scholarly journals Pressure dissolution features in Oxfordian microbial-sponge buildups with pseudonodular texture, Kraków Upland, Poland

Author(s):  
Jacek Matyszkiewicz ◽  
Alicja Kochman
Keyword(s):  
2019 ◽  
Vol 89 (10) ◽  
pp. 1055-1073 ◽  
Author(s):  
Nicolaas Molenaar ◽  
Marita Felder

ABSTRACT Dolomite is a common and volumetrically important mineral in many siliciclastic sandstones, including Permian Rotliegend sandstones (the Slochteren Formation). These sandstones form extensive gas reservoirs in the Southern Permian Basin in the Netherlands, Germany, Poland, and the UK. The reservoir quality of these sandstones is negatively influenced by the content and distribution of dolomite. The origin and the stratigraphic distribution of the dolomite is not yet fully understood. The aim of this study is to identify the origin of carbonate. The main methods used to achieve those aims are a combination of thin-section petrography, scanning electron microscopy (SEM and EDX), and XRD analyses. The present study shows that the typical dispersed occurrence of the dolomite is a consequence of dispersed detrital carbonate grains that served both as nuclei and source for authigenic dolomite cement. The dolomite cement formed syntaxial outgrowths and overgrowths around detrital carbonate grains. The study also shows that dolomite cement, often in combination with ankerite and siderite, precipitated during burial after mechanical compaction. Most of the carbonate grains consisted of dolomite before deposition. The carbonate grains were affected by compaction and pressure dissolution, and commonly have no well-defined outlines anymore. The distribution of dolomite cement in the Rotliegend sandstones was controlled by the presence of stable carbonate grains. Due to the restricted and variable content of carbonate grains and their dispersed occurrence, the cement is also dispersed and the degree of cementation heterogeneous. Our findings have important implications on diagenesis modeling. The presence of detrital carbonate excludes the need for external supply by any large-scale advective flow of diagenetic fluids. By knowing that the carbonate source is local and related to detrital grains instead of being externally derived from an unknown source, the presence of carbonate cement can be linked to a paleogeographic and sedimentological model.


2011 ◽  
Vol 236-238 ◽  
pp. 87-90
Author(s):  
Li Ying Guo

Ionic liquid, 1-(2-hydroxylethyl)-3-ethylene imidazolium chloride ([HeVIM]Cl) was synthesized and its chemical structures was examined by FTIR and 1HNMR. Fir powder was extracted with a mixture of benzene/ethanol or activated with 25% (mass fraction) NaOH under normal temperature and pressure, microwave and high pressure. Dissolution of the pretreated wood powder in [HeVIM]Cl by microwave (90°C, 400w) was studied. The results showed that the ionic liquid [HeVIM]Cl exhibited a good solubility. Wood powder pretreated with 25% NaOH under high pressure had the lowest crystallinity (2.4%) and the highest dissolution rate (21.6%).


2020 ◽  
Vol 115 (1) ◽  
pp. 33-50 ◽  
Author(s):  
Christopher R. Voisey ◽  
David Willis ◽  
Andrew G. Tomkins ◽  
Christopher J.L. Wilson ◽  
Steven Micklethwaite ◽  
...  

Abstract Orogenic Au deposits have contributed the majority of Au recovered globally throughout history. However, the mechanism that concentrates Au to extremely high bonanza grades in small domains within these deposits remains enigmatic. The volume of fluid required to provide extreme Au endowments in localized occurrences is not reflected in field observations (e.g., in the extent of quartz veining or hydrothermal alteration). Detailed optical, scanning and transmission electron microscopy, nanoscale secondary ion mass spectrometry, and 3-D neutron tomography have been used to investigate the processes responsible for development of anomalously high grade ore (upward of 3% Au) found in quartz veins at Fosterville gold mine (Victoria, Australia). Distinct textural settings of visible Au include (1) Au concentrated along pressure solution seams associated with wall-rock selvages, (2) as nano- to microscale dusty Au seams parallel to pressure solution seams, and (3) in microscale tension fractures perpendicular to stylolitic seams. The distribution of Au in arsenopyrite and pyrite hosted within pressure solution seams changes as a function of the extent of deformation. Sulfides in highly deformed pressure solution seams exclusively host Au as nano- to micrometer-sized clusters within features associated with corrosion and brittle failure, whereas sulfides in mildly deformed pressure solution seams have Au bound in the crystal structure. It is proposed that Au supersaturation in fluids introduced during seismic periods led to the deposition of abundant Au nanoparticles in quartz-carbonate veins. Subsequent pressure dissolution of vein quartz and carbonate during interseismic intervals allowed for episodic increase in the Au/quartz ratio and permitted liberation and migration of Au nanoparticles, promoting Au grain growth in favorable textural settings. Galvanic corrosion and brittle fracturing of auriferous sulfides during the interseismic period allowed additional remobilization and/or enrichment of sulfide-hosted Au. Repetition of this mechanism over the time scale of deposit formation acted to concentrate Au within the lodes. This Au ore upgrading model, referred to as “aseismic refinement,” provides a new insight for the genesis of ultrarich Au mineralization and, based on textures reported from many Au deposits, may be a globally significant component in the formation of orogenic Au deposits.


