Modeling the Effect of Curing Temperature and Pressure on Cement Hydration Kinetics

2013 ◽  
Vol 110 (2) ◽  
2012 ◽  
Vol 204-208 ◽  
pp. 3639-3643
Author(s):  
Chun Hua Rao ◽  
Lang Wu ◽  
Bin Lei

Abstract: Based on the cement hydration kinetics model proposed by R.Berliner, taking into account the factors such as each chemical phase of minerals, curing temperature, water-cement ratio, the final hydration degree and fineness of cement, a theoretical hydration kinetics equations was established in this paper. It can be used to predict the hydration rate and the change of hydration degree.


2021 ◽  
Author(s):  
Xuerui Wang ◽  
Feng Hao ◽  
Baojiang Sun ◽  
Zhiyuan Wang

Abstract The narrow density window in deep-water environment brought great challenges to well drilling and completion by causing well control issues. Managed Pressure Cementing (MPC) is a new technology developed from Manage Pressure Drilling (MPD), which can precisely control the annular fluid pressure profile. Accurate calculation of wellbore temperature and pressure is the key to MPC. This paper focus on coupled models of temperature and pressure for MPC in deep-water region. The well cementing process can be divided into two stages: fluid displacement stage and cement setting stage, which displays different characteristics. During the cementing displacement stage, the cement is in a flowable slurry state and is circulated into the annulus. During this process, the rheology of fluids if effected by temperature in wellbore. On basis of the fluid rheology model, a coupled model of temperature and pressure in wellbore is established considering the transient flow characteristics during cementing displacement stage. During cement setting stage, the cement slurry stops flowing and the significant cement hydration reaction starts. A large amount of hydration heat and obvious pressure reduction can be observed. On basis of the cement hydration kinetics model, a coupled model of temperature and pressure in wellbore during cementing setting stage is established. Based on the models established in this paper, a series of numerical simulations are conducted using a deep-water well. Simulation results show that neglecting the complicated interactions between temperature and pressure can cause a big error. During the cementing displacement stage, higher temperature in the deep part of wellbore reduces the fluid viscosity, which leads to a smaller friction. On the contrary, larger friction is observed near seabed as a result of the low temperature in deep-water environment. The pressure in wellbore changes frequently due to the coexistence of multiple fluids in wellbore. Therefore, a frequent control of annular fluid pressure is required using the MPC technology. During the cement setting stage, an obvious temperature increase is observed as a result of cement hydration heat. The pressure decreases with the depending of cement hydration. An addition back pressure at wellhead has to be added using the MPC technology. The transient temperature and pressure have impact on the rate of cement hydration in turn. Cement in the deep part of wellbore have a faster rate of cement hydration. The low temperature at mudline slows the cement hydration process. Considering the complicated interactions between temperature, pressure, cement hydration and fluid rheology, coupled models between temperature and pressure based on hydration kinetics during well cementing in deep-water region is established in the manuscript. The new model established in this paper plays an important role in the MPC technology.


2021 ◽  
Vol 11 (14) ◽  
pp. 6638
Author(s):  
Wenhao Zhao ◽  
Xuping Ji ◽  
Yaqing Jiang ◽  
Tinghong Pan

This work aims to study the effect of a nucleating agent on cement hydration. Firstly, the C-S-H crystal nucleation early strength agent (CNA) is prepared. Then, the effects of CNA on cement hydration mechanism, early strength enhancement effect, C-S-H content, 28-days hydration degree and 28-days fractal dimension of hydration products are studied by hydration kinetics calculation, resistivity test, BET specific surface area test and quantitative analysis of backscattered electron (BSE) images, respectively. The results show that CNA significantly improves the hydration degree of cement mixture, which is better than triethanolamine (TEA). CNA shortens the beginning time of the induction period by 49.3 min and the end time of the cement hydration acceleration period by 105.1 min than the blank sample. CNA increases the fractal dimension of hydration products, while TEA decreases the fractal dimension. CNA significantly improves the early strength of cement mortars; the 1-day and 3-days strength of cement mortars with CNA are more than the 3-days and 7-days strength of the blank sample. These results will provide a reference for the practical application of the C-S-H nucleating agent.


Author(s):  
Gilberto Artioli ◽  
Giorgio Ferrari ◽  
Maria Chiara Dalconi ◽  
Luca Valentini

2019 ◽  
Vol 9 (14) ◽  
pp. 2776 ◽  
Author(s):  
Sumra Yousuf ◽  
Payam Shafigh ◽  
Zainah Ibrahim ◽  
Huzaifa Hashim ◽  
Mohammad Panjehpour

Cement-based materials (CBMs) such as pastes, mortars and concretes are the most frequently used building materials in the present construction industry. Cement hydration, along with the resulting compressive strength in these materials, is dependent on curing temperature, methods and duration. A concrete subjected to an initial higher curing temperature undergoes accelerated hydration by resulting in non-uniform scattering of the hydration products and consequently creating a great porosity at later ages. This phenomenon is called crossover effect (COE). The COE may occur even at early ages between seven to 10 days for Portland cements with various mineral compositions. Compressive strength and other mechanical properties are important for the long life of concrete structures, so any reduction in these properties is of great concern to engineers. This study aims to review existing information on COE phenomenon in CBMs and provide recommendations for future research.


2013 ◽  
Vol 109 ◽  
pp. 291-297 ◽  
Author(s):  
Marcos A.S. Anjos ◽  
Antonio E. Martinelli ◽  
Dulce M.A. Melo ◽  
Tiago Renovato ◽  
Pablo D.P. Souza ◽  
...  

2013 ◽  
Author(s):  
Joseph J. Biernacki ◽  
Josephine H. Cheung ◽  
Jeffrey W. Bullard ◽  
William Hansen ◽  
Daniel Constantiner ◽  
...  

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