Revolutionizing Semiconductor Material Specifications

Author(s):  
RK Lowry
2020 ◽  
Author(s):  
Shogo Mori ◽  
Takahiro Aoki ◽  
Kaliyamoorthy Selvam ◽  
Shunichi Fukuzumi ◽  
Jieun Jung ◽  
...  

Despite the continuing popularity of radical reactions in organic synthesis, much remains to be explored in this area. Herein, we describe how spatiotemporal control can be exerted over the formation and reactivity of divergent exchangeable formamide radicals using nickel complexes with a semiconductor material (TiO<sub>2</sub>) under irradiation from near-UV–Vis light. Depending on the bipyridine ligand used and the quantity of the nickel complex that is hybridized on or nonhydridized over the TiO<sub>2</sub> surface, these radicals selectively undergo substitution reactions at the carbon center of carbon–bromine bonds that proceed via three different pathways. As the scalable production of formamides from CO<sub>2</sub> does not produce salt waste, these methods could add a new dimension to the search for carbon neutrality through the indirect incorporation of CO<sub>2</sub> into organic frameworks.


2021 ◽  
Vol 129 ◽  
pp. 114586
Author(s):  
Raphael M. Tromer ◽  
Leonardo D. Machado ◽  
Cristiano F. Woellner ◽  
Douglas S. Galvao

2015 ◽  
Vol 412 ◽  
pp. 103-108 ◽  
Author(s):  
Benjamin W. Montag ◽  
Michael A. Reichenberger ◽  
Kevin R. Arpin ◽  
Madhana Sunder ◽  
Kyle A. Nelson ◽  
...  

2016 ◽  
Vol 438 ◽  
pp. 99-103 ◽  
Author(s):  
Benjamin W. Montag ◽  
Michael A. Reichenberger ◽  
Nathaniel S. Edwards ◽  
Philip B. Ugorowski ◽  
Madhana Sunder ◽  
...  

2007 ◽  
Vol 101 (9) ◽  
pp. 09N504 ◽  
Author(s):  
R. R. Rakhimov ◽  
R. Bah ◽  
J. S. Hwang ◽  
S. P. Solodovnikov ◽  
I. A. Alexandrov ◽  
...  

Author(s):  
Xiao Tang ◽  
Kuanghui Li ◽  
Che-Hao Liao ◽  
Dongxing Zheng ◽  
chen Liu ◽  
...  

β-Ga2O3 is a wide bandgap semiconductor material promising for many fields such as gas sensors, UV detectors, and high power electronics. Until now, most epitaxial β-Ga2O3 thin films could only...


Sign in / Sign up

Export Citation Format

Share Document