2011 ◽  
pp. 247-254 ◽  
Author(s):  
M.C. Ruiz ◽  
O. Jerez ◽  
J. Retamal ◽  
R. Padilla

1990 ◽  
Vol 195 ◽  
Author(s):  
Morrel H. Cohen

ABSTRACTThree of the most important elements of the diagenesis of sedimentary rocks are consolidation, porosity reduction, and pressure dissolution or cementation. These are discussed qualitatively with special emphasis on the central role of contact formation in controlling both the driving forces and the kinetics of morphological change. It is shown, in particular, that the equilibrium forces would drive the rocks towards collapse of their porosity earlier in diagenesis were they not prevented by kinetic barriers. At greater depths these barriers are effectively removed by pressure concentration at the small contacts. We propose an explicit, qualitative mechanism leading to the observed morphologies and identify specific problems for quantitative analysis.


2004 ◽  
Vol 31 (1) ◽  
pp. 51
Author(s):  
ANDRÉIA REGINA DIAS ELIAS ◽  
LUIZ FERNANDO DE ROS ◽  
ANA MARIA PIMENTEL MIZUSAKI

Coastal-eolian sabkha sandstones from different ages and basins show similar diagenetic patterns, which understanding is important for their evaluation as geochemical systems and as hydrocarbon reservoirs. The Carboniferous sandstones of the Juruá Formation (Solimões Basin) are one of the most important gas reservoirs of Brazil. The sandstones and interbedded mudrocks, evaporites and dolostones were deposited within a coastal sabkha environment with pervasive eolian reworking, under increasing marine influence, and hot and dry climate. Four stacked drying/wetting upward cycles were identified, with sabkha facies in the base overlain by eolian deposits, followed again by sabkha deposits, commonly eroded by the next cycle. Eolian dune and sandsheet sandstones are the best reservoirs. The diagenetic evolution and the relationships among diagenesis, depositional facies and stratigraphic unit boundaries show similarities with other coastal-eolian sabkha sandstones. The eodiagenesis is characterized by mechanical compaction, hematite and infiltrated clay coatings, framboidal pyrite, microcrystalline and blocky dolomite. Mesodiagenesis comprises chemical compaction, K-feldspar and quartz overgrowths, poikilotopic anhydrite, feldspar dissolution and albitization, illite and chlorite authigenesis, and late quartz, Fedolomite/ ankerite, calcite and siderite. Localized telogenetic effects include oxidation of ferroan constituents and kaolinite precipitation. Blocky dolomite and quartz cementation, and chemical compaction through intergranular and stylolitic pressure dissolution are more abundant in the non-eolian sandstones. Microcrystalline pore-filling and pore-lining dolomite, and patchy, poikilotopic, post-compactional anhydrite cementation, mostly close to the contacts with interbedded evaporites, are more abundant in the eolian sandstones. These diagenetic patterns are similar to those of the Rotliegend Group in northern Germany and in the North Sea, of the Norphlet and Tensleep Formations in USA, of the Muschelkalk Formation in Spain, and of the Monte Alegre Formation from the Amazonas Basin, northern Brazil. The similarities among the diagenetic histories of these coastal-eolian sabkha sandstones are ascribed to their similar patterns of stratigraphic organization (intercalated evaporite and carbonate beds) and of composition and circulation of pore fluids.


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