scholarly journals Synthesis and Characterization of Novel Low-k Polyimides from Aromatic Dianhydrides and Aromatic Diamine Containing Phenylene Ether and Perfluorobiphenyl Units

2006 ◽  
Vol 38 (1) ◽  
pp. 79-84 ◽  
Author(s):  
Yasufumi Watanabe ◽  
Yuji Shibasaki ◽  
Shinji Ando ◽  
Mitsuru Ueda
2020 ◽  
Vol 32 (9) ◽  
pp. 1001-1009
Author(s):  
Yi-Sheng Luo ◽  
Qiu-Ying Wang ◽  
Xue-Chun Mao ◽  
Shou-Ri Sheng

A new aromatic diamine, 10,10-bis[4-(4-aminophenoxy)phenyl]-9(10 H)-anthrone (BAPA) has been synthesized from anthrone via three-step procedure. Direct phosphorylation polycondensation of BAPA with various aromatic dicarboxylic acids produced a series of cardo poly(ether amide)s with inherent viscosities of 0.97–1.29 dL g−1. All the polymers were readily soluble in polar solvents such as N-methyl-2-pyrrolidone, N, N-dimethylacetamide (DMAc), and pyridine at room temperature, and afforded transparent, strong, and flexible films upon casting from DMAc solvent. The resulting poly(ether amide)s had glass transition temperatures of 254–316°C, 10% weight loss temperatures of 495–524°C, and char yields of 55–70% at 800°C in nitrogen. These polymers were amorphous and their films exhibited tensile strengths of 81.6–104.7 MPa, tensile moduli of 1.8–2.4 GPa, and elongations at break of 8–15%.


2012 ◽  
Vol 24 (2) ◽  
pp. 85-96 ◽  
Author(s):  
Subramani Devaraju ◽  
Muthukumaraswamy Rangaraj Vengatesan ◽  
Mohan Selvi ◽  
Achimuthu Ashok Kumar ◽  
Mutukaruppan Alagar

2009 ◽  
Vol 123 (1-3) ◽  
pp. 45-49 ◽  
Author(s):  
Yanli Chen ◽  
Guangshan Zhu ◽  
Ye Peng ◽  
Hai Bi ◽  
Jing Feng ◽  
...  

2002 ◽  
Vol 10 (5) ◽  
pp. 241-245 ◽  
Author(s):  
Ji-Heung Kim ◽  
Jae Kwan Lee ◽  
Young Jun Kim ◽  
Jong Chan Won ◽  
Kil-Young Choi

Sign in / Sign up

Export Citation Format

Share Document