlying physico-chemical processes responsible for the practical properties of pristine and modified carbons using the methods of quantum chemistry. Method: This review focuses on the computational assessment of the influence of functionalization on the properties of carbons and enabling desired practical properties of the new materials. The first section of each part of this review focuses on graphene - nearly planar units built from sp2-carbons. The second section discusses patterns of sp2-carbons rolled-up into curved 3D-structures in a variety of ways (fullerenes). The overview of other types of carbonaceous materials including those with a high abundance of sp3-carbons, including nanodiamonds, can be found in the third section of each manuscript’s part. Conclusion: The computational methods are especially critical for predicting electronic properties of materials such as the band gap, conductivity, optical and photoelectronic properties, solubility, adsorptivity, potential for catalysis, sensing, imaging and biomedical applications. We expect that introduction of defects to carbonaceous materials as a type of their functionalization will be a point of growth in this area of computational research.

Novel Behavior in Smart Polymeric Materials: Stress Memory and its Potential Applications

2016 ◽  
Vol 97 ◽  
pp. 93-99
Author(s):  
Jin Lian Hu ◽  
Harishkumar Narayana
Keyword(s):  
Magnetic Field ◽  
Shape Memory ◽  
Smart Materials ◽  
Shape Memory Polymers ◽  
Polymeric Materials ◽  
External Stimulus ◽  
Artificial Muscles ◽  
Recovery Stress ◽  
Stress Memory ◽  
Potential Applications

Materials, structures and systems, responsive to an external stimulus are smart and adaptive to our human demands. Among smart materials, polymers with shape memory effect are at the forefront of research leading to comprehensive publications and wide applications. In this paper, we extend the concept of shape memory polymers to stress memory ones, which have been discovered recently. Like shape memory, stress memory represents a phenomenon where the stress in a polymer can be programmed, stored and retrieved reversibly with an external stimulus such as temperature and magnetic field. Stress memory may be mistaken as the recovery stress which was studied quite broadly. Our further investigation also reveals that stress memory is quite different from recovery stress containing multi-components including elastic and viscoelastic forces in addition to possible memory stress. Stress memory could be used into applications such as sensors, pressure garments, massage devices, electronic skins and artificial muscles. The current revelation of stress memory potentials is emanated from an authentic application of memory fibres, films, and foams in the smart compression devices for the management of chronic and therapeutic disorders.

scholarly journals 3D Printing of Solvent-Free Supramolecular Polymers

2021 ◽  
Vol 9 ◽  
Author(s):  
Harald Rupp ◽  
Wolfgang H. Binder
Keyword(s):  
3D Printing ◽  
Dynamic Properties ◽  
Polymeric Materials ◽  
Fundamental Principle ◽  
Supramolecular Polymers ◽  
Fused Deposition Modelling ◽  
Self Healing ◽  
Polymer Science ◽  
Fused Deposition ◽  
Molecular Ordering

Additive manufacturing has significantly changed polymer science and technology by engineering complex material shapes and compositions. With the advent of dynamic properties in polymeric materials as a fundamental principle to achieve, e.g., self-healing properties, the use of supramolecular chemistry as a tool for molecular ordering has become important. By adjusting molecular nanoscopic (supramolecular) bonds in polymers, rheological properties, immanent for 3D printing, can be adjusted, resulting in shape persistence and improved printing. We here review recent progress in the 3D printing of supramolecular polymers, with a focus on fused deposition modelling (FDM) to overcome some of its limitations still being present up to date and open perspectives for their application.

Sign in / Sign up

Export Citation Format

Share Document